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Chemical Hygiene Plan h - University of Alaska Fairbanks

1. Chemical Hygiene Plan e UNIVERSITY OF ALASKA FAIRBANKS INTRODUCTION ota est ipt tvm pad eee DAP 2 I ROLES AND RESPONSIBILITIES ee soto de o aeuo oe ens 3 A Ppncipal investigator 3 Laboratory Mud ath UIS UE ardet ics 3 C Chemical Hygiene Officer CHO eere e eee en ases en ea oa 3 1 EMPLOYEE INFORMATION AND TRAINING eese 3 Ill PRIOR APPROVAL CIRCUMSTANCES eese eese te 4 IV STANDARD OPERATING PROCEDUREG csssssssssssssesserssnsesesssecsesssesecsesseeesses 5 A General RN rede bM e rever 5 B Personal Hygletie oui ace decreto Op 5 G Housekeepifitu a enu op Pie ERR n UI boise rei 5 D Protective Clothing and Equipment eee ees eeeeee eene etn eterne tttntnn 6 E Flaibimable Malerials operario eti tip p iia FCR eye beads 8 F Reactive Chemicals oneri resort s Foe deo eb odo eat ri Os EE b bur pe 8 G Corrosive Chernicals cue e EROR DAR eer RE bone 8 FA Acids arid BAS OS i ruens nier bea vn TRETEN 10 Compressed Gas Cylinders COS EE Ste e ead 11 V GON TROL MEASURES n nds rea teat yen Pepe i tate 12 A Ventilation eu n
2. University Of Alaska Fairbanks Chemical Hygiene Plan PACKAGING REQUIREMENTS FOR ALL HAZARDOUS MATERIALS e The outside of the containers must be clean and free of chemical contamination e Use appropriate containers All glass containers must be securely packaged to prevent breakage during transport e All containers of liquids must have screw lids and must not leak when inverted Corks cotton plugs tape or parafilm are not acceptable lids for containers of hazardous materials e f possible use the same container for disposal of used material that held the new material originally e Metal cans are not acceptable for accumulating hazardous solvents except for waste oil e Loose solid materials must be placed in a sealed container or in a cardboard box lined with two polyethylene bags e Containers storing hazardous materials must be kept closed except when adding or removing contents DEFINITIONS OF HAZARDOUS MATERIALS Hazardous materials are those that could cause injury or death or damage or pollute land air or water Hazardous wastes are defined as substances that are ignitable flammable corrosive toxic explosive or reactive i e react with air water or acids or bases Specific definitions are found in the Code of Federal e Regulations 40CFR part 261 These are summarized below Ignitable This category contains materials that are easily combustible or flammable This includes liquids that hav
3. Date and time of the discharge or release Location of the discharge or release Describe the surface area impacted by the spill or release ie asphalt concrete gravel soil water and the size of the area impacted is approx sq ft Type and amount of oil or hazardous substance discharged or released Factors that caused or contributed to the discharge or release Description of the actions taken for containment and cleanup Estimated amount of oil or hazardous substance recovered in cleanup a How the cleanup materials currently contained and where are they stored O Proposed method and date for disposal Q Comments or follow up actions required UAF Spill Reporting Requirements For hazardous substance spills oil discharges to water or oil discharges greater than 55 gallons spilled to land the potentially responsible party must immediately notify ADEC 451 2360 UAF Dispatch Center 474 7721 Department Supervisor UAF EHS amp RM 474 5487 For oil spills to land in quantities less than 55 gallons the potentially responsible party must immediately notify Dispatch Center 474 7721 O EHS amp RM 474 5487 In all cases the potentially responsible party must complete the UAF Oil and Hazardous e Substances Spill Reporting Form Please see the form for additional instructions The Alaska Department of Environmental Conservation ADEC identifies t
4. MAJOR APPLIANCES DO NOT USE OPEN FLAMES FOR LIGHTING COMPLETE THE APPROPRIATE 9 ASSIST Call 911 REPORTING FORM University Of Alaska IN CASE OF EMERGENCY Appendix 5 University Of Alaska Fairbanks Chemical Hygiene Plan HAZARDOUS MATERIALS PICKUP AND DISPOSAL PROCEDURES Appendix 6 Hazardous materials are defined as those materials that are flammable corrosive air or water reactive or toxic see Definitions of Hazardous Materials below Environmental Health Safety and Risk Management EHS amp RM Hazardous Materials Section is charged with the responsibility of removing all hazardous materials used and unused from UAF facilities Materials picked up by EHS amp RM are recycled used by someone else or disposed of at an EPA approved facility The complete disposal procedure is found under UAF Policy 601 Hazardous Materials Management Procedure TO HAVE HAZARDOUS MATERIALS REMOVED FROM YOUR AREA YOU MUST e Communicate the need for the removal of hazardous materials or other chemicals by utilizing the UAF Hazardous Materials Transfer Request Forms which are available upon request from the EHS amp RM Hazmat Section e Fill out and affix required hazardous material label on containers and promptly place in approved hazardous material collection areas e Atthe time when the accumulation of a material begins the date should be clearly mark
5. production of 1 1 1 trichloroethane Column bottoms or heavy ends from the combined production of trichloroethylene and perchloroethylene By product salts generated in the production of MSMA and cacodylic acid Wastewater treatment sludge from the production of chlordane Wastewater and scrub water from the chlorination of cyclopentadiene in the production of chlordane Filter solids from the filtration of hexachlorocyclopentadiene in the production of chlordane Wastewater treatment sludges generated in the production of creosote Still bottoms from toluene reclamation distillation in the production of disulfoton Wastewater treatment sludges from the production of disulfoton Wastewater from the ashing and stripping of phorate production Filter cake from the filtration of diethylphosphorodithioic acid in production of phorate Wastewater treatment sludge from the production of phorate Wastewater treatment sludge from the production of toxaphene Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production of 2 4 5 T 2 6 dichlorophenol waste from the production of 2 4 D EPA HAZARDOUS WISIS CODES Continued Code Waste description K044 Wastewater treatment sludges from the manufacturing and processing of explosives K045 Spent carbon from the treatment of wastewater containing explosives K046 Wastewater treatment sludges from the man
6. Department name Storage Color Code Building name transfer location Room number Consolidation drum number Contact name Waste manifest number e Material origin academic Waste profile number 12 research Invoice number support Invoice line item number Chemical abstract service number Chemical characteristics Sigma Aldrich reference number Chemical incompatibilities Health hazard information Computer generated reports can be sorted by the criteria listed above Reports UAF EH amp S RM completes a biennial waste report for UAF campus facilities which is mandated by the EPA Currently biennial reporting is required on even numbered years for the previous year activities Biennial Reports are not currently required for CESQG s Empty Containers Empty containers should be clean and marked with the word Empty or the initials M T Containers which have held P listed acutely hazardous listed materials are regulated for disposal Pesticide containers should be triple rinsed with the rinsate added as a part of the application solution The container should be punctured and marked accordingly Broken glass should be properly packaged in puncture proof containers ie poly lined fibreboard boxes and marked to identify contents Bio Hazardous Materials Please refer to the UAF Institutional Biosafety Handbook which is available at http www uaf edu ibc The UAF Bloodborne Pathogen Policy and Procedure
7. Please note that although oxidizers and characteristic ignitable materials share the same waste code they are not compatible and must not be stored together D001 characteristics consist of e Liquids other than lt 24 vol aqueous alcohol solutions with a flash point less than 140 F using specified ASTM standard closed cup methods e Non liquids capable under standard temperature and pressure of causing fire through friction absorbtion of moisture or spontaneous chemical changes and when ignited burn vigorously enough to create a hazard e Ignitable compressed gases as defined by DOT in 49 CFR 173 300 Note The ignitability characteristic is different than the various classifications of flammable material under the International Classification System for hazardous materials used by DOT See 40 CFR 261 21 for complete information regarding characteristic wastes D002 characteristic wastes are corrosive wastes ie acidic or basic wastes and have the following characteristics e aqueous and exhibit a pH of lt 2 or gt 12 5 or e corrode steel SAE 1020 at a rate of 6 35 mm yr 0 25 in yr at a test temperature of 130 F 55 See 40 CFR 261 22 for complete information D003 characteristic wastes have reactive characteristics as defined in 40 CFR 261 23 The characteristic of reactivity is based on the waste having any of the following properties e tis normally unstable and readliy undergoes violent
8. Utilities in Fairbanks Please check with your community for specific discharge limitations CESQG Hazardous Waste Management Procedures To maintain CESGQ status and ensure the timely removal of regulated hazardous waste it is very important to keep a running inventory of those waste materials Inventories of surplus hazardous materials and chemical wastes will be compiled by completing the Non Radioactive Hazardous Materials Transfer Request Forms which are available from your Chemical Hygiene Officer Lab Manager or Safety Coordinator Each of the three part numbered forms has a similarly numbered adhesive container label When a waste is generated or a surplus material identified please complete the form and label and affix the hazardous material label on the container s At the time when the accumulation of the waste material begins the date should be clearly marked and visible for inspection mark satellite accumulation start date on transfer label The information to be completed on the Non Radioactive Hazardous Material Transfer Request Form includes e Material description and or chemical name If a chemical substance or mixture include the concentration and or percentages of the chemical constituents e Approximate quantity of the material e The physical state of the material i e solid liquid gas or semi solid e Container type i e glass plastic metal fiber board e On site temporary storage location o Da
9. mineral oil products 100 0 Oil and grease animal and vegetable based e 0 0 700 Pesticides all 0 5 Phenol 0 43 Silver 5 0 Tin 2 61 Zinc These limits apply at the point where the wastewater is discharged to the wastewater collection system All concentrations for metallic substances are for total metal unless indicated otherwise The superintendent may impose mass limitations in addition to or in place of the concentration based limitations above Where a user is subject to a categorical pretreatment standard and a local limit for a given pollutant the more stringent limit shall apply Code 1960 15 203 1 Ord No 5398 1 10 11 99 UAF Oil and Hazardous Substances Spill Reporting Form Page 1 of 2 UAF Use Report all spills to the UAF Dispatch Center at 474 7721 Ask for assistance if needed After reporting the spill complete this form provide a copy to your supervisor and fax copies to the UAF Dispatch Center fax 474 7377 and UAF EHS amp RM fax 474 5489 Contact Name Department Building Room Fax Contractor Use Report all spills to the UAF Dispatch Center at 474 7721 Ask for assistance if needed After reporting the spill complete this form provide a copy to the DDC Project Manager and fax copies to the UAF Dispatch Center fax 474 7377 and UAF EHS amp RM fax 474 5489 Project Location DDC Project Manager Company Name Contact Potential Responsible Party Date
10. 0236 0236 0237 0237 Waste description Ethanethioamide Thioacetamide Thiourea Benzene methyl Toluene Benzenediamine ar methyl Toluenediamine Benzenamine 2 methyl hydrochloride o Toluidine hydrochloride Benzene 1 3 diisocyanatomethyl R T Toluene diisocyanate R T Bromoform Methane tribromo Ethane 1 1 t trichloro Methyl chloroform 1 1 2 Trichloroethane Ethane 1 1 2 trichloro Ethene trichloro Trichloroethylene 1 3 5 Trinitrobenzene R T Benzene 1 3 5 trinitro 1 Propanol 2 3 dibromo phosphate 3 1 Tris 2 3 dibromopropyl phosphate 2 7 Naphthalenedisulfonic acid 3 3 16 3 dimethylf1 biphenyl 4 4 diyl bis azo bis 5 amino 4 hydroxy _ tetrasodium salt Trypan blue 2 4 1H 3H Pyrimidinedione 5 pee chloroethylamino Uracil mustard em Code U238 U238 U239 U239 U240 U240 0240 U243 U243 U244 U244 U246 U247 U247 U248 U248 U249 U271 U278 U278 20279 0279 17280 10280 Waste description Carbamic acid ethyl ester Ethyl carbamate urethane Benzene dimethyl LT Xylene 1 24 D salts amp esters Acetic acid 2 4 dichlorophenoxy salts amp esters Dichlorophenoxyacetic acid 2 4 D 1 1 1 2 3 3 3 hexachloro Hexachloropropene Thioperoxydicarbonic diamide H N C S S tetramethyl Thiram Cyanogen bromide CN Br Benzene 1 1 2 2 2 trchloroethylidene
11. 1 16 carboxylic acid 11 17 dimethoxy 18 3 4 5 trimethoxybenzoyl oxy methyl ester 3beta 16beta 17alpha 18beta 20alpha 3 Benzenediol Resorcinol 1 2 Benzisothiazol 3 2H one 1 1 dioxide amp salts Saccharin amp salts 1 3 Benzodioxole 5 2 Code Waste description U203 U204 U204 U205 U205 U206 U206 U206 U207 U207 U208 U208 U209 U209 U210 U210 un Ul U213 U213 U214 U214 U215 U215 U216 U216 U217 U217 i Safrole Selenious acid Selenium dioxide Selenium sulfide Selenium sulfide SeS RD D Glucose 2 deoxy 2 B methylnitrosoamino carbony amino Glucopyranose 2 deoxy 2 3 methyl 3 nitrosoureido D Streptozotocin 1 2 4 5 Tetrachlorobenzene Benzene 1 2 4 5 tetrachloro 1 1 1 2 Tetrach loroethane Ethane 1 1 1 2 tetrachloro 1 1 2 2 Tetrachloroethane Ethane 1 1 2 2 tetrachloro Ethene tetrachloro Tetrachloroethylene Carbon tetrachloride Methane tetrachloro Furan tetrahydro I Tetrahydrofuran 1 Acetic acid thallium salt Thallium 1 acetate Carbonic acid dithallium 1 salt Thallium I carbonate Thallium chloride Tlcl Thallium T chloride Nitric acid thallium 1 satt Thallium 1 nitrate EPA HAZARDOUS WASTE CODES e Continued Code 0218 0218 0219 220 0220 0221 0221 0222 0222 0223 0223 0225 0225 0226 0226 0227 0227 0228 0228 0234 0234 0235 0235
12. Injury Student Visitor UAF Accident Injury Report EMERGENCY ASSEMBLY POINT OUTSIDE Please keep this form in a prominent position in your off EMERGENCY EVENT FIRST ACTION THEN DO THIS FIRE OR EXPLOSION Call 911 PULL ALARM E CHEMICAL SPILL THAT SEIEN EVACUATE TO NEARBY AREA IS or MIGHT BE LIFE REMOVE VICTIMS CLOTHING DOUSE THREATENING W WATER 15 MINUTES pe __ Attend to anyone who may CHEMICAL SPILLNOT have been contaminated ae here EE CLOSE DOORS LIFE THREATENING call EHS amp RM Hazmat a didus AREAS Section at x5487 See Section V B of this Plan em ee DETAIN THOSE CONTAMINATED RADIOACTIVE SPILL 5 CONSULT RADIATION SAFETY MANUAL Call 911 ENSURE ACCESS TO THE AREA p ARRESE BEGIN CPR IF QUALIFIED ODD ODOR Call CHO EHS amp RM 5413 IDENTIFY SOURCE or Gas Odor UFD 7721 IF POSSIBLE EAR dup EARTHQUAKE DO NOT CALL INSIDE GET BENEATH STRUCTURE If a gas leak or electrical desk doorway OUTDOORS GET INTO Call 7000 FS OPEN AREA AFTER TREMOR SECURITY PROBLEM Call 6200 or 911 PERSON OR ANIMAL 24 hrs UAF Police DESCRIPTION EN GN GIVE EXACT LOCATION OF UTILITY Call x7000 FS FAILURE TURN OFF EQUIPMENT RE f aft i UTILITY FAILU If after gii
13. K125 Condensed column overheads from intermediate separation from the production of 1 1 dimethylhydrazine from acid hydrazides Product washwaters from the protein of dinitrotoluene via nitration of toluene Reaction by product water the drying column in the production of toluenediamine via hydrogenation of dinitrotoluene Condensed liquid light ends from purification of toluenediamine in production of toluenediamine via hydrogenation of dinitrotoluene Vicinals from the purification of toluenediamine in production of toluenediamine via hydrogenation of dinitrotoluene Heavy ends from purification of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene Organic condensate from the solvent recovery column in the production of toluene diisocyanate via phosgenation of toluenediamine Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene Spent adsorbent solids from purification of ethylene dibromide in the production of ethylene dibromide via bromination of ethene Process wastewater including supernates filtrates and washwaters from the production of ethylenebisdithiocarbamic acid and its salts Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid and its salts Filtration evaporation and centrifugation solids from the production of ethylene
14. N N Diethylhydrazine O O Diethyl S methyl dithiophosphate Phosphorodithioic acid O O diethyl S methyl ester 1 2 Benzenedicarboxylic acid diethy ester Diethyl phthalate Diethylstilbestero Phenol 4 4 1 2 diethyl 1 2 ethenediyl bis 1 3 Benzodioxole 5 propyl Dihydrosafrole 1 1 Biphenyl 4 4 diamine 3 3 dimethoxy 3 3 Dimethoxybenzidine _Dimethylamine 1 Methanamine N methyl Benzenamine N N dimethyl 4 phenylazo p Dimethylaminoazobenzene 7 12 Dimethylbenz aJanthracene Benz aJanthracene 7 12 dimethyl 1 1 Biphenyl 4 4 diamine 3 3 dimethyl 3 3 Dimethylbenzidine EPA HAZARDOUS e Continued Code 1096 0096 10097 0097 0098 0098 0099 0099 0101 U101 0102 0102 0103 0103 0105 1105 0106 0106 0107 U108 U108 U109 U109 Ul10 U110 Un 0111 Waste description alpha alpha Dimethylbenzylhydroperoxide R c ues Hydroperoxide L methyl 1 phenylethyl Q o pes Carbamic chloride dimethyl Dimethylcarbamoy chloride 1 1 Dimethylhydrazine Hydrazine 1 1 dimethy 12 Dimethylhydrazine Hydrazine 1 2 diphenyl 2 4 Dimethylphenol Phenol 2 4 dimethyl 1 2 Benzenedicarboxylic acid dimethyl ester f Dimethy phthalate Dimethyl sulfate Sulfuric acid dimethyl ester 2 4 Dinitrotoluene Benzene 1 methyl 2 4 dinitro 2 6 Dinitrotoluene Benzene 2 methyl 1 3 dinitro 1 2 Benzenedicarboxylic acid dioctyl ester Di n o
15. Oy a ctr von etis euo msi t eria ird 12 B Spill Clean up PFrOCBOUF6s 13 VI EXPOSURE MONITORING erre cete eeenen ento to rto e tato eto 15 VII MEDICAL CONSULTATIONS AND 15 Vill SELECT CARCINOGENS REPRODUCTIVE TOXINS HIGHLY ACUTE TOXINS HMM 15 NOTE You can save this document in your preferred Word Processor by clicking on the Edit menu choosing select all then click on Copy Paste it into your word processing program and edit for your laboratory specific Standard Operating Procedures The text in brackets are formatted for the table of contents The text will not show up when printed University Of Alaska Fairbanks Chemical Hygiene Plan LABORATORY EMERGENCY PROCEDURES DURING POWER OUTAGES Appendix 8 It is important to remember that some equipment cannot be turned off and certain other pieces of equipment do not shut themselves off when there is a power outage Pre plan specific procedures for your laboratory while adhering to the following Close chemical fume hood sashes No work is allowed in fume hoods during a power outage Ensure that all chemical containers are secured with caps parafilm etc All non essential electrical devices should be turned off Keep the doors of refrigerators and freezers closed Check to ensure large lasers rad
16. The waste container remains closed capped at all times unless adding or removing waste L The satellite accumulation start date is identified on the waste container The waste is stored in secondary containment The waste is segregated from all incompatible materials Incompatible materials are never stored in the same container _ Waste storage areas are inspected weekly by departmental personnel 1 Containers holding hazardous waste are in good condition and not subject to failure due to their contents Materials containing gt 500ppm VOC s in excess of 26 gallons per container are stored in DOT specification containers contact EHS amp RM Completed Hazmat Transfer Request forms are sent to UAF EHS amp RM to schedule waste removal when container is full University Of Alaska Fairbanks Chemical Hygiene Plan Decontamination Equipment and glassware decontamination procedures are as follows Other Information University Of Alaska Fairbanks Chemical Hygiene Plan LABORATORY INSPECTION CHECKLIST Appendix 2 Laboratory Safety Inspection Checklist This checklist is provided as a guideline to conduct internal safety surveys This summary does not list every possible hazard but may be useful in performing periodic safety inspections All items are not always applicable to ail facilities Please contact UAF EHS amp RM for assistance in correcting deficiencies Department Name Area Inspect
