EN MSDS-01 硝酸銀（2014.09.01.）英訳
Contents
1. transport 140 Class 1 hazardous material Nitrates Class 3 oxidizing solid designated quantity 1 000kg Deleterious substance not for pharmaceutical use Hazardous material oxidizing substance Notifiable substance Article 57 2 government ordinance Article 18 2 attached table No 9 137 Ver GHS 09 MSDS 01 Silver Nitrate 8 8 Pharmaceutical Affairs Law Powerful drug and designated drug PRTR Class 1 designated chemical substance attached table 1 82 Act on Port Regulations Hazardous material oxidizing substance Civil Aeronautics Act Oxidizing substance class 2 Regulations for the carriage and Oxidizing substance class 2 storage of dangerous goods in ship 16 Other Information Bibliography Reagent guidebook Revised 2003 Collection of Poisonous Materials Standard Notifications Revised and enlarged edition 1991 Dictionary of Chemistry 1987 30th printing Kyoritsu Shuppan Chemistry and Applications of Precious Metal Elements 1984 Kodansha Hazardous Materials Safety Management Ver 4 Japan Association for Safety of Hazardous Materials 12996 Chemical Products 1996 The Chemical Daily Chemical Substances Control Law chemical substance METI Collection of Chemical Product Laws 1992 The Chemical Daily RTECS 2008 Journal of the Japan Society for Occupational Health 2007 GHS classification results database NITE website GHS model MSDS information JISHA website Caution Hazard and harmful2. MSDS 01 Silver Nitrate 1 8 Materials Safety Data Sheet Silver Nitrate Created May 21 2007 PSESE SESILA S eee nee Revised Sep 91 2014 1 Chemical Substances and Company Information Name of Chemical Substance Silver nitrate l Company Name Toyo Chemical Industrial Co Ltd Address 2 26 13 Naka lzumi Komae City Tokyo Tel 81 3 3489 5152 Fax 81 3 3488 1706 Emergency Contact As above Recommended Applications and Silver plating silver powder antibacterial agents mirrors analytical test drugs Use Restrictions catalysts 2 Summary of Hazards GHS Classification Physicochemical hazards Explosives Outside classification Damage to health Flammable combustible gas Flammable combustible aerosol Burnable oxidation gas type High pressure gas Flammable liquid Flammable solid Autoreactive chemicals Spontaneously combustible liquids Spontaneously combustible solids Self heating chemicals Hydration reactive flammable chemicals Oxidizing liquids Oxidizing solids Organic peroxides Metal corroding substances Acute oral toxicity Acute percutaneous toxicity Acute inhaled gas toxicity Acute inhaled vapor toxicity Acute inhaled dust toxicity Acute inhaled mist toxicity Skin corrosiveness and irritation Critical injury to eyes and eye irritation Respiratory organ sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific marker organ and systemic
3. ant Japanese Regulations Land Regulations Information Maritime Regulations Information Aviation Regulations Information UN No Proper Shipping Name Class Sub Risk Packing Group Special Safety Measures Urgent Measures during a Crisis Policy Number 15 Applicable Laws Fire Service Act Poisonous and Deleterious Substances Control Law Industrial Safety and Health Law Collect the silver using a roasting and reduction process or an oxide precipitation process During roasting gasses containing NOx are emitted so do not roast using an incinerator without cleaning equipment Ideally entrust to a specialized company Suitably process containers according to the relevant regulations and local government standards When disposing of empty containers make sure to discard the contents completely Obey International Maritime Organization regulations Obey International Civil Aviation Organization International Air Transport Association regulations 1493 Silver nitrate 5 1 Obey Poisonous and Deleterious Substances Control Law and Fire Services Act regulations Obey Ship Safety Law regulations Obey the Civil Aeronautics Law 1493 Silver nitrate 5 1 During transport avoid direct sunlight and load so that the containers are not damaged corroded or leaking and secure the load to prevent toppling Do not transport together with food or livestock feed Yellow card display is required during
4. area Wash hands thoroughly after handling If not using deliberately avoid discharging into the environment Storage Technical measures Store hazardous materials in their storage location and install the lighting illumination and ventilation necessary for handling Storage conditions Avoid contact with heat shock friction flammable materials reducing substances and oxidants during storage Avoid storing with foodstuffs Prevent spatter leaks discharge seepage into the floor and theft etc during storage Ver GHS 09 MSDS 01 Silver Nitrate 5 8 Incompatible substances Avoid contact with heat reducing substances and oxidants during storage Container and packing materials Airtight containers glass polyethylene stainless steel etc 8 Exposure Avoidance and Protection Measures Control concentration No data Tolerable concentration Japan Society for Occupational 0 01mg m as Ag Health 2007 ACGIH 2007 version TWA 0 1mg m as Ag TWA 0 01mg m as soluble Ag Equipment measures Install local exhausters and eye and hand washing facilities in the handling locations Protective Equipment Respirator Poison masks respirator during fires and dust masks Hand protective equipment Wear protective gloves Rubber gloves etc Eye protective equipment Wear eye protective equipment Goggles etc Skin and body protective equipment Wear protective face equipment clothing and protecti