17. Yes No 1 Are all personnel aware of how to have hazardous waste removed from the lab or shop Yes No 2 Is the disposal of hazardous substances down the drain or in the normal trash prevented Yes No 3 Are personnel instructed to not dispose of chemicals by evaporation in the fumehood Yes No 4 Are the proper containers obtained and used for storing hazardous waste Yes No N A 5 Areall containers properly marked to identify their contents and constituent concentrations and labeled with the CESQG Hazardous Material Transfer Request tag Yes No 6 Is the satellite accumulation start date identified on the waste container Yes No N A 7 15 the accumulation of waste communicated to EH amp S RM in time to prevent the accumulation of more than 50 gallons of RCRA regulated waste and or 500 ml of acutely hazardous P listed waste Yes No N A 8 Areall containers kept tightly closed except when adding or removing waste Yes No N A 9 Are wastes properly segregated with regard to their chemical compatibility Yes No N A 10 Are liquid waste containers kept in secondary containment tubs Yes No N A 11 Are waste storage areas inspected weekly Yes No N A 12 Are waste minimization practices used in the shop or laboratory Yes No N A 13 15 infectious biohazardous waste properly bagged and autoclaved or incinerated 23 Yes No 14 Are all sharps collec
18. and lamps as described in 273 5 The universal waste regulations include seven subparts A brief description o four of these subparts follow Small quantity handlers SQHUW s 5000 kg or less of total universal waste handled at one time Notification to EPA is not required shipments are not required to be manifested no record retention requirement Large quantity handlers LQHUW s greater than 5000 kg of total universal waste at one time Must notify EPA of universal waste activity obtain an EPA ID number if they don t already have one and retain off site shipment records for 3 years This can be a logbook invoice manifest bill of lading or other shipping document Transporters of universal waste batteries must be done in accordance with Department of Transportation regulations found at 49 CFR part 171 180 Destination Facilities regulations found at 40 CFR 273 6 The management requirements for SQHUW s are found at 40 CFR 273 13 and include the following Packaging requirements A small quantity handler of universal waste must contain any universal waste battery that shows evidence of leakage spillage or damage that could cause leakage under reasonably foreseeable conditions in a container The container must be closed structurally sound compatible with the contents of the battery and must lack evidence of leakage spillage or damage that could cause leakage under reasonably foreseeable conditions Ensure that all
19. at points designed and approved by GHU Noxious or malodorous liquids gases solids or other wastewater which either singly or by interaction with other wastes are sufficient to create a public nuisance or a hazard to life or to pr vent entry into the sewers for maintenance or repair Wastewater which imparts color which cannot be removed by the treatment process such as but not limited to dye wastes and vegetable tanning solutions which consequently imparts color to the treatment plant s effluent thereby violating NPDES permit of the city and GHU color in combination with turbidity shall not cause the treatment plant effluent to reduce the depth of the compensation point for photosynthetic activity by more than ten percent from the seasonably established norm for aquatic life Wastewater containing any radioactive wastes or isotopes except as specifically approved by the superintendent in compliance with applicable state or federal regulations Stormwater surface water groundwater artesian well water roof runoff subsurface drainage swimming pool drainage condensate deionized water noncontact cooling water and unpolluted wastewater unless specifically authorized by the superintendent Sludges screenings or other residues from the pretreatment of industrial wastes Medical wastes except as specifically authorized by the superintendent in a wastewater discharge permit Wastewater causing alone or in c
20. at all times in laboratories where chemicals are being used This includes visitors Ordinary prescription glasses are not considered effective eye protection since they lack necessary shielding Chemical resistant goggles should be worn over the glasses or prescription safety glasses be provided to employees required to wear corrective lenses The wearing of contact lenses in the laboratory is very controversial Consult with an Optometrist prior to wear in the laboratory Safety glasses or chemical resistant goggles shall be worn over contacts at all times When working with corrosive toxic allergenic or sensitizing chemicals rough or sharp edged objects very hot or very cold materials gloves made of material known to be resistant to University Of Alaska Fairbanks Chemical Hygiene Plan Page 7 of 16 10 permeation by the substance shall be worn No one glove can protect against all hazards Cloth gloves while not appropriate for use around liquids can protect against light abrasive materials and moderate temperature changes Synthetic or rubber gloves protect against corrosives solvents and poisons Leather gloves often used for tasks like welding protect against sparks heat and rough abrasives Consult the manufacturer s performance chart or contact the Chemical Hygiene Officer to determine the proper choice of glove material Low heeled shoes with fully covered uppers shall be worn at all times in the labo
21. be generally required by GHU and paid all fees assessed for the privilege of the discharge Q1 Any hazardous wastes as defined in rules published by the state or in EPA rules 40 CFR 261 or 22 Persistent pesticides and or pesticides regulated by the Federal Insecticide Fungicide Rodenticide Act FIFRA Pollutants substances of wastewater prohibited by this section shall not be processed or stored in such a manner that they could be discharged to the POTW Code 1960 15 201 Sec 82 207 Federal Categorical Pretreatment Standards The national categorical pretreatment standards found in 40 parts 405 through 471 are incorporated by reference Code 1960 15 202 Sec 82 808 State requirements State requirements and limitations on discharges to the POTW shall be met by all users which are subject to such standards in any instance in which they are more stringent than federal requirements and limitations or those in this article or other applicable code Code 1960 8 15 203 Sec 82 209 Local limits The following pollutant limits are established to protect against pass through and interference No person shall discharge wastewater contained in excess of the following daily maximum allowable limits Concentration Material mg l 4 35 Arsenic 0 33 Cadmium 1 23 Chromium 3 38 Copper 1 20 Cyanide 0 69 Lead 0 19 Mercury 4 74 Nickel 25 0 Oil and grease petroleum or
22. example heating perchloric acid working with pyrophorics conducting electrophoresis distillations extractions etc e Areference to the UAF Chemical Inventory Worksheet that should be attached as Appendix 10 Please call 6771 or 5487 if you do not have this worksheet e For each chemical used in the lab that is also highlighted in yellow on the Inventory Worksheet a Specific Laboratory Hazard Statement is required and should be included in this Appendix A blank form is on the next page e Specific procedures neutralizing noncontaminated acid wastes e e Specific clean up procedures for the different types of chemical in used in the lab This should also include where the clean up materials are stored e Training requirements of lab personnel Documents should record who will be the trainer topics to be covered and the frequency of the training Methods and frequency of conducting chemical inventories including who will perform them where the inventory is listed is kept and how the list will be updated e Policy of disposing materials when the shelf life has expired e Policy for storing chemicals that require special attention such as refrigeration freezing acid cabinets flammable cabinets etc e Specific procedures for operations that are to be conducted in fume hoods e Any procedures in place for transporting chemicals e Procedures during Emergency Power Outages as referenced in Appendix 8 e Any other laboratory s
23. lowest possible level No task is so important and no service so urgent that it cannot be done safely In keeping with this commitment this Chemical Hygiene Plan was developed as part of the Laboratory Safety Program The Chemical Hygiene Plan CHP is designed to protect laboratory personnel from potential hazerds associated with the use of chemicals Compliance is mandatory for all employees working in campus laboratories due to requirements of the Occupational Safety and Health Administration OSHA standard on Hazardous Chemicals In Laboratories While these regulations pertain specifically to employees provisions of the CHP may apply to students and visitors depending on their activities A variety of hazardous chemicals are used in small quantities in research and teaching laboratories creating a unique environment with a number of risks These chemicals may cause injury or damage because they are toxic flammable corrosive or reactive with water and other materials How these substances are handled will determine the degree of risk The objective of this CHP is to provide uniform requirements for safe use of potentially hazardous substances in UAF laboratories General standard operating procedures are outlined including work with select carcinogens reproductive toxins and highly acute e substances Specific standard operating procedures developed by each lab for operations posing a special hazard for example heating perchlor
24. production of materials on equipment previously used for the manufacturing use as a reactant chemical intermediate or component in a formulating process of tetra penta or hexachlorobenzene under alkaline conditions Discarded unused formulations containing tri tetra or pentachlorophenol or discarded unused formulations containing compounds derived from these chlorophenols This listing does not include formulations containing hexachlorophene synthesized from prepurified 2 4 Mi E as the sole component Residues resulting from the incineration or thermal treatment of soil contaminated with _ EPA hazardous waste nos F020 F021 F022 F023 F026 and F027 Wastewaters process residuals preservative drippage and spent formulations from wood preserving processes generated at plants that currently use or have previously used chlorophenolic formulations except potentially cross contaminated wastes that have had the F032 waste code deleted in accordance with Section 261 35 i e the newly promulgated equipment cleaning or replacement standards and where the generator does not resume or initiate use of chlorophenolic formulations This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and or pentachlorophenol Wastewaters process residuals preservative drippage and spent formulations from wood preserving processe
25. that is available at http www uaf edu safety or contact EH amp S RM Section for more information Used Oil Management Used oil management standards are found at 40 CFR Part 279 Used oil means any oil that has been refined from crude oil or any synthetic oil that has been used and as a result of such use is contaminated by physical or chemical impurities Used oils must be 13 e Collected in clean containers in good condition no severe rusting apparent structural defects or deterioration that are intact and do not leak containers of used oil including collection and transfer containers must be marked with the words Used Oil Adhesive Used Oil labels are available from EH amp S Risk Management Also identify containers of used oil with the Non Radioactive Hazardous Materials Transfer form and adhesive label e Used oil containers should remain closed at all times other than when adding or removing used oil e Solvents parts washer fluids carburetor cleaners or glycols must never be added to the used oil container Used Oil Spills Releases Notify EH amp S RM 40 CFR 279 22 d identifies the following cleanup steps in the event of a release of used oil a stop the release b contain the released used oil c clean up and mange properly the used oil and other materials and d if necessary repair or replace any leaking used oil storage containers or tanks prior to returning them to se
26. trifluoroethane ortho dichlorobenzene trichtorofluoromethane and 1 1 2 trichloroethane all spent solvent mixtures blends containing before use a total of ten percent or more by volume of one or more ofthe above halogenated solvents or those solvents listed in F001 F004 and F005 and still bottoms from the recovery of these spent solvents and spent solvent mixtures The following spent non halogenated solvents xylene acetone ethyl acetate ethyl benzene ethyl ether methyl isobutyl ketone n butyl alcohol cyclohexanone and methanol all spent solvent mixtures blends containing before use only the above spent nonhalogenated solvents and all spent solvent mixtures blends containing betore use one or more of the above nonhalogenated solvents and a total of ten percent or more by volume of one or more of those solvents listed in F001 F002 F004 and F005 and still bottoms from the recovery of these spent solvents and spent solvent mixtures The following spent nonhalogenated solvents cresols cresylic acid and nitrobenzene and the still bottoms from the recovery of these solvents all spent solvent mixtures blends containing before use a total of ten percent or more by volume of one or more of the above nonhalogenated solvents or those solvents listed in F001 F002 and F005 and still bottoms from the recovery of these spent solvents and spent solvent mixtures The following spent nonhalogenate
27. wastewater from the production of toxaphene Untreated wastewater from the production of 2 4 D Waste leaching solution from acid leaching of emission contro dust sludge from secondary lead smelting Distillation tar residues from the distillation of aniline based compounds inthe __ production of veterinary pharmaceuticals from arsenic or organo arsenic compounds Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from arsenic organo arsenic compounds Process residues from aniline extraction from the production of aniline Combined wastewaters generated from nitrobenzene aniline production Separated aqueous stream from the reactor product washing step in the production of chlorobenzenes Wastewater treatment sludge from the mercury cell process in chlorine production Column bottoms from product separation from the production of 1 1 j dimethylhydrazine UDMH from carboxylic acid hydrazides Condensed column overheads from product separation and condensed reactor vent gases from the production of 1 1 dimethylhydrazine from carboxylic acid hydrazides Spent filter cartridges from product purification from the product of 1 1 dimethylhydrazine from carboxylic acid hydrazides EPA HAZARDOUS WASTE CODES Continued Code Waste description K110 K111 K112 K113 K114 K115 K116 K117 K118 K123 K124
28. 0 one 2 3 dimethoxy EPA HAZARDOUS WASTE CODES tinued Code Waste desc ription P020 Dinoseb P020 Phenol 2 1 methylpropyl 4 6 dinitro P021 Calcium cyanide P021 Calcium cyanide Ca CN P022 Carbon disulfide P023 Acetaldehyde chloro P023 Chloroacetaldehyde P024 Benzenamine 4 chloro P024 P026 1 o Chlorophenyl thiour a P026 Thiourea 2 chlorophenyl P027 P028 P028 P029 P029 P030 P031 P031 p033 P033 P034 e P036 P036 3 Chloropropionitrile 3 chloro Benzene chloromethyl Benzyl chloride Copper cyanide Copper cyanide Cu CN Cyanides soluble cyanide salts not otherwise specified Cyanogen Ethanedinitrile Cyanogen chloride Cyanogen chloride CN CI 2 Cyclohexyl 6 dinitrophenol Phenol 2 cyclohexyl 4 6 dinitro Arsonous dichloride phenyl Dichlorophenylarsine Code P037 P037 P038 P038 P039 P039 P040 P040 P041 P041 P042 P042 P043 P043 P044 P044 P045 P045 P046 P046 P047 P047 Waste description 2 7 3 6 Dimethanonaphth 2 3 b oxirene 3 4 5 6 9 9 hexachloro 1a 2 2a 3 6 6a 7 7a octahydro 1aalpha 2beta 2aalpha 3beta 6beta 6aalpha 7beta Jaalpha Dieldrin Arsine diethyl Diethylarsine Disulfoton Phosphorodithioic acid O 0 diethyl S 2 ethylthio ethyl ester O O Diethyl O pyrazinyl phosphorothioate Phosphorothioic acid O O diethyl O pyraz
29. 171 172 173 177 and 178 e All shipments must be properly packaged and documented Hazardous waste shipments for small and large quantity generators must be documented on Uniform Hazardous Waste Manifests Shipments must be made by EPA permitted transporters Non hazardous waste manifests are typically used for shipments of materials from Conditionally Exempt Small Quantity Generators Waste manifests are completed by UAF s hazardous waste contractor 21 IATA ICAO Air Transport Regulations containing additional shipping information for air transportation is available from the Dangerous Goods Regulations This reference material includes such information needed to properly package and identify materials for air transport documentation on Shipper s Declaration for Dangerous Goods manifests It also contains specific information regarding air carrier limitations identifies items they will not accept for shipment Copies are available from the International Air Transport Association 2000 Peel Street Montreal Quebec Canada H3A 2R4 Please refer to the Dangerous Goods Regulations or contact EH amp S RM for more information Commercial drivers licenses with hazardous materials endorsements are required for transporting placarded amounts of hazardous materials wastes Contact EH amp S Risk Management x 5487 for more information 22 e UAF Hazardous Waste Self Audit Checklist Name Location Date
30. 2 Always use these chemicals in a hood with adequate air flow face velocity between 80 and 120 feet per minute or other containment device for procedures which may result in the generation of aerosols or vapors containing the substance 3 Use high efficiency particulate air HEPA filters or high efficiency scrubber systems to protect vacuum lines and pumps 4 Decontaminate designated areas before normal work is resumed there This includes contaminated equipment e 5 Remove any protective apparel place it in an appropriately labeled container and thoroughly wash hands forearms face and neck on leaving a designated area 6 Prepare wastes for disposal in accordance with Chemical Waste Disposal Guidelines 7 Do not wear jewelry when working in designated areas since decontamination of jewelry may be difficult or impossible Page 16 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan Appendix 1 e LABORATORY SPECIFIC STANDARD OPERATING PROCEDURE In addition to the Chemical Hygiene Plan you must include your own laboratory specific SOP s in this Appendix Examples of information to provide include e Specialized Laboratory Equipment Description Policies Procedures and Operating Requirements Such equipment includes but is not limited to Ventilation lasers Atomic Absorption Muffle furnaces etc e Specific standard operating procedures developed by each lab for operations posing a special hazard for
31. 3068 88 0 7440 43 9 56 23 5 305 03 3 56 75 7 13010 47 4 95 83 0 1333 82 0 15663 27 1 6358 53 8 11114 92 4 CATEGORY IARC 2Bs NTPAHC NTPAHC IARC 2Bs NTPAHC IARC 1 NTPHC NTPHC IARC 1 IARC 1 NTPHC IARC 1 NTPHC IARC 1 NTPHC IARC 2B IARC 2Bs IARC 1 NTPHC ARC 1 NTPHC IARC 1 NTPHC OSHA 13 IARC 2A IARC 3 NTPAHC IARC 2Bs IARC 1 NTPAHC IARC 1 NTPHC OSHA 13 IARC 2A NTPAHC IARC 1 NTPHC IARC 2Bs NTPAHC IARC 2B NTPAHC IARC 1 NTPHC IARC 2B IARC 1 IARC 1 NTPAHC IARC 2Bs NTPAHC IARC 1 NTPHC IARC 2A IARC 2Bs IARC 2B NTPHC University Of Alaska Fairbanks Chemical Hygiene Plan CHEMICAL NAME Creosote s p Cresidine Cupferron Cycasin Cyclophosphamide Dacarbazine Daunomycin DDT N N Diacetylbenzidine 2 4 Diaminoanisole sulfate 4 4 Diaminodiphenyl ether 2 4 Diaminotoluene Dibenz a h acridine Dibenz a jJacridine Dibenz a h anthracene Dibenzo a e pyrene Dibenzo a h pyrene Dibenzo a i pyrene Dibenzo q i pyrene Dibromochloropropane DBCP 3 3 Dichlorobenzidine Dichlorodiaminodiphenyl ether Diethyl sulfate Diethylstilbestrol Dihydrosafrole 3 3 Dimethoxybenzidine trans 2 Dimethylamino methylimino 5 2 5 nitro 2 furyl vinyl 1 3 4 oxadiazole 1 1 Dimethylhydrazine UDMH Dimethyl sulfate Dimethylaminoazobenzene Dimethylcarbamoyl chloride Dioxane Estrone Ethyl methanesulfonate EMS CAS NUMBER 8001 58 9 120 71 8 135 20 6 14901 08 7 50 18 0 4342 03 4 20830
32. 74 7721 and UAF EH amp S RM 907 474 5487 The caller should try to provide a detailed description of the spill including the name and approximate quantity of the chemical s involved Do not put yourself or others at risk to obtain this information The Fire Department is responsible for notifying UAF Environmental Health amp Safety Risk Management and or the Fairbanks Borough Hazardous Material Response Team as deemed necessary In all instances report chemical spills to the UAF Fire Department and complete the UAF Oil and Hazardous Substances Spill Reporting Form see attachment 4 More instructions and reporting information is included in the reporting form Cleanup of small chemical spills in which no fire or health hazards are present and no injuries have occurred can be done by department personnel Personnel doing the cleanup must be properly trained and have access to the appropriate personnel protective equipment necessary to cleanup the spill Do not attempt clean up the spill if it puts you or others at risk General Rules and Precautions include o Call 907 474 7721 to communicate as much information about the spill as possible If the material or hazards are unknown do not put yourself or others at risk to gain additional information Without putting yourself at risk attend to anyone who may have been contaminated by the spill o Avoid breathing vapors of the spilled material If available ensure that the fume hood
33. 8 Nitrogen dioxide P078 Nitrogen oxide NO PO81 1 2 3 Propanetriol trinitrate R 081 Nitroglycerine R P082 Methanimine N methyl N nitroso P082 N Nitrosodimethylamine P084 N Nitrosomethyivinylamine P084 Vinylamine N methyl N nitroso P085 Diphosphoramide octamethyl P085 Octamethylpyrophosphoramide P087 Osmium oxide OsO T 4 P087 Osmium tetroxide 22 poss T Oxabicyclo 2 2 1 heptane 2 3 dicarboxylic acid PO88 Endothall P089 Parathion P089 Phosphorothioic acid 0 0 diethyl 0 4 nitrophenyl ester P092 Mercury acetato O phenyl Code Waste description i P092 Phenylmercury acetate P093 Phenylthiourea P093 Thiourea phenyl P094 Phorate P094 Phosphorodithioic acid O O diethyl S ethylthio methyl ester P095 Carbonic dichloride P095 Phosgene P096 Hydrogen phosphide P096 Phosphine P097 Famphur P097 Phosphorothioic acid O 4 dimethylamino sulfonyl phenyl O O dimethyl ester P098 Potassium cyanide P098 Potassium cyanide K CN P099 Argentate 12 bis cyano C potassium P099 Potassium silver cyanide PIO Ethyl cyanide P101 Propanenttrile P102 2 1 01 P102 Propargyl alcohol P103 Selenourea P104 Silver Pl04 Silver cyanide Ag CN P105 Sodium azide P106 Sodium cyanide P106 Sodium cyanide Na CN Code P108 P108 P109 P109 110 P110 Pl P111 P112 P112 113 P113 Pil4 Pil4 115 115 116 116 P118
34. 81 3 50 29 3 613 35 4 39156 41 7 101 80 4 95 80 7 226 36 8 224 42 0 53 70 3 192 65 4 189 64 0 189 55 9 189 55 9 96 12 8 91 94 1 284 34 86 8 64 67 5 56 53 1 94 58 6 119 90 4 55738 54 0 57 14 7 77 78 1 60 11 7 79 44 7 123 91 1 53 16 7 62 50 0 CATEGORY IARC 2Bs IARC 2Bs NTPAHC NTPAHC IARC 2Bs NTPAHC IARC 1 NTPHC IARC 2B NTPAHC IARC 2Bs IARC 2B NTPAHC IARC 2Bs IARC 2Bs NTPAHC IARC 2Bs IARC 2Bs NTPAHC IARC 2Bs NTPAHC IARC 2Bs NTPAHC IARC 2B NTPAHC IARC 2Bs IARC 2Bs NTPAHC IARC 2Bs NTPAHC IARC 2Bs NTPAHC IARC 2Bs NTPAHC IARC 2B NTPAHC OSHA 13 IARC 2Bs IARC 2A NTPAHC IARC 1 NTPHC IARC 2Bs IARC 2B NTPAHC IARC 2Bs IARC 2Bs NTPAHC IARC 2A NTPAHC IARC 3 NTPAHC OSHA 13 IARC 2A NTPAHC IARC 2B NTPAHC IARC 2B NTPAHC IARC 2B University Of Alaska Fairbanks Chemical Hygiene Plan CHEMICAL NAME Ethylene dibromide EDB Ethylene thiourea Ethyleneimine Formaldehyde 2 2 Formylhydrazino 4 5 nitro 2 furyl thiazole Glycidylaldehyde Hexachlorobenzene Hexamethyl phosphoramide Hydrazine sulfate 1 1 Lasiocarpine Lead acetate Lead chromate VI oxide Lindane and mixed isomers Melphalan Merphalan Mestranol Methyl chloromethyl ether 4 4 Methylene bis 2 chloroaniline 4 4 Methylene bis N N dimethyl benzeneamine 4 4 Methylene bis 2 methylaniline Methylenedianiline Methylenedianiline dihydro chloride Methyl iodide Methyl methanesulfonate MMS Methyinitroanthraquinone
35. Alaska Fairbanks Chemical Hygiene Plan IV STANDARD OPERATING PROCEDURES General Rules A B Page 5 of 16 1 For chemicals they are working with all employees should know a the chemical s hazards as determined from a MSDS and other appropriate references b appropriate safeguards for using that chemical including personal protective equipment how to properly store the chemical when it is not in use proper chemical waste disposal procedures Appendix 6 proper personal hygiene practices appropriate procedures for emergencies including first aid evacuation routes and spill cleanup procedures Employees should avoid working alone Arrangements should be made between individuals working in separate laboratories outside of regular working hours to crosscheck each other periodically Experiments known to be hazardous should not be undertaken by an employee who is alone in the laboratory A 0cco Personal Hygiene 1 2 3 4 Wash promptly whenever a chemical has contacted your skin Flush for at least 15 minutes prior to seeking medical attention Avoid inhalation of chemicals Do not sniff to test chemicals Do not use mouth suction to pipette anything Pipetting aids must be used at all times Do not bring food including gum and candy beverages tobacco or cosmetic products into chemical storage or use areas Eating drinking and applying cosmetics is allowed in designated areas only Smoking is prohibit
36. Checklist ecce 23 Attachments gt ther Xx enis e neat Ga 25 University of Alaska Fairbanks Environmental Health amp Safety Risk Management Introduction to Hazardous Waste Management Background In Alaska hazardous wastes are regulated by the Environmental Protection Agency under the authority of the Resource Conservation and Recovery Act RCRA Hazardous waste regulations are found in the Code of Federal Regulations CFR at 40 CFR Parts 260 282 These regulations identify e Cradle to grave responsibilities for generators of hazardous waste e Criteria for the identification and listing of hazardous wastes e Enforceable standards applicable to hazardous waste generators transporters and treatment storage and disposal facilities Based upon the volume and type of wastes generated hazardous waste generators are classified into three categories e Conditionally Exempt Small Quantity Generators CESQG e Small Quantity Generators SQG e Large Quantity Generators LQG Conditionally Exempt Small Quantity Generators A generator is a conditionally exempt small quantity generator if the facility generates no more than 100 kg kilograms of RCRA hazardous waste or 1 kilogram of acutely hazardous waste P listed waste in a calendar month One kilogram equals approximately 2 2 pounds Wastes accumulated on site shou
37. Corrosive C Reactive C Pyrophoric C Water Reactive L Peroxide Former Special Precautions Potential Routes of Exposure check all that apply C Inhalation LI Skin Absorption O Ingestion Injection Other Personal Protective Equipment check all that apply C Gloves specify type L Splash goggles L Safety glasses Face shield C Lab coat C Apron Rubber boots C Half face respirator Full face respirator C Powered air purifying respirator C Supplied air respirator C Self contained breathing apparatus SCBA Other PPE please describe University Of Alaska Fairbanks Chemical Hygiene Plan Specify cartridge type e Please notify UAF Environmental Health Safety and Risk Management if respiratory protection is needed Medical examinations and fit tests are required for most respirator users Engineering Ventilation Controls 1 Fumehood use only L Local exhaust ventilation required _ Glove box use required L Glove bag use required Biosafety Cabinet use only identify biosafety cabinet class Class Class II Class III C Ground fault interrupter required L Grounding required C Shielding required C Relief valve required C Vacuum breakers required L Back flow preventers required C Spill containment required L Leak detection required C Monitoring required Alarm s required Other please describe e Special Handling Procedures and Storage Requirem
38. Cresol D025 p Creso EPA HAZARDOUS WASTE CODES Code D026 D027 D028 D029 D030 D031 D032 D033 D034 D035 D036 D037 D038 D039 D040 D041 D042 D043 Waste description Cresol 1 4 Dichlorobenzene 1 2 Dichloroethane 1 1 Dichloroethylene 2 4 Dinitrotoluene Heptachlor and its epoxide Hexachlorobenzene Hexachlorobutadiene Hexachloroethane Methyl ethyl ketone Nitrobenzene Pentachlorophenol Pyridine Tetrachloroethylene Trichlorethylene 2 4 5 Trichlorophenol 2 4 6 Trichlorophenol Vinyl chloride HAZARDOUS WASTE FROM NONSPEGINIG SOURCES SEE 40 CFR 261 31 F001 The following spent halogenated solvents used in degreasing tetrachloroethylene trichlorethylen methylene chloride 1 1 1 trichloroethane carbon tetrachloride and chlorinated fluorocarbons all spent solvent mixtures blends used in degreasing containing before use a total of ten percent or more by volume of one or more of the above halogenated solvents or those solvents listed in F002 F004 and F005 and still bottoms from the recovery of these spent solvents and spent solvent mixtures EPA HAZARDOUS WASTE CODES Continued Code Waste description Code Waste description F002 F003 F004 F005 The following spent halogenated solvents tetrachloroethylene methylene chloride trichloroethylene 1 1 1 trichloroethane chlorobenzene 1 1 2 trichloro 1 2 2
39. Ethanediamine N N dimethy N 2 pyridinyl N 2 thienylmethyl Methapyrilene Carbonochloridic acid methyl ester LT EPA HAZARDOUS WASTE CODES Continued Code U156 U157 U157 U158 U158 0159 0159 0160 0160 0161 0161 0161 0162 0162 0163 0163 0164 0164 0165 0166 0166 0167 0167 0168 0168 0169 20169 10170 Waste description Methyl chlorocarbonate 1 T 3 Methylcholanthrene Benz j aceanthtylene 1 2 dihydro 3 methyl 4 4 Methylenebis 2 chloroaniline Benzenamine 4 4 methylenebis 2 chloro 2 Butanone 1 T Methyl ethyl ketone 2 Butanone peroxide R T Methyl ethyl ketone peroxide R T 4 Methyl 2 pentanone I Methyl isobutyl ketone I Pentanol 4 methyl 2 Propenoic acid 2 methyl methyl ester T Goo em eng Methyl methacrylate LT Guanidine N methyl N nitro N nitroso MNNG 4 1H Pyrimidinone 2 3 dihydro 6 methyl 2 thioxo Methylthiouracil Naphthalene 1 4 Naphthalenedione 1 4 Naphthoquinone 1 Napthalenamine alpha Naphthylamine 2 Napthalenamine beta Naphthylamine Benzene nitro Nitrobenzene 17 p Nitrophenol LT Code Waste description U170 0171 0171 0172 0172 0173 10173 70174 0174 0176 0176 0177 0177 0178 0178 0179 0179 0180 0180 UISI U181 0182 0182 0183 0183 0184 0184 0185 0185 Phenol 4 nitro 2 Nitropropane 1 T Propane 2 nitro 1 1 But
40. L Materials which require monitoring under these conditions are listed in OSHA Regulations If an employee would like to have an exposure assessment conducted the CHO should be contacted Exposure assessments and monitoring may be conducted by the CHO Facility Services or a UAF Industrial Hygienist Documentation of exposure monitoring shall be kept and maintained as part of each employee s personnel record MEDICAL CONSULTATIONS AND EXAMINATIONS Employees shall be provided an opportunity to receive medical attention including any related follow up examinations at UAF s expense under the following circumstances A individual develops signs or symptoms associated with exposure to hazardous chemicals in the laboratory B Exposure monitoring reveals an exposure level routinely above the action level or PEL for an OSHA regulated substance for which there are exposure monitoring and medical surveillance requirements C Anaccident such as a spill leak equipment failure or explosion results in possible over exposure to hazardous chemicals The is responsible for establishing and maintaining an accurate record of any medical consultations and examinations provided to an employee SELECT CARCINOGENS REPRODUCTIVE TOXINS HIGHLY ACUTE TOXINS The procedures described in this section are mandatory when performing laboratory work with greater than 10 mg or 100 mL of any carcinogen reproductive toxin or substance that has a h
41. Methylnitronitrosoguanidine Methylazoxymethanol acetate Methylthiouracil Metronidazole Michler s ketone Mirex Mitomycin C Monocrotaline Mustard gas alpha Naphthylamine CAS NUMBER 106 93 4 964 45 7 15 15 64 50 00 0 3570 75 0 765 34 4 118 74 1 680 31 9 10034 93 2 303 34 4 301 04 2 18454 12 1 58 89 9 148 82 3 531 76 0 72 33 3 107 30 2 101 14 4 101 61 1 838 88 0 101 77 9 13552 44 8 74 88 4 66 27 3 129 15 7 70 25 7 592 62 1 56 04 2 443 48 1 90 94 8 2385 85 5 50 07 7 315 22 0 505 60 2 134 32 7 CATEGORY IARC 2B NTPAHC IARC 2B NTPAHC OSHA 13 IARC 2B NTPAHC IARC 2B IARC 2B IARC 2B NTPAHC IARC 2B NTPAHC NTPAHC IARC 2B NTPAHC IARC 1 NTPHC NTPAHC IARC 1 NTPHC IARC 2B IARC 2B NTPAHC OSHA 13 IARC 2B NTPAHC NTPAHC IARC 2A NTPAHC NTPAHC IARC 3 NTPAHC IARC 2A IARC 2B IARC 2A IARC 2B IARC 2B IARC 2B NTPAHC NTPAHC IARC 2B NTPAHC IARC 2B IARC 2B IARC 1 NTPHC OSHA 13 o University Of Alaska Fairbanks Chemical Hygiene Plan CHEMICAL NAME CAS NUMBER CATEGORY beta Naphthylamine 2 Naphthylamine 91 59 8 S T NTPHC OSHA 5 Nitroacenaphthene 602 87 9 IARC 2B 4 Nitrobiphenyl 92 93 3 OSHA 13 5 Nitro o anisidine 99 59 2 NTPAHC N Nitrosodimethylamine 62 75 9 OSHA 13 beta Propiolactone 57 57 8 OSHA 13 IARC International Agency for Research on Cancer Group 1 The agent mixture is carcinogenic to humans The exposure circumstances entail expos
42. P118 P119 P119 P120 P121 P121 Waste description Strychnidin 10 one amp salts Strychnine amp salts Tetraethyldithiopyrophosphate Thiodiphosphoric acid tetraethy ester Plumbane tetraethyl Tetraethyl iead Diphosphoric acid tetraethyl ester Tetraethyl pyrophosphate Methane tetranitro R ee Thallic oxide Thallium oxide Selenious acid dithallium 1 salt Thallium I selenite Sulfuric acid dithallium 1 salt Thallium I sulfate Hydrazinecarbothioamide Thiosernicarbazide Methanethiol trichloro Trichloromethanethiol vanadate Vanadic acid ammonium salt Vanadium oxide V O Vanadium pentoxide Zinc cyanide Zinc cyanide Zn CN EPA HAZARDOUS WASTE CODES Code P122 P123 P127 P127 P127 P128 P128 P185 P188 P189 P189 P190 P191 P191 P192 P192 P194 P194 P196 Continued Waste description Zinc phosphide Zn P when present at concentrations greater than 1096 R T Toxaphene 7 Benzofuranol 2 3dihydro 2 2 dimethyl methylcarbamate Carbofuran 7 Benzufuranol 2 3 dihydro 2 2 dimethyl methylcarbamate Phenol 4 dimethylamino 3 5 dimethyl methylcarbamate ester Mexacarbate 1 3 Dithiolane 2carboxaldehyde 2 4 dimethyl O methylamino carbonyl oxime Physostigmine salicylate Carbosulfan Carbamic acid dibutylamino thio methyl 2 3 dihydro 2 2dimethyl Ilbenzofurany este
43. TOXIC WASTES SEE 40 CFR 261 33 FOR AN ALPHABETIZED LISTING 2 3 4 6 Tetrachlorophenol 2 4 5 T 2 4 5 Trichlorophenol 2 4 6 Trichlorophenol Acetic acid 2 4 5 trichlorophenoxy Pentachlorophenol See Phenol 2 3 4 6 tetrachloro F027 Phenol 2 4 5 trichloro Phenol 2 4 6 trichloro Phenol pentachloro Propanoic acid 2 2 4 5 trichlorophenoxy Silvex 2 4 5 TP 0001 Acetaldehyde 1 0001 Ethanal 1 002 2 Propanone 1 0002 s A celos 1 0003 Acetonitrile LT U004 Acetoahedok U004 Ethanone 1 Code 17005 0005 0006 0007 0007 008 0008 0009 0009 0010 voll 0012 0012 0014 0014 0015 0015 0016 0017 0017 Waste description 2 Acetylaminofluorene Acetamide N 9H fluoren 2 yl Acetyl chloride CR T 2 Propenamide Acrylamide 2 Propenoic acid 1 Acrylic acid 2 Propenenitrile Acrylonitrile Azirino 2 3 3 4 1 2 ajindole 4 7 dione 6 amino 8 aminocarbonyl oxy methyl 1 12 2 8 8a 8b hexahydro 8a methoxy 5 methyl 1aS 1aalpha 8beta 8aalpha 8balpha Mitomycin C 1H 1 2 4 Triazol 3 amine Amitrole Aniline 1 T Benzenamine LT Auramine Benzenamine 4 4 carbonimidoylbis N N dimethyl Azaserine L Serine diazoacetate ester Benzlcjacridine Benzal chloride Benzene dichloromethyl Benz a anthracene Benzene 1 T Benzenesulfonic acid ch
44. The following a PARTIAL list of known or potential carcinogens CHEMICAL NAME CAS NUMBER CATEGORY 2 Acetylaminofluorene 53 96 3 NTPAHC OSHA 13 Acrylonitrile 107 13 1 IARC 2B NTPAHC Actinimycin D 50 76 0 IARC 3 Adriamycin 23214 928 IARC 2A NTPAHC Aflatoxins 1402 68 2 IARC 1 NTPHC 2 Aminoanthraquinone 117 79 3 NTPAHC o Aminoazotoluene 97 56 3 IARC 2Bs 4 Aminodiphenyl 92 67 1 2 Amino 5 5 nitro 2 furyl 1 3 4 thiadiazole 712 68 5 IARC 2Bs Amitrole 61 82 5 IARC 2B NTPAHC University Of Alaska Fairbanks Chemical Hygiene Plan CHEMICAL NAME O Anisidine O Anisidine hydrochloride Aramite Arsenic Arsenic compounds Arsenic pentoxide Arsenic trioxide Arsenic inorganic compounds Asbestos Auramine Azaserine Azathioprine Benzene Benzidine Benzo a pyrene Benzo b fluoranthene Benzotrichloride Benzyl violet Beryllium and compounds Bis chloromethyl ether Bis chloroethyl nitrosourea 1 4 Butanediol dimethane sulphonate B butyrclactone Cadmium and compounds Carbon tetrachloride Chlorambucil Chloramphenicol Chlorinated toluenes 1 2 Chloroethyl 3 cyclo hexyl 1 nitrosourea 4 Chloro o phenylenediamine Chromium hexavalent compounds Cisplatin Citrus red no 2 Cobalt chromium alloy CAS NUMBER 90 04 0 134 29 2 140 57 8 7440 38 2 7440 38 2 1303 28 2 1327 53 3 7440 38 2 492 80 8 115 02 6 446 86 6 71 43 2 92 87 5 50 32 8 205 99 2 98 07 7 1694 09 3 7440 41 7 542 88 1 154 93 8 55 98 1
45. Transfer of flammable liquids from 5 gallon containers or less to smaller containers shall be conducted in a laboratory fume hood or an approved flammable liquid storage room F Reactive Chemicals A reactive chemical is one that 1 Fits the OSHA definition of unstable in 1910 1450 b Unstable reactive means a chemical which in the pure state or as produced or transported will vigorously polymerize decompose condense or will become self reactive under conditions of shocks pressure or temperature 2 Is ranked by the National Fire Protection Association NFPA as 3 e or 4 for reactivity 3 Is identified by the Department of Transportation DOT as An oxidizer b organic peroxide or Aclass A B or C explosive 4 Violently reacts with exposure to water or air Handle reactive chemicals with all proper safety precautions This includes designating a separate storage area monitoring periodically for degradation and using appropriate personal protection G Corrosive Chemicals 1 Materials are classified as corrosive if they a capable of rapidly eroding building materials or metals or b irritate or destructively attack organic tissues such as skin eyes lungs and stomach Page 3 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan Examples of commonly used chemicals that have corrosive properties are acetic anhydride bromine chlorine fluorine glacial acetic
46. Waste Management Table of Contents RACK FOU M T 3 Conditionally Exempt Small Quantity Generators 3 Small Quantity 4 Large Quantity Generators ssssssssssssseseeseeseeeeneme eene enne nennen rennen 4 RCRA Hazardous Waste Criteria cesses eene eene eene ener 4 Characteristic wastes i eei tei a ve viec tas net one Pg d zio 4 Ejsted Wastes uod onere vxo ars c ove 7 CESQG Hazardous Waste Management 8 The Eight Primary RCRA Concerns sssssssssssseseeeeeee nennen nennen nnns 9 General rules for proper management of surplus hazardous materials and wastes 10 Waste Determination outil ti ee e EY etd 11 Hazmat Facility chemical check in procedures 12 Record KeeDifiq i ed ha edo eu dee 12 aire ceria wean scien ne Des ble ER maa 13 Empty Contaillers ee ee stt ta aus 13 Bio Hazardous Materials oec Gaetano edere isa 13 Used Oil Management oxic 5 vete i ceto Le e especies 13 Universal Waste Batteries Information 15 Backg