5. ecautions protective Cordon off the periphery of the dispersal area to prohibit the entrance of personnel equipment and measures during When working wear protective equipment to prevent the inhalation of spattered emergencies adhesions dust and gas etc and work from upwind Remove all ignition sources Environmental precautions Make sure there is no discharge of the product or unprocessed thick effluent into rivers etc Collection and neutralization Collect any spatter in a container and then add saline to create silver chloride and collect the silver and then flush away using copious amounts of water Preventing secondary accidents Prevent inflow to drainage ditches sewers cellars or sealed locations 7 Handling and Storage Precautions Handling Technical measures No naked flames Avoid shock and high temperatures Beware of contact with flammable materials organic materials and reducing substances etc Local exhaust and overall Ideally handle in locations with local exhausters and overall ventilators ventilation Precautions for safe handling Do not handle until all safety precautions and readings are understood Prohibit the use of high temperature devices sparks and naked flames in the vicinity When using the product do not eat drink or smoke Do not touch inhale or drink Prevent contact with eyes skin and clothing Do not inhale dust fumes or mist Use only outdoors or in a well ventilated
6. eive diagnosis treatment If ingested rinse out the mouth and immediately consult a physician for treatment If inhaled Consult a physician promptly If you feel unwell consult a physician to receive diagnosis and treatment Gather any leaks Storage Lock the storage location Store separately from flammable and other prohibited materials Ver GHS 09 MSDS 01 Silver Nitrate 3 8 Chemical Substance Chemical name or general name Molecular formula molecular weight Chemical characteristics chemical or structural formula CAS No Reference numbers in gazetted list in japan CSCL and ISHL Impurities and stabilization additives that contribute to the classification Concentration or concentration range 4 Emergency Measures If inhaled Adhesion to skin Contact with eyes If ingested Predicted acute symptoms and delayed onset symptoms Most important signs and symptoms Protection of people implementing emergency measures Special precautions for physicians 5 Measures during Fires Flame retardants Disposal If discarding contents or containers entrust to a specialized waste disposal company 3 Composition and Component Information Silver nitrate I AgNO 169 87 Silver nitrate T O NaON 7761 88 8 1 8 No data 99 9 min Causes irritation and chemical burns to the mucous membranes of the nose throat and bronchus Blow nose and gargle Con
7. ness evaluations were created using the data and information available at the current time but is not necessarily thorough so handle with care Further the data and evaluations described herein are not in any way guaranteed The descriptions refer to normal handling so for special handling first implement safety measures conforming to the new application and methods of use This MSDS is translated into English Original version is Japanese Ver GHS 09
8. organ irritation Organ lung kidney and hematological system damage due to long term or repeated exposure Extremely strong poison to aquatic life Extremely strong poison to aquatic life due to long term effects Cautions Safety Measures Obtain the user manual before use Do not handle until all safety precautions and readings are understood Keep away from ignition sources such as heat fireworks naked flames and high temperatures No smoking Do not spray on naked flames or other ignitions sources Take preventive measures to avoid mixing with flammable or prohibited substances When using the product do not eat drink or smoke Use only outdoors or in a well ventilated area Wear protective gloves goggles and face mask Prevent contact with eyes skin and clothing Do not inhale the dust Wash hands thoroughly after handling Avoid discharging into the environment Emergency Measures If the substance contacts the eye irrigate with water thoroughly for several minutes If contact lenses can be removed easily remove and wash them If eye irritation persists consult a physician and receive treatment If clothing is spattered promptly remove and isolate all soiled clothing Wash contaminated clothing before reuse If the substance adheres to the skin wash using copious amounts of soap and water If skin irritation occurs consult a physician and receive treatment If exposed or fear exposure consult a physician and rec