47. acid hydrochloric acid hydrofluoric acid nitric acid potassium hydroxide sodium hydroxide sulfuric acid Safe handling procedures will vary with each operation and the type and concentration of the corrosive chemical Page 9 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan H Page 10 of 16 Acids and Bases e 1 following general guidelines should be followed for procedures involving acids and bases a b C Never pour water into acid Slowly add the acid to the water and stir Open bottles or carboys slowly and carefully wearing protective equipment to guard hands face and body OSHA requires suitable facilities such as a safety shower and eyewash to be located within the work area The American National Standards Institute ANSI recommends that the safety shower and eyewash be within 100 feet of the work area for quick drenching or flushing of the eyes and body Eyewash stations and showers should be tested annually by Facility Services Procedures requiring the use of concentrated acids and bases must be conducted in a fume hood Never mix acid wastes with other materials such as solvents metal contaminated solutions etc Noncontaminated acid wastes can be easily disposed by neutralization Specific procedures are outlined in Appendix 1 When disposable containers are completely emptied of their contents flush them thoroughly with water before e throwing them away Never dispose of
48. acids or bases in the sanitary sewer system i e down the drain until neutralized pH 6 0 8 0 Neutralization may be conducted in the laboratory when included as part of an experiment and should be conducted in a fume hood The solution should then be poured slowly down the drain with copious amounts of water i e leave the water running for approximately 5 minutes Contact EHS amp RM Hazmat Section 474 5487 for assistance with disposal of large quantities more than 1 gallon or 1 2 pound of acids and bases Each laboratory should have access to a spill kit that includes acid and base neutralizer follow Spill Response Procedures in section V B Never use combustible organic materials sawdust excelsior wood scraps and shavings paper rags or burlap bags to absorb or cleanup spillage University Of Alaska Fairbanks Chemical Hygiene Plan RECEIVI 1 2 7 8 l Compressed Gas Cylinders Use of compressed gases in the laboratory requires anticipating chemical physical and health hazards Cylinders that are knocked over or dropped can be very dangerous If a valve is knocked off the cylinder can become a lethal projectile Accidental releases may result in an oxygen depleted atmosphere or adverse health effects In short improper handling and use can cause structural damage severe injury and possibly death The following guidelines will help ensure safe handling use and storage of compressed gas cylinde
49. anamine N butyl N nitroso N Nitrosodi n butylamine Ethanol 2 2 nitrosoimino bis N Nitrosodiethanolamine Ethanamine N ethyl N nitroso N Nitrosodiethylamine N Nitroso N ethylurea Urea N ethyl N nitroso N Nitroso N methylurea Urea N methyl N nitroso Carbamic acid methylnitroso ethyt ester N Nitroso N methylurethane N Nitrosopiperidine Piperidine 1 nitroso N Nitrosopyrrolidine Pyrrolidine 1 nitroso 5 Nitro o toluidine Benzenamine 2 methyl 5 nitro 1 3 5 Trioxane 24 trim thyl Paraldehyde Benzene pentachloro Pentachlorobenzene Ethane pentachloro Pentachloroeihane Benzene pentachloronitro Pentachloronitrobenzene PCNB HAZARDOUS WASTE CODES Continued Code Waste description E MMC EC C a RR E 0186 0186 0187 0187 0188 0189 0189 0190 0190 0191 019 0192 0193 0193 0194 0194 0196 0197 0197 0200 0200 U201 o 0202 0202 0203 0192 1 3 Pentadiene 1 1 Methylbutadiene I Acetamide N 4 ethoxyphenyl Phenacetin Phenol Phosphorus sulfide R Sulfur phosphide R 1 3 Isobenzofurandione Phthalic anhydride 2 Picoline Pyridine 2 methyl Benzamide 3 5 dichloro N 1 2 propynyl Pronamide 1 2 Oxathiolane 2 2 dioxide 1 3 Propane sultone 1 Propanamine 1 T n Propylamine 1 7 Pyridine 2 5 Cyclohexadiene 1 4 dione p Benzoquinone Reserpine Yohimban
50. ar device when a Procedures call for work with toxic substances which are volatile i e evaporate at normal temperature and pressure or b There is a possibility the action level or PEL will be exceeded 2 The protection provided by laboratory fume hoods is dependent upon two important factors i a proper use of the hood and b maintenance of adequate airflow through the hood 3 The way the hood is used will determine the degree of protection it will provide Each employee is responsible for implementing the following work practices when using a hood a Continually monitor air being drawn into the hood This can be done by attaching a light weight strip of paper to the bottom of the sash b Operate the hood at a sash position that will provide splash protection for the user e g 10 12 inch opening for hoods with vertical sliding up and down sashes and the sashes closed as much as possible for continuous air flow hoods with horizontal sliding left and right sashes This helps to ensure optimum protection when conducting operations in the hood c Avoid using the hood for storage of bottles and equipment especially along the back wall Any apparatus that must be housed within the hood should fit completely inside the hood Elevate the apparatus on blocks at least 2 inches e Page 12 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan B Page 13 of 16 off the bench top to allow air to flow freel
51. ate Ethanol 2 2 oxybis dicarbamate Ethanamine N diethyl Triethylamine 2 4 6 Tribromophenol Thiophanate methyl Carbamic acid 1 2 phenylenebis iminocarbonothioyl bis dimethy ester Ethanimidothioci acid N N thiobis methylimino carbonyloxy bis dimethyl ester Propoxur Phenol 2 1 methylethoxy methylcarbamate Prohibited Sewer Discharge Standards amp Supplementary Discharge Limitations Golden Heart Utilities Wastewater Utility 4247 Peger Road Fairbanks Alaska 99709 5468 Chapter 82 Article II Division 6 Utilities Wastewater Treatment Regulations General Requirements Sec 82 206 Prohibited discharge standards a General prohibitions No usei shall introduce or cause to be introduced into the GHU wastewater collection system or into the POTW any pollutant or wastewater which causes pass through or interference These general prohibitions apply to all users of the POTW whether or not they are subject to categorical pretreatment standards or any other national state or local pretreatment standards or requirements b Specific prohibitions No use shall introduce or cause to be introduced into the GHU wastewater collection system or into the POTW the following pollutants substances or wastewater 1 2 3 4 5 6 7 Pollutants which create a fire or explosive hazard in the GHU wastewater collection system and or the POTW including but no
52. aterials on equipment previously used for the production or manufacturing use as a reactant chemical intermediate or component in a formulating process of tri and tetrachlorophenols This listing does not include wastes from equipment used only for the production or use of hexachlorophene from highly purified 2 4 5 trichlorophenol Process wastes including but not limited to distillation residues heavy ends tars and reactor clean out wastes from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five with varying amounts and positions of chlorine substitution This listing does not include wastewaters wastewater treatment sludge spent catalysts and wastes listed in Sections 261 31 or 261 32 Condensed light ends spent filters and filter aids and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes These chlorinated aliphatic hydrocarbons are those having carbon chain Jengths ranging from one to and including EPA HAZARDOUS WASTE CODES Continued Code Waste description F027 F028 F032 F034 five with varying amounts and position of chlorine substitution Wastes except wastewater and spent carbon from hydrogen chloride purification from the
53. ation of Hazardous Materials Waste Regulations governing the transportation of hazardous materials by commercial vehicle are found in 49 CFR 171 178 All persons who package handle offer for transport transport or receive hazardous materials shipments must attend and complete documented Hazardous Materials Transportation training per Subpart H of 49 CFR If you are not a certified shipper please contact EH amp S RM for assistance with hazardous materials shipping needs and for the use of UAF s 24 hour emergency phone number UAF Fire amp Police Dispatch Center 474 7721 A provision for use of this number is that Dispatch must know the pertinent details of the shipment This can be accomplished by faxing a copy of the bill of lading prior to or at the time of the shipment to Dispatch fax 474 7377 A hazardous materials shipment request form is available at the EH amp S RM website located at www uaf edu safety e The DOT Hazardous Materials Table Special Provisions Hazardous Material Communication Requirements and Emergency Response Information requirements are located in 49 CFR Part 172 The Department of Transportation hazardous materials shipping regulations are available at http www myregs com dotrspa e General requirements for shipments and packagings are found in 40 CFR Part 173 Prior to transport materials must be properly packaged and labeled in accordance to DOT transportation regulations as found in 49 CFR Parts 107
54. batteries are completely discharged before segregation in the appropriate container Labeling requirements Universal waste batteries i e each battery or a container in which batteries are contained must be labeled or marked clearly with any on of the following phrases Universal Waste Battery ies or Waste Battery ies or Used Battery ies Accumulation time limitations A small quantity handler of universal waste may accumulate universal waste for no longer than one year from the date the universal waste is generated or received from another handler The 15 handler must be able to demonstrate the length of time that the universal waste has been e accumulated from the date it becomes a waste or was received Employee training A small quantity handler of universal waste must inform all employees who handle or have responsibility for managing universal waste The information must describe proper handling and emergency procedures appropriate to the type s of universal waste handled at the facility Responses to releases A small quantity handler of universal wastes must immediately contain any releases of universal waste and other residues from universal wastes Determine whether or not any of the material resulting from the release is hazardous waste and if so compliance with all applicable requirements of 40 CFR parts 260 272 is required Standard Operating Procedures e Call EHS amp RM Hazmat Secti
55. be easily decontaminated Yes No N A 28 Biological safety cabinets are installed is such a manner that fluctuations of the room air supply and exhaust air do not cause biological safety cabinets to operate outside their parameters for containment The biological cabinets are located away from doors from windows that can be opened from heavily traveled laboratory areas and from other potentially disruptive equipment so as to maintain the biologica safety cabinets air flow parameters for containment Yes No N A 29 An eyewash station is readily available __ No N A 30 Illumination is adequate for all activities avoiding reflections and glare that could impede e vision K Hazardous Waste Yes No N A 1 Is all lab personnel aware of how to have hazardous waste picked up Yes No N A 2 Is the disposal of hazardous substances down the drain or in the normal trash prevented Yes No N A 3 Are lab personnel instructed to not dispose of chemicals by evaporation in the fumehood Yes No N A 4 Are the proper containers obtained and used for storing hazardous waste Yes No N A 5 Are all containers properly marked to identify their contents and constituent concentrations and labeled with the UAF Non Radioactive Transfer Request tag Yes No N A 6 Is the satellite accumulation start date identified on the waste container Yes No N A 7 Are all containers kept tightly closed except when ad
56. be placed in a sealed container or in a cardboard box lined with two polyethylene bags Containers storing hazardous waste must be kept closed except when adding or removing contents Any leaks or spills must be promptly reported to your departmental Chemical Hygiene Officer CHO Lab Manager or Safety Officer They in turn should notify the appropriate parties including UAF Dispatch 907 474 7721 and Environmental Health amp Safety Risk Management 907 474 5487 Attach information to the container to identify any special known or suspect hazard information Hazardous materials should never be simply abandoned at hazardous material collection areas or accumulation sites Waste Determination Upon receipt of the Non Radioactive Hazardous Materials Transfer Request UAF EH amp S RM s Hazmat Section will review the regulatory requirements to establish whether or not the material is a RCRA regulated waste Non regulated potentially hazardous waste Useable surplus material Recyclable material Hazardous waste that can safely be consolidated with other chemically compatible waste streams to reduce over all disposal costs ie consolidated non flammable halogenated liquids e Non hazardous waste e TSCA regulated waste 11 o An inventory of materials for disposal will be compiled and submitted to the university disposal contractor approximately three weeks prior to the anticipated pick up RCRA regulated waste
57. bisdithiocarbamic acid and its salts EPA HAZARDOUS WASTE CODES Continued Code Waste description K126 Baghouse dust and floor sweepings in K131 K132 K136 K140 o K142 K143 K144 e K147 milling and packaging operations from production or formulation of ethylenebisdithiocarbamic acid and its salts Wastewater from the reactor and spent sulfuric acid from the acid dryer from the production of methyl bromide Spent absorbent and wastewater separator solids from the production of methyl bromide Still bottoms from the purification of ethylene dibromide in the production of ethylerie dibromide via bromination of ethene Floor sweepings off specification product and spent filter media from the production of 2 4 6 tribromophenol Process residues from the recovery of coal tar including but not limited to tar collecting sump residues from the production of coke from coal or the recovery of coke by products produced from coal This listing does not include K087 decanter tank sludge from coking operations Tank storage residues from the production of coke from coal or from the recovery of coke by products from coal Process residues from the recovery of light oil including but not limited to those generated in stills decanters and wash oil recovery units from the recovery of coke by products produced from coal Wastewater sump residues from light oil refining inclu
58. boratory including but not limited to Material Safety Data Sheets MSDS s Training Employee training shall include 1 The physical and health hazards associated with chemicals stored and used in their work area 2 contents of this Chemical Hygiene Plan 3 Methods and observations that may be used to detect the presence or release of a hazardous chemical e g exposure monitoring conducted by the CHO visual appearance or odor of hazardous chemicals when being released etc 4 The measures employees can take to protect themselves from these hazards including specific procedures the employer has implemented to protect employees from exposure to hazardous chemicals such as appropriate work practices emergency procedures and personal protective equipment to be used Ili PRIOR APPROVAL CIRCUMSTANCES Employees must obtain prior approval to proceed with a laboratory task from the PI or his her designee when moo wp Fage 4 of 16 Radioactive materials will be used Recombinant DNA or biological material of Biosafety Level 3 or greater will be used It is likely that exposure limit concentrations could be exceeded or that other harm is likely There is failure of any equipment used in the process especially of safeguards such as chemical fume hoods Members of the laboratory staff become ill suspect that they or others have been exposed or otherwise suspect a failure of any safeguards e University Of
59. bsf methoxy Methoxychlor 2H 1 Benzopyran 2 one 4 hydroxy 3 3 oxo I phenyl butyl amp salts when present at concentrations of 0 394 or less Warfarin amp salts when present at concentrations of 0 3 or less Zinc phosphide Zn P when present at concentrations of 10 or less Benomyl Bendiocarb 1 3 Benzodioxol 4 ol 2 2 dimethyl methyl carbamate Carbaryl 1 Naphthalenol methylcarbamate Barban Carbamic acid 3 chlorophenol 4 chloro 2 butyny ester Benzenamine 2 methyl Code U328 U353 U353 U359 U359 U364 U364 U367 U367 U372 U372 U373 U373 U387 U387 U389 Waste description o Toluidine Benzenamine 4 methyl p Toluidine Ethanol 2 ethoxy Ethylene glyco monoethyl ether 1 3 Benzodioxol 4ol 2 2 dimethyl Bendiocarb phenol 7 Benzofuranol 2 3 dihydro 2 2 dimethyl Carbofuran phenol Carbamic acid 1H benzimidazol 2 yl methyl ester Carbendazim Carbamic acid phenyl 1 methylethyl ester Propham Carbamothiocic acid dipropyl S phenylmethyl ester Prosulfocarb Triallate EPA HAZARDOUS WASTE CODES Continued Code Waste description U389 U394 U394 U395 U395 10404 00404 10408 0409 0409 0410 U4II U411 Carbamothiocic acid bis 1 methylethyl S 2 3 3 trichloro 2propenyl ester Ethanimidothioic acid 2 dimethylamino _N hydroxy 2 oxo methyl ester A2213 Diethylene glycol dicarbam
60. ch tops floors fume hoods or in aisles Each laboratory must have a puncture resistant e g cardboard container specifically designated for glassware disposal At the end of each workday the contents of all unlabeled containers are to be considered waste and disposed of appropriately Collection containers for wastes must be clearly labeled including hazard identification All work areas especially laboratory bench tops should be kept clear of clutter All aisles corridors stairs and stairwells shall be kept clear of chemicals equipment supplies boxes and debris Food and drink for human consumption shall not be kept in the same refrigerator used to store chemicals and laboratory samples Eating and office areas must be clearly separated from laboratory and chemical storage areas Empty containers shall be treated in the following manner a For water soluble solvents triple rinse deface the label relabel as Empty and dispose with normal trash b For non water soluble solvents triple rinse using a solvent capable of removing the chemical ALL rinsate must be collected in a hazardous waste disposal container Deface the label relabel as Empty and dispose with normal trash D Protective Clothing and Equipment 1 2 Page 6 of 16 Carefully inspect all protective equipment prior to use Do not use defective equipment Eye protection safety glasses chemical resistant goggles or face shield shall be worn
61. change without detonating e Itreacts violently with water e It forms potentially explosive mixtures with water e When mixed with water it generates toxic gases vapors or fumes in a quantity sufficient to present a danger to human health or the environment e tisacyanide or sulfide bearing waste which when exposed to pH conditions between 2 and 12 5 can generate toxic gases vapors or fume in a quantity sufficient to present a danger to human health or the environment e tis capable of detonation or explosive reaction if it is subjected to a strong initiating source or if heated under confinement e tis readily capable of detonation or explosive decomposition or reaction at standard temperature and pressure e Itis a forbidden explosive as defined in 49 CFR 173 51 or a Class A explosive as defined in 49 CFR 173 53 or a Class B explosive as defined in 49 CFR 173 88 D004 D043 TCLP Toxicity Characteristic Leaching Procedure wastes contain the following contaminants at concentrations equal to or in excess of the maximum concentration limits as defined in 40 CFR 261 24 Suspect TCLP waste materials are analyzed by EPA Method 1311 TCLP analytes consist of 8 metals 6 pesticides and 26 organic compounds EPA HW __ Contaminant Regulatory Level mg L D004 Arsenic 5 0 D005 Barium 100 0 D018 Benzene 0 5 D006 Cadmium 1 0 D019 Carbon tetrachloride 0 5 D020 Chlordane 0 03 D021 Chlorobenzene 100 0 D022 Chloroform 6 0 D007 Chrom
62. ctyl phthalate gt 1 4 Diethyleneoxide D 1 4 Dioxane 1 2 Diphenylhydrazine Hydrazine 1 2 diphenyl 1 Propanimine N propyl 1 Dipropylamine I 1 Propanamine N nitroso N propyl Di n propylnitrosamine WASTE CODES Code 0112 Utl2 0113 0113 0114 0114 0115 116 0116 0117 117 118 0119 0119 0120 0121 0121 0122 00123 10124 0124 4125 U125 U126 126 2727 L Waste description Acetic acid ethyl ester T Ethyl acetate 1 2 Propenoic acid ethyl ester 0 Ethyl acrylate I Carbamodithioic acid 1 2 ethanediylbis salts amp esters Ethylenebisdithiocarbamic acid salts amp esters Ethylene oxide 1 T Oxirane 2 Imidazolidinethione Ethylenethiourea Ethane 1 1 oxybis 1 Ethyl ether 1 2 Propen ic acid 2 methyl ethyl ester Ethyl methacrylate Ethyl methanesulfonate Methanesulfonic acid ethyl ester Fluoranthene Methane trichiarofl er Trichloromonofluoromethane Formaldehyde Formic acid C T Furan 0 Furfuran 1 2 Furancarboxaldehyde Furfural N Glycidylaldehyde Oxiranecarboxyaldehyde Benzene hexachloro Code U127 U128 U128 U129 0142 Waste description Hexachlorobenzene 1 3 Butadiene 1 1 2 3 4 4 hexachloro Hexachlorobutadiene Cyclohexane 1 2 3 4 5 6 hexachloro lalpha 2alpha 3beta 4alpha Salpha 6beta Lindane 1 3 Cyclopentadiene 1 2 3 4 5 5 hexachlor
63. cylinders stored separately Yes No N A 4 the cylinders legibly marked to identify contents Yes No N A 5 Are gages of oxygen regulators marked with the words Use No Oil Yes No N A 6 Are the regulators connections and supply lines in good condition Yes No N A 7 Are flash arresters on flammable gas supplies for atomic absorption instruments in house propane gas lines hydrogen and oxy acetylene torch lines H Hazardous Materials Yes No N A 1 Are chemical containers properly labeled with the chemical name and hazard of the material Yes No N A 2 Are chemicals color coded to identify proper storage location Yes No N A 3 Are chemicals stored according to hazard classification and compatibility Yes No N A 4 all containers of potential peroxide forming chemicals dated upon receipt and utilized or disposed within one year Yes No N A 5 Are flammable liquids stored in flammable liquid storage cabinets or in closed metal safety cans whenever possible Yes No N A 6 No storage of corrosive chemicals above eye level e I Standard Microbiological Practices Applicable to Biosafety Level 1 amp 2 Laboratories Additional conditions and requirements for Biosafety Level 2 Laboratories begins at item J Biosafety Level 1 Standard Microbiological Practices __Yes No N A 1 Access to the laboratory is limited or restricted at the discretion of the laboratory director when expe
64. d solvents toluene methyl ethyl ketone carbon disulfide isobutanol pyridine benzene 2 ethoxyethanol and 2 nitropropane all spent solvent mixtures blends containing before use a total of ten percent or more by volume of one or more of the above nonhalogenated solvents or those solvents listed in F001 F002 or F004 and still bottoms fromthe F006 F007 F008 F009 F010 F012 F019 F020 recovery of these spent solvents and spent solvent mixtures Wastewater treatment sludges from electroplating operations except from the following processes 1 sulfuric acid anodizing of aluminum 2 tin plating on carbon steel 3 zinc plating segregated basis on carbon steel 4 aluminum or zinc aluminum plating on carbon steel 5 cleaning stripping associated with tin zinc and aluminum plating on carbon steel and 6 chemical etching and milling of aluminum Spent cyanide plating bath solutions from electroplating operations Plating bath residues from the bottom of plating baths from electroplating operations in which cyanides are used in the process Spent stripping and cleaning bath solutions from electroplating operations in which cyanides are used in the process Quenching bath residues from oil baths from metal heat treating operations in which cyanides are used in the process Spent cyanide solutions from slat bath pot cleaning from metal heat treating operations Que
65. d with hazardous chemicals such as ethidium bromide Radioactive materials areas All labs where radioactive materials were used must be swiped to ensure that the lab is free of radioactive contamination Please contact EHS amp RM prior to moving anything out of the lab as all potentially contaminated surfaces items must be tested o If the lab is destined to become an unrestricted space it must be decommissioned Please contact EHS amp RM for further assistance General lab cleanliness o All lab bench tops sinks and shelves should be washed down with soap and water so that they are free of dust and dirt o All trash should be removed from the lab and floors should be swept and or mopped o All tape should be removed from walls doors drawers and cabinets o posters should be removed from walls and doors Following completion of this checklist the lab will be inspected by your CSO EHS amp RM or departmental head prior to being turned over to either a new occupant or to Facilities Services for renovations and or painting The lab will not be released until all of the guidelines listed above have been met Please ask for assistance if necessary For office use only Inspected by Date Pas s Y N Notes Revised 12 7 04 University Of Alaska Appendix 5 In Case of Emergency YOU ARE IN ROOM IN BLDG IN CASE OF EMERGENCY Appendix 5 AT PHONE Employee Workers Compensation First Report of
66. ding but not limited to _ intercepting or contamination sump sludges from the recovery of coke produced from coal Residues from naphthalene collection and recovery operations from the recovery of coke by products produced from coal Tar storage residues from coal tar refining ao Code K148 K149 K150 K151 K156 K157 K158 K159 Waste description Residues from coal tar distillation including but not limited to still bottoms Distillation bottoms from the production of alpha or methyl chlorinated toluenes ring chlorinated toluenes benzoy chlorides and compounds with mixtures of these functional groups This waste does not include still bottoms from the distillation of benzoy chloride Organic residuals excluding spent carbon adsorbent from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha or methyl chlorinated toluenes benzoyl chlorides and compounds with mixtures of these functional groups Wastewater treatment sludges excluding neutralization and biological sludges generated during the treatment of wastewaters from the production of alpha or methyl chlorinated toluenes benzoyl chlorides and compounds with mixtures of these functional groups Organic waste including heavy ends still bottoms light ends spent solvents filtrates and decamtates from the production of carbamates and carbamoyl oximes This li
67. ding or removing waste Yes No N A 8 Are wastes properly segregated with regard to their chemical compatibility Yes No N A 9 liquid waste containers kept in secondary containment tubs Yes No N A 10 Are waste storage areas inspected weekly by lab personnel e __ No N A 11 Are waste minimization practices used in the laboratory Yes No N A 12 15 infectious biohazardous waste properly bagged and autoclaved or incinerated Page 7 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan Yes No N A 13 Are all sharps collected in puncture and leak resistant containers prior to decontamination disposal e Yes No N A 14 Is broken glass collected in puncture resistant containers marked with the words Broken Glass and sealed before disposal Page 8 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan LABORATORY SAFETY TRAINING RECORD Appendix 3 Print this form and keep it with your Chemical Hygiene Plan This is to certify that the individuals listed below were trained on the following elements of the Chemical Hygiene Plan Standard Operating Procedures Prior Approval Circumstances Conducting a Hazard Assessment Methods of Control Proper Laboratory Hood Use Exposure Detection Chemical Storage Laboratory Waste Disposal Emergency Notification Procedures Spill Response Procedures Emergency Preparedness Date Locat
68. e U049 Benzenamine 4 chloro 2 methyl ED hydrochloride 0066 Propane 1 2 dibromo 3 chloro 10050 Chrysene 0067 Ethane 1 2 dibromo U05 Creosote U067 Ethylene dibromide e Code 0068 0068 10069 0069 1070 0070 0071 0071 0072 0072 0073 Waste description Methane dibromo Methylene bromide 1 2 Benzenedicarboxylic acid dibutyl ester Dibutyl phthalate Benzene 1 2 dichloro o Dichlorobenzene Benzene 1 3 dichloro m Dichlorobenzene Benzene 1 4 dichloro p Dichlorobenzene ME 1 1 Biphenyl 4 4 diamine 3 3 dichloro 3 3 Dichlorobenzidine 1 4 Dichloro 2 butene LT 2 Butene 1 4 dichloro 1 T Dichlorodifluoromethane Methane dichlorodifluoro Ethane 1 1 dichloro Ethylidene dichloride Ethane 1 2 dichloro Ethylene dichloride 1 1 Dichloroethylene Ethene 1 1 dichloro 1 2 Dichloroethylene Ethene 1 2 dichloro E Methane dichloro Methylene chloride 2 4 Dichlorophenol Phenol 2 4 dichloro 2 6 Dichlorophenol EPA HAZARDOUS WASTE CODES Continued Code Waste description U082 0083 0083 0084 0084 0085 0085 0086 0086 0087 0087 7088 0088 0089 0089 0090 0090 0091 12091 0092 0092 0093 0093 0094 0094 0095 0095 Phenol 2 6 dichloro Propane 1 2 dichloro Propylene dichloride 1 3 Dichloropropene 1 Propene 1 3 dichloro 1 2 3 4 Diepoxybutane 1 T 2 2 Bioxirane Hydrazine 1 2 diethyl
69. e a flash point less than 60C 140F and non iquids that are capable under standard temperature and pressure of causing fire through friction absorption of moisture or spontaneous chemical change and when ignited burn so vigorously and persistently that they create a hazard and any ignitable compressed gas described in 40 CFR 173 300 Examples are solvents and spent solvents acetone benzene ethyl acetate ethyl ether methanol methyl isobutyl ketone xylene ignitable paint waste some paint removers brush cleaners and stripping agents epoxy resins and adhesives epoxies rubber cements and marine glues inks containing flammable solvents and some degreasers For additional information see 40 CFR 261 21 Corrosive This category includes acids and bases or mixtures having a pH less than or equal to 2 or greater than or equal to 12 5 and materials that burn the skin or dissolve metals Examples are strong mineral acids chromic sulfuric hydrochloric or nitric strong alkalis potassium hydroxide rust removers and acid or alkaline cleaning fluids This category also includes solids that when rnixed with water form solutions that are strongly acidic or basic ferric chloride sodium hydroxide For additional information see 40 CFR 261 22 e University Of Alaska Fairbanks Chemical Hygiene Plan Reactive This category includes materials that are unstable or undergo rapid or violent chemical reaction when exposed to ai
70. e during collection handling processing storage transport or shipping Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan Yes No N A 15 Laboratory equipment and work surfaces are decontaminated with an effective disinfectant on a routine basis after work with infectious materials is finished and especially after overt spills splashes or other contamination by infectious materials Contaminated equipment is decontaminated according to local state or federal regulations before it is sent for repair or maintenance or packaged for transport in accordance with applicable local state or federal regulations before removal from the facility Yes No N A 16 Spills and accidents that result in overt exposures to infectious materials are immediately reported to the laboratory director Medical evaluation surveillance and treatment are provided as appropriate and written records are maintained Yes No N A 17 Animals not involved in the work being performed are not permitted in the lab Biosafety Level 2 Safety Equipment Primary Barriers Yes No N A 18 Properly maintained biological safety cabinets preferably Class II or other appropriate personal protective equipment or physical containment devices are used whenever a Procedure with a potential for creating infectious aerosols or splashes are conducted These may include centrifuging grinding blending vigorous shaking or mixing s
71. e material to cleanup the spill o Materials resulting from cleanup operations may be RCRA regulated Contact EH amp S RM for assistance and removal Emergency Procedures v Evacuation Information Evacuate the building using the nearest exit or alternate exit if the nearest exit is blocked Do not use elevators Take personal belongings keys purses wallets etc Secure any hazardous materials or equipment before leaving Follow directions given by emergency personnel Go to Evacuation Assembly Points EAP designated on the building s emergency evacuation sign Assist persons with disabilities Do not leave area campus until your status is reported to your supervisor resident advisor or instructor Hazardous Material Emergency Procedures If an emergency or if anyone is in danger call 911 Move away from the site of the hazard to a safe location Follow the instructions of emergency personnel Alert others to stay clear of the area Notify emergency personnel if you have been exposed or have information regarding the release 20 e v Activate the nearest fire alarm pull station and call 911 from the nearest phone if possible Y Evacuate the building and go to the Evacuation Assembly Point or designated area of safe refuge Y Advise emergency personnel of anyone still inside the building v Donotenter the building until authorized by emergency personnel Transport
72. e than 1 kg of acutely hazardous waste per month or more than 100 kg of spill cleanup materials contaminated with a RCRA acutely hazardous waste CESQG s SQG s LQG s 100 kg month 7100 kg lt 1000 kg gt 1000 kg per month kg P listed kg P listed per month or gt 1 kg P listed Never to exceed 1000 kg in Never to exceed 6000 kg in Must ship RCRA regulated storage prior to disposal storage wastes every 90 days Must ship within 180 days Pending distance to EPA permitted TSDF Treatment Storage and Disposal Facilities The University of Alaska Fairbanks Rural Campuses and other extended sites are currently regulated as conditionally exempt small quantity generators of hazardous waste Wastes are primarily generated by laboratory procedures and facility maintenance activities RCRA Hazardous Waste Criteria RCRA hazardous wastes fall into two major categories characteristic wastes see 40 CFR 261 20 and listed wastes see 40 CFR 261 30 Characteristic wastes D code designations are materials that meet specified criteria as being ignitable corrosive reactive or toxic Characteristic waste code D001 are ignitable wastes having a flash point of less than or equal to 140 F Oxidizers as defined in 49 CFR Department of Transportation regulations are also listed as D001 hazardous wastes Oxidizers are defined as a material that may generally by yielding oxygen cause or enhance the combustion of other materials
73. ed Inspected by Date of Inspection A Administrative Yes No N A 1 Are employees aware of how to access and interpret Material Safety Data Sheets MSDS s Yes No N A 2 Are safety training records maintained and available for review by employees EH amp S outside agencies Yes No N A 3 Isthe Department s Chemical Hygiene Plan readily available to all employees Yes No N A 4 Are safety inspection reports maintained and available for review by employees EH amp S outside agencies Yes No N A 5 Is an annual or continuous listing of the chemical inventory maintained and available to employees EH amp S outside agencies B General Safety Concerns Yes No N A 1 Has an emergency information sign been posted outside the lab indicating department personnel to contact in the event of an emergency Yes No N A 2 Are rooms cabinets designated areas containing such materials as regulated hazardous substances radioactive materials and biohazardous materials posted with the appropriate warning signs Yes No N A 3 Are all exits and aisles to the outside free from any obstructions Yes No N A 4 Are there provisions in place to prevent acids caustics flammable liquids and other potentially hazardous substances from entering the sewer discharge system via floor or any other type of drain C Seismic Safety Yes No N A 1 Does shelving have lips or restraints in p
74. ed and visible for inspection mark satellite accumulation start date on transfer label e Send the white and yellow copies of the three part UAF Hazardous Material Transfer Request Form to the EHS amp RM Hazmat Section e Retain the pink copy of request form for department records e Upon receipt of the UAF Hazardous Material Transfer Request Form the EHS amp RM Hazmat Section will arrange for pick up and transfer of all the materials listed on the form to an approved hazardous material accumulation site The hazardous materials are removed from collection areas by EHS amp RM Hazmat Section personnel PROCEDURES FOR PROPERLY COLLECTING STORING HANDLING AND TRANSPORTING HAZARDOUS MATERIALS e Keep all hazardous materials in appropriate closed containers with airtight lids Do not store hazardous materials in a fume hood Keep all hazardous material containers closed at all times except when adding or removing the material e Do mix incompatible chemicals i e oxidizers with flammables e Do not mix hazardous materials with non hazardous materials It greatly increases waste disposal costs e Accurately label all containers with chemical names and exact content as well as date of purchase It is imperative to avoid producing containers whose contents are unknown Such materials are very expensive to dispose of If containers of unknown chemicals are found please contact EHS amp RM Hazmat Section to make special arrangements
75. ed in this document 2 ensure that the necessary protective and emergency equipment is available in working order and that appropriate training has been provided 3 ensure that periodic laboratory inspections are performed refer to Appendix 2 4 know current legal requirements concerning regulated substances 5 review and evaluate the effectiveness of the laboratory specific Standard Operating Procedures SOP at least annually and update as necessary B Laboratory Employees Laboratory employees are responsible for planning and conducting each operation in accordance with practices and procedures established in this CHP 2 using equipment only for its designed purpose 3 being familiar with emergency procedures including knowledge of the location and use of emergency equipment for the laboratory as well as how to obtain additional help in an emergency 4 knowing the types of protective equipment available and using the proper type for each procedure 9 being alert to unsafe conditions and actions and calling attention to them so corrections can be made as soon as possible C Chemical Hygiene Officer CHO is an employee designated by the employer who is qualified by training or experience to provide technical guidance in the development and implementation of the provisions of the CHP The current Chemical Hygiene Officer for the building lab is designated by the Dean Director or Department Head The Chemical Hygi
76. ed in all UAF facilities Wash well with soap and water before leaving the laboratory Avoid the use of solvents for washing skin Solvents remove the natural protective oils from skin and can cause irritation and inflammation In some cases washing with solvent may facilitate absorption of toxic chemicals Housekeeping Housekeeping is directly related to safety and must be given importance of equal value to other procedures Lack of good housekeeping reduces work efficiency and may result in accidents Laboratory personnel must adhere to the following 1 Access to emergency equipment showers eyewashes fire extinguishers exits and circuit breakers shall never be blocked or obstructed Chemical containers should be regularly monitored for proper labeling and container integrity Labels which are fading falling off or deteriorating must be promptly replaced If abbreviations are used they should be kept to a minimum and clearly identify the contents of the container as well as hazards associated with use i e HgCl2 poison HCl corrosive MeOH flammable University Of Alaska Fairbanks Chemical Hygiene Plan 10 H2O2 corrosive oxidizer Nonhazardous buffer etc Improperly labeled or unlabeled chemicals make hazard identification and disposal difficult and may create a hazard All chemicals should be placed in their proper storage areas at the end of each workday Chemicals shall not be stored on desks laboratory ben