9. s to be avoided Light and heat Incompatible substances Flammable substances and reducing substances Hazardous degradable organisms Silver and NO 11 Harmfulness Information Acute toxicity Oral lethal dose 10g Mouse oral LD50 50mg kg Rat oral LD50 1 173mg kg Mouse intraperitoneal LD50 17mg kg Rat intraperitoneal LD50 83mg kg Skin corrosiveness and irritation Mild skin irritation Skin irritation Rabbit 500mg 24hr mild Critical injury to eyes and Eye irritation Rabbit 10mg strong eye irritation Respiratory organ and skin sensitivity No data Germ cell mutagenicity No data Carcinogenicity No data Reproductive toxicity No data Specific marker organ and No data systemic toxicity single exposure Specific marker organ and Risk of organ skin and respiratory organ damage due to long term or repeated systemic toxicity repeated exposure exposure Inhalable respiratory organ No data harmfulness 12 Environmental Impact Information Ecotoxicity Toxic to aquatic environment life forms and affects the ecosystem Persistence and degradability No data Bioaccumulation No data Ver GHS 09 MSDS 01 Silver Nitrate 7 8 13 Disposal Precautions Residual waste Dirty containers and packaging 14 Shipping Precautions International Regulations Maritime Regulations Information Aviation Regulations Information UN No Proper Shipping Name Class Sub Risk Packing Group Marine Pollut
10. sult a physician if necessary Irritates and corrodes skin Wash with copious amounts of water Consult a physician if the corrosion is severe Causes a feeling of contamination and irritates the membranes Wash using dilute salt water and copious amounts of water and then consult a physician Drink copious amounts of tepid water lukewarm salt water milk and egg whites etc to induce vomiting and then consult a physician Eye pain and severe chemical burns No information Rescuers should wear suitable protective equipment according to the circumstances No information Water jets foam retardants powder retardants excluding hydrogen carbonate dry sand etc Ver GHS 09 MSDS 01 Silver Nitrate 4 8 Characteristic dangers There is a risk of exacerbating fires Strong heat causes harmful gas NOx to be emitted so wear protective equipment when firefighting Extinguishants that must not be used Carbon gas and hydrogen carbonate powder retardants Characteristic extinguishing methods Promptly move containers in the vicinity of the fire to a safe location If moving is not possible scatter water on the containers and their surroundings to cool Protection of firefighters Fight fire from upwind and avoid inhaling poisonous gasses etc Wear respiratory protectors depending on the circumstances Keep upwind all personnel unnecessary to disaster prevention activities 6 Measures during Leaks Physical pr
11. toxicity single exposure Specific marker organ and systemic toxicity Single exposure Specific marker organ and systemic toxicity repeated exposure Inhalable respiratory organ harmfulness Ver GHS 09 Outside scope of classification Outside scope of classification Outside scope of classification Outside scope of classification Outside scope of classification Outside classification Outside classification Outside scope of classification Outside classification Outside classification Outside classification Outside scope of classification Class 2 Outside scope of classification Cannot classify Class 4 Cannot classify Outside scope of classification Cannot classify Cannot classify Cannot classify Class 1A to 1C Class 1 Cannot classify Cannot classify Cannot classify Cannot classify Class 2 Class 1 hematological system Class 3 Airway irritation Class 1 Lung kidney and cardiovascular systems Cannot classify MSDS 01 Silver Nitrate 2 8 Damage to the environment Acute aquatic environmental harm Class 1 Chronic aquatic environmental harm Class 1 Label Elements Picture descriptions and labels A Cautionary terms Danger Hazard information Risk of fire accelerant Oxidation substance Harmful if ingested Critical eye injury Critical skin chemical burns Suspected risk of malign influence on reproductive functions or fetus Risk of organ hematological system damage and respiratory
12. ve shoes etc Protective clothing protective boots etc Hygiene measures When using the product do not eat drink or smoke Wash hands thoroughly after handling 9 Physical and Chemical Properties Physical properties shape and Colorless to white crystalline powder color etc Odor Slightly acidic odor pH Weak acidity when dissolved in water Melting point and coagulation point 212 C melting point Boiling point initial boiling point No data and boiling range Ignition point No data Explosion range No data Vapor pressure No data Vapor density vapor 1 No data Specific gravity density d 4 35 Solubility Water 20 C 215 7 g 100ml Ethanol 15 C 3 8 g 100g Acetone 15 C 0 35 g 100g Octanol water partition coefficient No data Spontaneous ignition temperature No data Dissolution temperature Dissolves at 444 C Odor threshold value No data Vaporization speed butyl acetate 1 No data Burnability solids and gas No data Viscosity No data Ver GHS 09 MSDS 01 Silver Nitrate 6 8 10 Stability and Reactivity Stability Has properties that oxidize other substances and when mixed with flammable substances dissolves due to heat shock friction etc to cause fierce burning In the presence of organic residue the silver separates and discolors due to light Possibility of harmful reactions Substance is an oxidant and reacts with flammable substances and reducing substances Condition
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