77. ene Officer shall 1 assist PI s and other laboratory employees with development and implementation of appropriate chemical hygiene procedures and practices including providing consultation and information 2 keep abreast of legal requirements concerning regulated substances and communicate any changes to PI s and laboratory employees 3 seek ways to improve the overall chemical hygiene program Il EMPLOYEE INFORMATION AND TRAINING Page 3 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan PI s shall ensure that information and training are provided at the time of an employee s initial assignment to a work area where hazardous chemicals are e present and prior to assignments involving new exposure situations Refresher information and training shall be conducted at least annually and documented A B Information All laboratory personnel shall be informed of 1 Requirements of the OSHA Standard Occupational Exposure to Hazardous Chemicals in Laboratories 29 CR 1910 1450 2 Thecontents and availability of this Chemical Hygiene Plan 3 Permissible Exposure Limits PELs for OSHA regulated substances or recommended exposure limits where there is no applicable OSHA standard 4 Signs and symptoms associated with exposures to hazardous chemicals used in their laboratory 5 The location of reference materials on the hazards safe handling storage and disposal of hazardous chemicals found in the la
78. enerated in one or more additional units after wastewaters have been treated in aggressive biological treatment units and K051 wastes are not included in this listing This listing does include residuals generated from processing or recycling oil bearing hazardous secondary materials excluded under 261 4 a 12 i if those residuals are to be disposed of Petroleum refinery secondary emulsified oil water solids separation sludge Any sludge and or float generated from the physical and or chemical separation of oil water solids in process wastewaters and oily cooling wastewaters from petroleum refineries Such wastes include but are not limited to all sludges and floats generated in induced air flotation IAF units tanks and impoundments and all sludges generated in DAF units Sludges generated in stormwater units that do not receive dry weather flow sludges generated in aggressive biological treatment units as a Lg Code Waste description defined in Section 261 31 b 2 including sludges generated in one or more additional units after wastewaters have been treated in aggressive biological treatment units F037 K048 and K051 wastes are exempted from this listing F039 Leachate resulting from the treatment storage or disposal of wastes classified by more than one waste code under Subpart D _ or from a mixture of wastes classified under Subparts C and D of this part Leachate resulting fr
79. ents Accumulation of materials in containers larger than 26 gallons must be approved by your Chemical Hygiene Officer or EH amp S RM Safety Officer prior to use To maintain satellite accumulation area status no more than one quart of acutely hazardous P listed waste or 55 gallons of hazardous waste may be collected in a shop or laboratory prior to removal Jfa laboratory or shop accumulates in excess of 500 ml of acutely hazardous waste see P list or 50 gallons of a regulated waste personnel must contact EH amp S amp RM immediately to request the removal of those materials If accumulating ignitable materials care must be taken to store the material in accordance with applicable fire safety codes and procedures 10 Before placing hazardous materials in a collection area check containers thoroughly to assure e that no leaks are present e The outside of the containers must be clean and free of chemical contamination e Use appropriate containers All glass containers must be securely packaged to prevent breakage during transport e All containers of liquids must have screw lids and must not leak when inverted Corks cotton plugs tape or parafilm are not acceptable lids for containers of hazardous materials e containers of liquids must be placed in secondary containment e If possible use the same container for disposal of used material that held the new material originally e Loose solid materials must
80. ents C Refrigerated storage L Freezer storage C Store with desiccant L Store under nitrogen Light sensitive L Water reactive C Ventilated storage required L Spill containment required Describe safe handling and storage procedures Spill Response Procedures Leaks or spills must be promptly reported to the UAF Fire Department 911 or 7721 The caller should try to provide a detailed description of the spill including the name and approximate quantity of the chemical s involved Do not put yourself or others at risk to gather this information if it is unknown The Fire Department is responsible for notifying UAF Environmental Health Safety and Risk Management or Hazardous Materials Response Team as deemed necessary o University Of Alaska Fairbanks Chemical Hygiene Plan Waste Disposal The UAF non radioactive hazardous materials Transfer Request form is used to communicate the need for chemical waste removal Chemical wastes are managed by UAF Environmental Health Safety and Risk Management Hazardous Materials Division phone 5487 For radioactive waste removal contact the UAF Radiation Safety Officer Basic in lab non radioactive waste management procedure checklist L The waste container is labeled with the UAF Non Radioactive Hazardous Materials Transfer Request adhesive tag The waste container is marked to identify its contents including the quantity or percentage of its constituents
81. es No N A 18 Bench tops impervious to water and are resistant to moderate heat and the organic solvents acids alkalis and chemicals used to decontaminate the work surface and equipment Yes No N A 19 Laboratory furniture is capable of supporting anticipated loading and uses Spaces between benches cabinets and equipment are accessible for cleaning Yes No JN A 20 If the laboratory has windows that open to the exterior they are fitted with fly screens J Biosafety Level 2 Additional Conditions and Requirements Yes No N A 1 The laboratory director has established policies and procedures whereby only persons who have been advised of the potential hazards and meet specific entry requirements e g immunizations may enter the laboratory Yes No N A 2 A biohazard sign has been posted on the entrance to the laboratory when etiologic agents are e in use Appropriate information that is posted includes the agent s in use the biosafety level the required immunizations the investigator s name and telephone number any personal Page 4 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan Yes No N A 3 protective equipment that must be worn in the laboratory and any procedures for exiting the laboratory Laboratory personnel have received appropriate immunizations or tests for agents handled or potentially present in the laboratory e g hepatitis B vaccine or TB skin t
82. esting Yes No N A 4 When appropriate considering the agent s handled baseline serum samples for laboratory Yes No N A 5 Yes No N A 6 __ No N A 7 and other at risk personnel are collected and stored Additional serum specimens may be collected periodically depending on the agents handled or the function of the facility Biosafety procedures have been incorporated into standard operating procedures or in a biosafety manual adopted or prepared specifically for the laboratory by the laboratory director Personnel are advised of special hazards and are required to read and follow instruction on practices and procedures The biosafety procedures described in item 67 are available for review at the following location s L eee The laboratory director has ensured that laboratory and support personnel receive appropriate training on the potential hazards associated with the work involved the necessary precautions to prevent exposures and the exposure evaluation procedures Personnel receive annual updates or additional training as necessary for procedural or policy changes Yes No N A 8 A high degree of precaution must always be taken with any contaminated sharp items Yes No N A 9 including needles and syringes slides pipettes capillary tubes and scalpels Needles and syringes or other sharp instruments are restricted in the laboratory for use only when there is no alternative s
83. he following notification requirements for spill reporting Hazardous substances discharges must be reported as soon as the person has knowledge of the discharge Oil discharges to water must be reported immediately Oil discharges to land Spills greater than 55 gallons must be reported immediately Spills greater than 10 gallons but less than 55 gallons must be reported within 48 hours UAF EHS amp RM will assist the responsible party in reporting the spill e Spills from 1 to 10 gallons are reported on a monthly log The monthly spill log is compiled and reported by UAF EHS amp RM Spills to secondary containment greater than 55 gallons must be reported within 48 hours UAF EHS amp RM will assist the responsible party in reporting the spill For more information please call UAF Environmental Health Safety and Risk Management e 474 5487 Never put yourself at risk to cleanup a hazardous substance spill If you don t know please don t go files UAF Spill Reporting Form AH Purpose doc Page 2 of 2 Chukchi Campus Non Radioactive Hazardous Material Fiscal Year Transfer Request Form Department Contact Phone Building Room Date month day year Material Origin Research Academic Support Number of Container Total Volume Chemical Name Description for mixtures please list or ppm of constituents Containers Size Liters or Kilograms specify o
84. ic acid working with pyrophorics conducting electrophoresis distillations extractions etc must be developed for your laboratory specific SOP s Appendix 1 Maintaining a safe and healthy environment in the laboratory is ultimately the responsibility of the Chemical Hygiene Officer CHO However each individual is expected to conduct all operations and procedures involving chemicals in a safe and prudent manner Basic Instructions e Assign PI and Lab Supervisor page 3 of the CHP Complete Appendix 1 for each lab s Standard Operating Procedures Then return a copy of Appendix 1 to Environmental Health Safety and Risk Management EHS amp RM fnsms2 uaf edu Complete the Chemical Inventory Worksheet excel spreadsheet Then return a copy of the inventory to EHS amp RM fnsms2 uaf edu e If any chemicals are present in the lab that are highlighted in yellow on the inventory worksheet a Laboratory Hazard Statement form must be completed and included in Appendix 1 A blank form is available in Appendix 1 of this CHP e Retain a copy of the CHP and inventory in the lab it pertains to e Page 2 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan l ROLES AND RESPONSIBILITIES A Principal Investigator Pl PI Lab Supervisor The PI has responsibility for implementation of the Chemical Hygiene Plan CHP in his her laboratory The PI shall 1 ensure that workers are trained and follow the CHP outlin
85. igh degree of acute toxicity A Definitions 1 Select carcinogens any substance defined as such by OSHA refer to Appendix 7 2 Reproductive toxin chemicals which affect reproductive capabilities including chromosomal damage mutations and effects on fetuses teratogenesis 3 Highly Acute Toxin is any substance for which a the median oral LD50 is less than or equal to 50 mg kg when administered orally to albino rats or b the median inhalation lethal concentration LC50 value is less than or equal to 200 ppm by volume of gas or vapor or 2 mg liter or less of dust mist or fume when i Page 15 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan administered continuously for one hour or less to albino rats or C the median LD50 is less than or equal to 200 mg kg when administered by continuous contact for 24 hours or less with the bare skin of albino rabbits 4 Designated area a hood glove box portion of a laboratory or an entire laboratory room designated as the only area where work shall be conducted with quantities of select carcinogens reproductive toxins or highly acute toxins in excess of the limits specified above B Designated Area Access to designated areas shall be restricted Only trained employees will be allowed to work with chemicals in the designated area All such persons will 1 Usethe smallest amount of chemical that is consistent with the requirement of the work to be done
86. imethanonaphthalene 1 2 3 4 10 10 hexa chloro 1 4 42 5 8 82 hexahydro Ialpha 4alpha Sbeta 8beta Sabeta sodrin EPA HAZARDOUS WASTE CODES Code P062 P062 P063 P063 P064 p064 P065 P065 P066 P066 P067 P067 P068 P068 P069 P070 P070 P071 P071 P072 P072 P073 P073 Continued Waste description Hexaethyl tetraphosphate Tetraphosphoric acid hexaethyl ester Hydrocyanic acid Hydrogen cyanide Methane isocyanato Methyl isocyanate Fulminic acid mercury 2 salt RT Mercury fulminate R T Ethanimidothioic acid N methylamino carbonyT oxy ester Methomyl 1 2 Propylenimine Aziridine 2 methyl Hydrazine methyl Methyl hydrazine 2 Methyllactonitrile _ Propanenitrile 2 hydroxy 2 methyl Aldicarb Propanal 2 methyl 2 methylthio o eao ante an Methy parathion Phosphorothioic acid O O dimethyl O 4 nitrophenyl ester alpha Naphthylthiourea Thiourea 1 naphthalenyl Nickel carbonyl Nickel carbonyl Ni CO T 4 1 UA EPA HAZARDOUS WASTE CODES Code Wastedescription FCO eee Continued Code Waste description P074 Nickel cyanide P074 Nickel cyanide Ni CN PO75 Nicotine amp salts P075 Pyridine 3 1 methyl 2 pyrrolidinyl S amp salts P076 Nitric oxide P076 Nitrogen oxide NO P077 Benzenamine 4 nitro P077 p Nitroaniline P07
87. ing but not limited to broken capillary tubes and pipettes blades from power tools glass microscope slides and cover plates and hypodermic and non hypodermic needles There may be other hazardous substance that are not included here It is your responsibility to determine if the materials you use are hazardous to human health or the environment If you have any doubt tag it for pickup and EHS amp RM Hazmat Section will dispose of it appropriately You can find information about your material by looking at the Material Safety Data Sheet available from the manufacturer You should have Material Safety Data Sheets accessible for all substances you utilize UAF Hazardous Materials Shipment Request Form Instructions Complete the following questionnaire and submit to your Lab Safety Manager Jn the event that your department does not employ an individual that is trained and certified to prepare hazardous materials shipments please fax the request form to UAF Environmental Health Safety and Risk Management fax 474 5489 Note In addition to chemical substances the hazardous materials shipping regulations include such items as batteries internal combustion engines dry ice diagnostic specimens etc A searchable copy of the regulations is available at http www myregs com dotrspa Shipped From include department name street address point of contact and phone number Shipped To include name street address point
88. inyl ester Diethyl p nitrophenyl phosphate Phosphoric acid diethyl 4 nitrophenyl ester 1 2 Benzenediol 4 1 hydroxy 2 methylamino ethyl R Epinephrine Diisopropylfluorophosphate DFP Phosphorofluoridic acid bis 1 methylethyl ester Dimethoate Phosphorodithioic acid O O dimethyl S 2 methylamino 2 oxoethyl ester 2 Butanone 3 3 dimethyl 1 methylthio O methylamino carbonyl oxime Thiofanox alpha alpha Dimethylphenethylamine Benzeneethanamine alpha alpha dimethyl 4 6 Dinitro o cresol amp salts Phenol 2 methyl 4 6 dinitro amp salts i Code P048 P048 P049 P049 P050 P050 P051 P051 P054 P054 P056 P057 P057 P058 P058 P059 P059 P060 P060 Waste description 2 4 Dinitropheriol Phenol 2 4 dinitro Dithiobiuret Thioimidodicarbonic diamide H N C S NH 6 9 Methano 2 4 3 benzodioxathiepin 6 7 8 9 10 10 hexachloro 1 5 5a 6 9 9a hexahydro 3 oxide Endosulfan 2 7 3 6 Dimethanonaphth 2 3 b oxirene 3 4 5 6 9 9 hexachloro 1a 2 2a 3 6 6a 7 7a octahydro 1aalpha 2beta 2abeta 3alpha 6alpha 6abeta 7beta 7aalpha amp metabolites Endrin Endrin amp metabolites Aziridine Ethyleneimine Fluorine Acetamide 2 fluoro Fluoroacetamide Acetic acid fluoro sodium salt _ Fluoroacetic acid sodium salt 4 7 Methano 1H indene 1 4 5 6 7 8 8 heptachloro 3a 4 7 7a tetrahydro Heptachlor 1 4 5 8 D
89. io frequency generators etc have been turned off Turn off all gas cylinders at the tank valves If a low flow of an inert gas is being used to blanket a reactive compound or mixture it may be appropriate to leave the flow of gas on The decision to do this should be part of the written Standard Operating Procedure specific for each lab in Appendix 1 Check all cryogenic vacuum traps CO and solvent The evaporation of trapped materials may cause dangerous conditions Check all pressure temperature air or moisture sensitive materials and equipment This includes vacuum work distillations glove boxes used for airless moistureless reactions University Of Alaska Fairbanks Chemical Hygiene Plan REQUIREMENTS FOR STORAGE AND HANDLING OF FLAMMABLE AND COMBUSTIBLE LIQUIDS Appendix 9 dor t CLASS IA E Flash point less than 73F less than 73F 73 100 F 100 140F Boiling point r less than greater than 100F 1 OOF Flammability Potential Extremely Very High io High i En RC UM cx uuu EXAMPLES OF acetaldehyde acetone acetate formaldehyde COMMONLY USED benzoyl ethanol butanol hydrazine MATERIALS peroxide butylamine chlorobenzene kerosene ethyl ether gasoline turpentine pentane methanol i xylene methyl isopropanol l formate NFPA 704 HAZARD RATINGS MAXIMUM 1 pint 1 quar
90. ion Instructor NAME please print Department Title Add additional pages as necessary Appendix 4 Chemical Hygiene Plan Checklist for Vacating Labs name Person s completing checklist ilding Room Date lab is to be vacated When vacating a lab space please complete this checklist and return to your Chemical Safety Officer CSO As a courtesy to the next person moving into the lab outgoing PIs are responsible for ensuring that the following checklist is completed Questions Call EHS amp RM at x5812 for assistance with any of the items below or if you do not have a CSO a Chemicals All chemicals and chemical wastes must be removed from the lab o Contact your CSO regarding the following For assistance in moving chemicals to a new lab space To surplus unwanted chemicals For assistance in arranging for chemical and other hazardous waste to be removed from the lab o Contact your CSO if your lab needs to be decontaminated e g if you used ethidium bromide or other toxic chemicals in the lab Equipment All unwanted equipment including glassware and other lab supplies must be removed from the lab Freestanding chemical storage cabinets e g flammables and corrosives may remain as long as they are empty and clean Hoods Fume hood work surfaces must be free of chemical spills and any paper liners should be removed and disposed of appropriately e g in trash or in chemical waste if contaminate
91. ipped 5 Describe how the material is currently packaged ie glass plastic metal fibreboard original packagings etc Material Description please complete questions 1 thru 5 for each individual substance 1 Name of Material 2 Physical state ie solid liquid gas semisolid 3 Quantity of material per container 4 Total quantity of material to be shipped 5 Describe how the material is currently packaged ie glass plastic metal fibreboard original packagings etc University Of Alaska Fairbanks Chemical Hygiene Plan SELECT CARCINOGENS Appendix 7 OSHA s definition of Select Carcinogens includes substances on the following lists OSHA Regulated Carcinogens including substance such as 29 CFR 13 Carcinogens 1910 1003 Acrylonitrile 1910 1045 Inorganic Arsenic 1910 1018 Asbestos 1910 1101 Benzene 1910 1028 1 3 Butadiene 1910 1051 Cadmium 1910 1027 Coke oven emissions 1910 1029 1 2 Dibromo 3 chloropropane 1910 1044 Ethylene oxide 1910 1047 Formaldehyde 1910 1048 Methylene chloride 1910 1052 Methylenedianiline 1910 1050 Vinyl chloride 1910 1017 WHO IARC Monographs Database Group 1 List of Human Carcinogens Group 2A List of Probable Human Carcinogens Group 2B List of Possible Human Carcinogens NTP s most recent Report on Carcinogens List of Substances Known to be Human Carcinogens List of Substances Reasonably Anticipated to be Human Carcinogens
92. ium 5 0 D023 o Cresol 200 0 D024 m Cresol 200 0 D025 p Cresol 200 0 D026 Cresol mixed isomers 200 0 D016 2 4 Dichlorophenoxyacetic acid 10 0 D027 1 4 Dichlorobenzene 7 5 D028 1 2 Dichloroethane 0 7 D030 2 4 Dinitrotoluene 0 13 D012 Endrin 0 02 D031 Heptachlor and it s epoxides 0 008 D032 Hexachlorobenzene 0 13 D033 Hexachlorobutadiene 0 5 D034 Hexachloroethane 3 0 D008 Lead 5 0 D013 Lindane 0 4 D009 Mercury 0 2 D014 Methoxychlor 10 0 D035 Methyl ethyl ketone 200 0 D036 Nitrobenzene 2 0 EPA HW Contaminant Regulatory Level mg L D037 D038 D010 D011 D039 D015 D040 D041 D042 D017 D043 Pentachlorophenol 100 0 Pyridine 5 0 Selenium 1 0 Silver 5 0 Tetrachloroethylene 0 7 Toxaphene 0 5 Trichloroethylene 0 5 2 4 5 Trichlorophenol 400 0 2 4 6 Trichlorophenol 2 0 2 4 5 TP Silvex 1 0 Vinyl chloride 0 2 Listed wastes fall into two major categories with two subcategories each F and K listed wastes originate from processes or procedures U and P listed wastes are from discarded commercial chemical products off specification species container residues and spill residues containing one or more of the listed wastes Process wastes originating from general and specific activities or processes F listed wastes are listed wastes from non specific sources such as F001 spent halogenated solvents used in degreasing Refer to 40 CFR 261 31 K listed wastes are listed wastes from specific sources such as K001 bo
93. lace to prevent spillage Yes No N A 2 Is overhead storage minimized and restrained Yes No N A 3 Are cabinets and storage shelves over 42 inches in height braced or otherwise fastened to the wall to prevent their falling in the event of an earthquake D Personal Protective Equipment Yes No N A 1 Is the appropriate personal protective equipment required for the lab available and utilized Safety Glasses ____ Goggles Face Shields Gloves ____ Lab Coats ____ Aprons Foot wear Page 1 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan E Laboratory Equipment Yes No N A 2 Are the eyewash and emergency shower stations free from any obstructions and have been tested within the last 12 months Yes No 3 Is the maximum operable sash height information posted on the chemical fumehood s Yes No N A 4 Is the maximum operable sash height information followed by ail fumehood users Yes No 5 Is an airflow indicator located on the fumehood Yes No N A 6 Has the fumehood been tested within the last year Yes No N A 7 15 storage with the fumehood minimized and operations conducted at least six inches inside the fumehood face Yes No N A 8 Are the biological safety cabinets appropriate for the biohazard class of material being examined Yes No N A 9 Are the biological safety cabinets certified annually Yes No N A 10 Is non ionizing
94. ld never be allowed to exceed 1000 kilograms 2 200 pounds of RCRA regulated hazardous waste or 1 kilogram 2 2 pounds of acutely hazardous waste If volumes of regulated waste are generated in excess to these limitations the generator will become subject to additional regulations 40 CFR Part 262 Conditionally exempt small quantity generators of hazardous waste shall comply with standards set forth in 40 CFR 261 5 Special requirements for hazardous waste generated by conditionally exempt small quantity generators Materials that are regulated but do not count towards the 1 000 kilogram maximum quantity of waste in storage include Spent lead acid batteries that are shipped for recycling Fluorescent lamps that are shipped for recycling Cathode ray tubes ie computer monitors TVs for redistribution or recycling Used oil as long as it is not mixed with hazardous waste 213 Small Quantity Generators A generator is a SQG as defined by the following criteria In one or more months of the year the site generated more than 100 kg of hazardous waste but in no month generated 1000 kg or more of hazardous waste or no more than 1 kg of acutely hazardous P listed waste or had no more than 100 kg of cleanup materials from the cleanup of spillage of a P listed waste Large Quantity Generators A generator is a LQG as defined by the following criteria The site generated more than 1000 kg of hazardous waste per month or mor
95. le local state and federal regulations before removal from the facility amp __Yes__No__N A 9 biohazard sign may be posted at the entrance to the laboratory whenever infectious agents are present The sign may include the name of the agent s in use and the name and phone number of the investigator Yes No N A 10 Housekeeping and maintenance activities are adequate in eliminating pest management issues Biosafety Level 1 Safety Equipment Primary Barriers Yes No N A 11 Special containment devices or equipment such as a biological safety cabinet are generally not required for manipulations of agents assigned to Biosafety Level 1 Yes No N A 12 Itis recommended that laboratory coats gowns or uniforms be worn to prevent contamination or soiling of street clothes Yes No N A 13 Gloves should be worn if the skin on the hands is broken or if a rash is present Alternatives to powdered latex gloves should be available Yes No N A 14 Protective eyewear should be worn for conduct of procedures in which splashes of microorganisms or other hazardous materials is anticipated Biosafety Level 1 Laboratory Facilities Secondary Barriers Yes No N A 15 Laboratories should have doors for access control Yes No N A 16 Each laboratory contains a sink for hand washing Yes No N A 17 The laboratory is designed so that it can be easily cleaned Carpets and rugs in laboratories are not appropriate Y
96. loride C R Benzenesulfonyl chloride C R _ 1 1 Bipheny 4 4 diamine EPA HAZARDOUS WASTE CODES Code U021 0022 0023 0023 0024 0024 0025 0025 0026 0026 0027 0027 0028 0028 0029 0029 030 U030 U031 U031 U032 U032 U033 0033 0034 0034 0035 0035 Continued Waste description Benzidine Benzo a pyrene Benzene trichloromethyl Benzotrichloride CR T Dichloromethoxy ethane Ethane 1 1 chloro Dichloroethyl ether Ethane 1 1 oxybis 2 chloro Chlomaphazin Naphthalenamine N N bis 2 chloroethyl Dichloroisopropyl ether Propane 2 2 oxybis 2 chloro 1 2 Benzenedicarboxylic acid bis 2 ethylhexyl ester Diethylhexyl phthalate Methane bromo Methyl bromide 4 Bromopheny phenyl ether Benzene 1 bromo 4 phenoxy 1 Butanol 1 n Buty alcohol 1 Calcium chromate i 2 Chromic acid H CrO calcium salt Carbon oxyfluoride R T Carbonic difluoride Acetaldehyde trichloro Chloral Benzenebutanoic acid 4 bis 2 chloroethyl amino Chlorambucil EPA HAZARDOUS WASTE CODES e Continued Code Waste description Code Waste description 0036 4 7 Methano 1H indene 1 2 4 5 6 7 8 8 U052 Cresol Cresylic acid octachloro 2 3 3 4 7 Ta hexahydro 0052 Phenol methyl U036 Chlordane alpha amp gamma isomers U053 2 Butenal 0037 Benzene chloro U053 Crotonaldehyde U037 Chlorobenzene 0055 Benzene I methyle
97. materials must be managed to prevent the accumulation of more that 1000 kilograms of regulated waste or 1 kilogram of acutely hazardous P Listed waste EH amp S RM chemical review procedures e All materials must be documented on the CESGQ Hazardous Materials Transfer Request Forms EH amp S RM will perform a regulatory and safety information review and waste determination for the materials identified on the transfer forms This is accomplished by accessing information available from but not limited to the following resources 40 CFR Parts 260 299 49 CFR Parts 100 177 Sigma Aldrich Library of Regulatory amp Safety Data Sigma Aldrich Library of Chemical Safety Data Bretherick s Handbook of Reactive Chemical Hazards Merck Index CRC Handbook of Laboratory Safety Farm Chemicals Handbook JT Baker Safety Storage Information Material Safety Data Sheets a good link to MSDS s is available at e http www ilpi com msds 0000000000 e List pertinent information on the CESGQ Hazardous Materials Transfer Request form Record keeping CESQG Hazardous Materials Transfer Request form information will be entered into the EH amp S RM chemical inventory data base Information recorded if pertinent includes Item transfer number EPA Waste ID number Date DOT Hazard Class Chemical listing of constituents DOT Shipping Name Quantity UN NA Number Number of containers Information Container type Flash point Physical state of material pH
98. me EH amp S Use Only 4 RCRA Hazardous Waste of C Non RCRA Hazardous Waste C Non Hazardous Waste C Surplus Chemical C TSCA Waste L Other Reg Waste Accumulation Start Date UAF Conditionally Exempt Small Quantity Generator Chemical Transfer Disposal Request Worksheet files CESQG Disposal Request Worksheet xls Please send the completed worksheet to UAF EHS RM ST email fnwrk1 uaf edu or fnred uaf edu or call 907 474 5413 for assistance Location of materials for shipment Contact name amp phone number i Chemical name or material description if a mixture please include a listing and approximate concentration of constituents form number p p Transfer Number of containers Quantity per container Container type glass plastic metal fibreboard Physical state solid liquid gas semisolid Comments 2 University Of Alaska Fairbanks Chemical Hygiene Plan INTRODUCTION e The University of Alaska Fairbanks UAF encourages and supports all programs which promote safety good health and well being of UAF faculty staff students participants in UAF sponsored programs and visitors It is the policy of UAF to provide safe and healthful conditions and to reduce injuries and illnesses to the
99. mit Do not mix hazardous with non hazardous wastes The derived from rule indicates that any waste derived from the treatment of characteristic waste remains a hazardous waste unless the waste does not exhibit the characteristic Any waste derived from the treatment of a listed waste is regulated as a listed waste The contained in policy relates to releases of a characteristic or listed waste into soil surface waters sediments or groundwater If hazardous waste contaminates these media then the media is regulated as a hazardous waste Media contaminated with a characteristic waste is regulated as long as it exhibits that characteristic Media contaminated with a listed wastes remains regulated as a listed waste until such time that the waste is formally de listed by the EPA the hazardous constituents have been completely removed or until a specific determination has been made by the authorized agency that the residuals hazardous constituents do not pose a threat to the environment or human health Non RCRA regulated wastes may still be prohibited from sewer or sanitary landfill disposal Local POTW s public owned treatment works establish prohibited discharge standards They also typically incorporate the national categorical pretreatment standards 40 CFR Subchapter N Parts 405 471 More information regarding the prohibited discharge standards is found at Attachment 2 The regulations found at attachment 2 are from Golden Heart and College
100. nching wastewater treatment sludges from metal heat treating operations in which cyanides are used in the process Wastewater treatment sludges from the chemical conversion coating of aluminum except from zirconium phosphating in aluminum can washing when such phosphating is an exclusive conversion coating process Wastes except wastewater and spent carbon from hydrogen chloride purification from the production or manufacturing use asa reactant chemical intermediate or component in a formulating process of tri or tetrachtorophenol or of intermediates used to produce their pesticide derivatives This listing does not include wastes from Code F021 F022 F023 F024 F025 Waste descripti n the production of hexachlorophene from highly purified 2 4 5 trichlorophenol Wastes except wastewater and spent carbon from hydrogen chloride purification from the production or manufacturing use as a reactant chemical intermediate or component in a formulating process of pentachlorophenol or of intermediates used to produce derivatives Wastes except wastewater and spent carbon from hydrogen chloride purification from the manufacturing use as a reactant chemical intermediate or component in a formulating process of tetra penta or hexachlorobenzenes unger alkaline conditions Wastes except wastewater and spent carbon from hydrogen chloride purification from the production of m
101. nents are permitted for use with gas cylinders Only use regulators approved for the type of gas in the cylinder Do not use adapters to interchange regulators Open cylinder valves slowly and away from the direction of people including yourself Never force a gas cylinder valve If the valve cannot be opened by the wheel or small wrench provided the cylinder should be returned Page 11 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan 3 Noattempt shall be made to transfer gases from one cylinder to another to refill cylinders or to mix gases in a cylinder in the laboratory e 4 cylinders are to be considered full unless properly identified as empty by the user Empty cylinders must be returned to the supplier and not accumulated Compressed gases must not be used to clean your skin or clothing Never heat cylinders to raise internal pressure Do not use copper 26596 connectors or tubing with acetylene Acetylene can form explosive compounds with copper silver and mercury 8 Always leave at least 30 psi minimum pressure in all empty cylinders Do not leave an empty cylinder attached to a pressurized system NON V CONTROL MEASURES A Ventilation 1 Laboratory ventilation is normally designed to provide a minimum of eight air changes per hour This flow is not necessarily sufficient to prevent accumulation of chemical vapors Laboratory work shall be conducted in a fume hood glove box or simil
102. ng does not include inert support media DISCARDED COMMERCIAL CHEMICAL PRODUCTS OFF SPECIFICATION SPECIES CONTAINER RESIDUALS AND SPILL RESIDUES THEREOF ACUTE HAZARDOUS WASTE SEE 40 CFR 261 33 FORAN ALPHABETIZED LISTING P001 P001 P002 P002 P003 P003 P004 2H 1 Benzopyran 2 one 4 hydroxy 3 3 oxo 1 phenylbutyl amp salts when present at concentrations greater than 0 3 Warfarin amp salts when present at concentrations greater than 0 3 1 Acetyl 2 thiourea Acetamide N aminothioxomethyl 2 Propenal Acrolein 1 4 5 8 Dimethanonaphthalene 1 2 3 4 10 10 hexa chloro 1 4 42 5 8 8a EPA HAZARDOUS WASTE CODES Code P004 P005 P005 P006 P007 P007 P008 P008 P009 P009 P010 P011 P011 P012 P012 P013 P014 P014 P015 P016 P016 P017 P017 P018 P018 Continued Waste description hexahydro lalpha 4alpha 4abeta Salpha 8alpha 8abeta Aldrin 2 Propen 1 ol Allyl alcohol Aluminum phosphide R T 3 2H Isoxazolone 5 aminomethyl 5 Aminomethy 3 isoxazolol 4 Aminopyridine 4 Pyridinamine Ammonium picrate R Phenol 2 4 6 trinitro ammonium salt R Arsenic acid HAsO Arsenic oxide As 0 Arsenic pentoxide Arsenic oxide As 0 Arsenic trioxide Barium cyanide Benzenethiol Thiophenol Beryllium powder Dichloromethyl ether Methane oxybis chloro 2 Propanone 1 bromo Bromoacetone Brucine Strychnidin 1
103. number is forwarded to Emergency Dispatch so essentially x 7000 is manned 24 hours If the danger level is immanent leave the lab immediately If conditions warrant i e concentrations are not higher than the LEL activate the fire alarm via the pull down stations that are located near building exits When arriving in a safe area call 911 Spill Clean up Procedures Bos e Attend to anyone who may have been contaminated Notify occupants in the immediate area about the spill Evacuate all nonessential personnel from the spill area If the spilled material is flammable turn off all ignition and heat sources this includes magnetic stirrers Avoid breathing vapors of the spilled material If medically qualified and trained as required in the Respiratory Protection Program use a respirator if necessary Ensure that the fume hood s is on Open windows where possible to increase exhaust ventilation University Of Alaska Fairbanks Chemical Hygiene Plan 7 Secure cleanup supplies Ensure protective apparel is resistant to e the spill material 8 Confine or contain the spill to a small area 9 Use appropriate kit to neutralize and absorb inorganic acids and bases Page 14 of 16 University Of Alaska Fairbanks Chemical Hygiene Plan VI VII VIII EXPOSURE MONITORING Exposure monitoring shall be performed when there is reason to believe that exposures are in excess of the action level or the PE
104. o Hexachlorocyclopentadiene Ethane hexachloro Hexachloroethane Hexachlorophene Phenol 2 2 methylenebis 3 4 6 trichloro Hydrazine R T Hydrofluoric acid C T Hydrogen fluoride C T Hydrogen sulfide Hydrogen sulfide H S Arsinic acid dimethyl Cacodylic acid Indeno 1 2 3 cd pyrene Methane iodo Methyl iodide Propanol 2 methyl 1 T Jsobutyl alcohol T 1 3 Benzodioxole 5 1 propenyl Isosafrole 1 3 4 Metheno 2H cyclobuta cd pentalen 2 one 1 1a 3 3a 4 5 5 5a 5b 6 decachlorooctahydro Kepone EPA HAZARDOUS WASTE CODES Code U143 0145 0145 0146 0146 0147 0147 0148 0148 0149 0149 U150 U150 0151 0152 0152 0153 0153 0154 0154 0155 0155 0156 Continued Waste description 2 Butenoic acid 2 methyl 7 2 3 dihydroxy 2 1 methoxyethyl 3 methyl 1 oxobutoxy methyl 2 3 5 7a tetrahydro 1H pyrrolizin 1 y ester 1S 1alpha Z 7 2S 3R 7aalpha Lasiocarpine Acetic acid lead 2 salt Lead acetate Lead phosphate Phosphoric acid lead 2 salt 2 3 Lead subacetate Lead bis acetato O tetrahydroxytri 2 5 Furandione Maleic anhydride 3 6 Pyridazinedione 1 2 dihydro Maleic hydrazide Malononitrile Propanedinitrile L Phenylalanine 4 bis 2 chloroethyl amino Melphalan Mercury 2 Propenenitrile 2 methyl 1 T Methacrylonitrile 1 T Methanethiol 1 T Thiomethanol 1 T Methanol 1 Methyl alcohol 1 1 2
105. of contact and phone number Special shipping requirements ie cold packs dry ice Preferred shipping method and carrier ground transport air transport via Proposed date for shipment Will a return shipment of these materials be required Yes Material Description please complete questions 1 thru 5 for each individual substance 1 Name of Material 2 Physical state ie solid liquid gas semisolid 3 Quantity of material per container 4 Total quantity of material to be shipped 5 Describe how the material is currently packaged ie glass plastic metal fibreboard original packagings etc Please identify additional materials for this shipment on the attached continuation sheet Hazmat Shippers Request Form submitted by Page 1 of Phone Date Page 2 Material Description please complete questions 1 thru 5 for each individual substance 1 Name of Material 2 Physical state ie solid liquid gas semisolid 3 Quantity of material per container 4 Total quantity of material to be shipped 5 Describe how the material is currently packaged ie glass plastic metal fibreboard original packagings etc Material Description please complete questions thru 5 for each individual substance 1 Name of Material 2 Physical state solid liquid gas semisolid 3 Quantity of material per container 4 Total quantity of material to be sh
106. om the management of one or more ofthe following EPA Hazardous Wastes and no other hazardous wastes retains its hazardous waste code s F020 F021 F022 F023 F026 F027 and or F028 HAZARDOUS WASTE FROM SPECIF IC SOURCES SEE 40 CFR 261 32 001 Bottom sediment sludge from the treatment ef wastewaters from wood preserving processes that use creosote and or pentachlorophenol K002 Wastewater treatment sludge from the production of chrome yellow and orange pigments K003 Wastewater treatment sludge from the production of molybdate orange pigments K004 Wastewater treatment sludge from the production of zinc yellow pigments K005 Wastewater treatment sludge from the production of chrome green pigments K006 Wastewater treatment sludge from the production of chrome oxide green pigments anhydrous and hydrated K007 Wastewater treatment sludge from the production of iron blue pigments K008 Oven residue from the production of chrome oxide green pigments K009 Distillation bottoms from the production of Meesidenyde from ethylene Code K010 K013 K014 K015 K016 K017 K021 Waste description Distillation side cuts from the production of acetaldehyde from ethylene Bott m stream from the wastewater stripper in the production of acrylonitrile Bottom stream from the acetonitrile column in the production of acrylonitrile Bottoms from the acetonitrile
107. on 474 5487 or 474 5758 to obtain battery collection containers with lids Mixing battery types is permissible under SQHUW regulations found at 40 CFR 273 13 a 2 ii e Ensure that each collection container is marked with the words Universal Waste e Batteries and that each collection container is marked with the date that the accumulation of batteries began Container labels are available from EHS amp RM Hazmat Section e Ensure that the collection containers are closed at all times unless adding or removing e In writing identify the location of the battery collection container s under your control to EHS amp RM Hazmat Section USED FLUORESCENT LAMP MANAGEMENT INFORMATION Background On June 28 1999 the EPA announced that spent mercury containing fluorescent lamps were included in the universal waste final rule This Final Rule 59 FR 38288 pertains to the management of spent mercury containing lamps including fluorescent high pressure sodium neon HID high intensity discharge mercury vapor and metal halide lamps Other universal wastes include spent lead acid batteries mercury thermostats and certain types of pesticides The final rule defines four types of universal waste handlers generators 16 Small quantity handlers SQHUW s 5000 kg or less of total universal waste handled at one time Notification to EPA is not required shipments are not required to be manifested no rec
108. onic disruption opening containers of infectious materials whose internal pressures may be different form ambient pressures inoculating animals intranasally and harvesting infected tissues from animals or embryonate eggs b High concentrations of large volumes of infectious agents are used Such materials may be centrifuged in the open laboratory if sealed rotor heads or centrifuge safety cups are used and if these rotors or safety cups are opened only in the biological safety cabinet e Yes No N A 19 A biosafety cabinet is available in this laboratory Provide a description of the cabinet including manufacturer class and safety features Yes No N A 20 Face protection goggles mask face shield or other splatter guard are used for anticipated splashes or sprays of infectious or other hazardous materials to the face when the microorganisms must be manipulated outside of the biosafety cabinet Yes No N A 21 Protective laboratory coats gowns smocks or uniforms designated for lab use are wom while in the laboratory This protective clothing is removed and left in the laboratory before leaving for non laboratory areas e g cafeteria library administrative offices All protective clothing is either disposed of in the laboratory or laundered by the institution it should never be taken home by personnel Yes No N A 22 Gloves are worn when hands may contact potentially infectious materials contaminated surface or eq
109. onjunction with other sources the treatment plant s effluent to fail a toxicity test Detergents surface activity iue or other substances which may cause excessive foaming i in the POTW Any liquids solids or gases which by reason of their nature or quantity are or may be sufficient either alone or by interaction with other substances to cause fire or explosion or be injurious in any other way to the POTW or to the operation of the POTW at no time shall two successive readings on an explosion meter at the point of discharge into the system or at any point in the system be more than five percent nor any single reading over ten percent of the lower explosive limit LEL of the meter 18 Grease animal guts or tissue paunch manure bones hair hides or fleshings entrails whole blood feathers ashes cinders sand spent lime stone or marble dusts metal glass straw shavings grass clippings rags spent grains spent hops wastepaper wood plastics gas tar asphalt residues residues from refining or processing of fuel or lubricating oil mud or glass grinding or polishing wastes 19 Any substance which will cause the POTW to violate its NPDES and or other disposal system permits Q0 The contents of any tank or other vessel owned or used by any person in the business of collecting or pumping sewage effluent septage or other wastewater unless the person has first obtained testing and approval as may
110. ord retention requirement Large quantity handlers LQHUW s greater than 5000 kg of total universal waste at one time Must notify EPA of universal waste activity obtain an EPA ID number if they don t already have one and retain off site shipment records for 3 years This can be a logbook invoice manifest bill of lading or other shipping document Transporters of universal waste do not need to comply with the RCRA manifest requirements Transporters can store universal wastes for ten days or less If shipments are made to facilities with State Authorization and where lamps are already regulated as a hazardous waste then a uniform hazardous waste manifest is required to document the shipment Destination Facilities regulations found at 40 CFR 273 6 The management requirements for SQHUW s and LQHUW s are found at 40 CFR 273 13 and include the following Packaging requirements to prevent breakage of spent lamps during accumulation storage and transport as identified in the Final Rule Universal waste lamps must be stored in containers or packages that remain closed are structurally sound adequate to prevent breakage compatible with contents of the lamps and lack evidence of leakage spillage or damage that could cause leakage under reasonably foreseeable conditions Examples of acceptable packaging could include placing lamps evenly spaced in double or triple ply cardboard containers with closed lids Labeling requirement
111. orinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes i in chlorine production Distillation bottoms from aniline production Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or organo arsenic compounds Distillation or fractionation column bottoms from the production of chlorobenzenes Solvent washes and sludges caustic washes and sludges or water washes and sludges from cleaning tubs and equipment used in the formulation of ink from pigments driers soaps and stabilizers containing chromium and lead Decanter tank tar sludge from coking operations Spent potliners from primary aluminum reduction Emission control dust or sludge from ferrochromiumsilicon production Emission control dust or sludge from ferrochromium production Distillation light ends from the production of phthalic anhydride from ortho xylene Distillation bottoms from the production of phthalic anhydride from ortho xylene Distillation bottoms from the production of 1 1 1 trichloroethane Heavy ends from the heavy ends column from the production of 1 1 1 trichloroethane Code K097 K098 K099 K100 K101 K102 K103 K104 K105 K106 Co K107 K108 K109 _ Waste description Vacuum stripper discharge from the chlordane chlorinator i in the production of chlordane Untreated process
112. ous waste must always be closed during storage except when it is necessary to add or remove waste per 40 CFR 265 173 a A container holding hazardous waste must not be opened handled or stored in a manner which may rupture the container or cause it to leak per 40 CFR 265 173 b Containers holding hazardous wastes must be made of or lined with materials that will not react with the waste so that as the waste is stored the ability of the container to hold the waste will not be impaired per 40 CFR 265 172 If a container holding hazardous waste is not in good condition or if it begins to leak the contents must be transferred to a container in good condition per 40 CFR 256 171 a Assure the hazardous materials located in collection areas are stored in a safe manner i e with regard to chemical compatibility To determine chemical compatibility refer to the UAF Chemical Hygiene Plan s Appendix 10 Chemical Inventory Worksheet The worksheet includes DOT Hazard Class and storage color coding information The information is accessible at the EH amp S RM website http www uaf edu safety Additional references are available at EH amp S RM Liquid wastes should be stored in secondary containment Hazardous material collection areas satellite accumulation areas should be inspected by departmental personnel at least once per week Label and identify the contents of all containers List the name and percentages of all constitu
113. pecific procedure that is required Portions of these requirements may be omitted if they are adequately covered in the Departmental Laboratory Policies amp Procedures University Of Alaska Fairbanks Chemical Hygiene Plan Specific Laboratory Hazard Statement e This hazard statement is to be completed for any chemical present in the lab that is highlighted in yellow on the chemical inventory worksheet The following information is provided to communicate potentially hazardous operations and the actions taken to mitigate their associated hazards Department Name Lab Location Building Room Laboratory Contacts Name Work Phone Home Phone Name Work Phone Home Phone Name Work Phone Home Phone Project Description please include quantity and concentration of chemical Anticipated Duration of Project Laboratory Process or Equipment Approval Required Yes O No L Principal Investigator Lab Supervisor University Of Alaska Fairbanks Chemical Hygiene Plan Chemical Information Chemical Name CAS Quantity LEL UEL Physical State Solid Liquid Gas Semi solid Freezing Point LD50 Fire Code Classification Boiling Point LC50 PEL Fumehood Use Only Yes No Hazard Type check all that apply C Toxic C Highly Toxic Carcinogen Teratogen C Mutagen C Biohazardous C Radioactive C Explosive C Flammable Oxidizer L
114. purification column in the production of acrylonitrile Still bottorns from the distillation of benzyl chloride Heavy ends or distillation residues from the production of carbon tetrachloride Heavy ends still bottoms from the purification column in the production of epichlorohydrin Heavy ends from the fractionation column in ethyl chloride production Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production Aqueous spent antimony catalyst waste from fluoromethane production Distillation bottom tars from the production of phenol acetone from cumene Distillation light ends from the production of phthalic anhydride from naphthalene Distillation bottoms from the production of phthalic anhydride from naphthalene Distillation bottoms from the production of nitrobenzene by the nitration of benzene Stripping still tails from the production of methyl ethyl pyridines Centrifuge and distillation residues from toluene diisocyanate production EPA HAZARDOUS WASTE CODES Continued Code Waste description K028 K029 K030 K031 K032 K033 K034 Ko35 K036 K038 K039 K040 K041 K042 K043 Spent catalyst from the hydrochlorinator reactor in the production of 1 1 1 trichloroethane Waste from the product steam stripper in the
115. r Metolcarb Dimetilan Carbamic acid dimethyl 1 dimethyl amino carbonyl 5 methyl 1 H pyrazol 3 yl ester Isolan Carbamic acid dimethyl 3 methyl 1 1 methylethyl 1H pyrazo 5 y ester Ethanimidothioc acid 2 dimethylamino N methylamino carbonyl oxy 2 oxo methy ester Oxamyl Manganese bis dimethylcarbamodithioato 5 5 EPA HAZARDOUS WASTE CODES Continued Code P196 P197 P197 P198 P198 P199 P199 P201 P201 P202 P202 P202 P203 P203 P204 P204 P205 Waste description Manganese dimethyldithiocarbamate Formparanate Methanimidamide N N dimethyl N 2 methyl 4 methylamino carbonyl oxy phenyl Methanimidamide N N dimethyl N 3 methylamino carbonyljoxy phenyl monohydrochloride Formetanate hydrochloride Methiocarb Phenol 3 5 sei CE methylcarbamate Promecarb Phenol 3 methy 5 1 methylethyl methy carbamate Phenol 3 1 methylethyl methyl carbamate 3 Isopropylphenyl N methylcarbamate m Cumenyl methylcarbamate Aldicarb sulfone Propanal 2 methyl 2 methyl sulfonyl O methylamino carbonylJoxime Physostigmine Pyrrolo 2 3 bJindol 5 ol 1 2 3 3a 8 8a hexahydro 1 3a 8 trimethylmethyl carbamate ester 3aS cis Ziram Code Waste description DISCARDED COMMERCIAL CHEMICAL PRODUCTS OFF SPECIFICATION SPECIES CONTAINER RESIDUES AND SPILL RESIDUES THEREOF
116. r water or other material generate toxic gases or vapors when mixed with water or when exposed to pH conditions between 2 and 12 5 as in the case with cyanide or sulfide containing materials forms potentially explosive mixtures with water are capable of detonation or explosive reaction when heated or subjected to shock Examples are acetyl chloride chromic acid cyanides hypochlorides organic peroxides perchlorates permanganates sulfides some plating materials and bleaches For additional information see 40 CFR 261 23 Toxic This category includes heavy metal compounds such as arsenic barium cadmium chromium lead mercury silver selenium etc Pesticides such as Aldrin arsenic pentoxide arsenic trioxide cacodylic acid chlordane copper cyanides DDT Dieldrin dimethylcarbamoyl chloride Endrin Lindane pentachlorophenol strychnine etc Pathogenic Carcinogenic Infectious and Etiologic agents Includes any material that directly cause health problems such as a viable microorganism or its toxin which causes or may cause disease in humans or animals 41 CFR 173 134 Infectious waste includes BloodBorne pathogens for example hepatitis or AIDS virus For a more detailed definition see the UAF Biosafety Manual and BloodBorne Pathogens Exposure Control Plan available from the e Department of EHS amp RM phone 5413 Sharps Sharps are defined as any non contaminated sharp object that can penetrate the skin includ
117. radiation equipment such as lasers microwaves and ultraviolet light sources properly posted and shielded Yes No N A 11 Are vacuum systems that are capable of imploding protected with cages or barriers are smaller vacuum systems taped Yes No N A 12 Glass dewars are wrapped or shielded Yes No N A 13 Vacuum pump belt guard is place Yes No N A 14 Two pronged appliances are not with a five foot radius or directly located above a sink or flammable materials Yes No N A 15 GFI s ground fault interrupters are located on outlets within six feet of sinks F Refrigerators Yes No N A 1 Are food and beverages kept out of work areas and out of laboratory refrigerators Yes No N A 2 Is the proper type of refrigerator used i e explosion proof for flammable liquids Yes No N A 3 The laboratory refrigerators are properly marked prohibiting the storage of food or drink Yes No N A 4 Walk in refrigerators can be opened from the inside Yes No N A 5 The refrigerator freezer is free of chemical spills or contamination all containers are labeled stoppered or tightly closed G Compressed Gases Yes No N A 1 Are all cylinders properly secured in an upright position Page 2 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan Yes No N A 2 Are protective caps in place when the cylinder is not in use e Yes No N A 3 Are incompatible
118. ratory Shoes or sandals with open toes shall not be worn Long pants and long sleeves should be worn when working with or around chemicals Long hair should be held in place behind the head Loose clothing especially loose trouser legs and sleeves should not be worn in the laboratory A full body length rubber plastic or neoprene apron appropriate for the material being handled should be worn if there is risk of splash or spill A proper respirator must be worn whenever exposure by inhalation is likely to exceed the action level or Personnel Exposure Limit PEL and a fume hood is not accessible Procedures specified in the UAF Respiratory Protection Program must be followed Employees must be medically qualified trained and fit tested prior to using a respirator Consult your PI and or the CHO before doing any such work University Of Alaska Fairbanks Chemical Hygiene Plan E Flammable Materials e Precautions for safe handling of flammable materials include the following 1 Storage of flammable substances shall be limited to quantities specified in Appendix 9 2 Flammable substances shall be handled only in areas free of ignition sources 3 Flammable substances should never be heated by using an open flame Preferred heat sources include steam baths water baths oil baths heating mantles and hot air baths 4 Class liquids Appendix 9 shall not be transferred from one vessel to another in any exit way 5
119. rganic compounds inorganic compounds and heavy metals x X X Container Type Glass 1 Plastic Other Physical State sSolid L_ Liquid Semi solid Transfer Information Satellite Accumulation Area Cabinet Shelf Consolidation Drum Accumulation Start Date month Other Accumulation Start Date Compatibility Information Storage Color Code Hazard Comments Flam Liquid Characteristics Oxidizer L Mutagen month Toxic Highly Toxic Reactive Lachrymator explain reactivity in comments Corrosive Hygroscopic w Teratogen Flam Solid Irritant Carcinogen Regulatory Information EPA Waste ID i EH amp S Use Only i RCRA Regulated Non Regulated TSCA Regulated DOT Hazard LJ Na amp Est pH LD50 mg kg E MSDS Attached RCRA Hazardous Waste Non RCRA Hazardous Waste Non Hazardous Waste Yes Specific Gravity inhalation Est Flashpoint CAS Number TSCA Waste Surplus Chemical Other Regulated Waste Data Entry By C No Please send white and yellow copies to University of Alaska Fairbanks Environmental Health Safety amp Risk Mgmt PO Box 758145 Fairbanks AK 99775 8145 Requested For Information Call 907 474 5487 Fiscal Year Non Radioactive Hazardous Material Satellite Accumulation Area m Na
120. riments or work with cultures and specimens are in progress Yes No N A 2 Persons wash their hands after they handle viable materials after removing gloves and before leaving the laboratory Yes No N A 3 Eating drinking smoking handling contact lenses applying cosmetics and storing food for human use are not permitted in the work areas Persons who wear contact lenses in laboratories should also wear goggles or a face shield Food is stored outside the work area in cabinets or refrigerators designated and used for this purpose only Yes No N A 4 Mouth pipetting is prohibited mechanical pipetting devices are used Yes No N A 5 Policies for the safe handling of sharps are instituted Yes No N A 6 All procedures are performed carefully to minimize the creation of splashes or aerosols Yes No N A 7 Work surfaces are decontaminated at least once a day and after any spill of viable material __Yes No N A 8 All cultures stocks and other regulated wastes are decontaminated before disposal by an approved decontamination method such as autoclaving Materials to be decontaminated outside of the immediate laboratory are to be placed in a durable leakproof container and Page 3 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan closed for transport from the laboratory Materials to be decontaminated outside of the immediate laboratory are packaged in accordance with applicab
121. round oce toa iv piscinis uitiis edito leer armas EE tucon ee 15 Packaging requirements ec evt edet ee UE tula ec glide intro fecun ee 15 Labeling requiremebls oen tine EM RERO peu rene 15 Standard Operating Procedures 16 Used Fluorescent Lamp Management 16 16 Packaging req iremerits cbe la eU 17 Labeling requirements ueni pe apo uiv adim Rit ba edet 17 Employee training requirements ssssssssssss eem ere 17 Standard Pro edures hdc eun ken avs iere Ligue site QM gn 18 Broken Lamp Procedures i 18 Hazardous Waste Minimization cene eene eene nennen tnmen 18 Chemical Spills iie oet ex tr Pr era vas ke E PREX RUNE 19 General Rules and Precautiors ente rh epee 19 Emergericy OLD a PRIN IR MR E EU IER 20 Hazardous Material Emergency Procedures 20 2i Er C RM E ERN 21 Transportation of Hazardous Materials Waste eene 21 UAF Hazardous Waste Self Audit
122. rs NG AND STORAGE Be sure to arrange a return agreement with suppliers prior to purchase since disposal of compressed gas cylinders is difficult and very expensive Cylinders should not be accepted unless the cylinder contents are clearly labeled Color code only should not be accepted since it does not constitute adequate labeling Do not accept cylinders which are damaged or do not have a valve protection cap All gas cylinders in use shall be secured in an upright position in racks holders or clamping devices When cylinders are grouped together they should be individually secured and conspicuously labeled on the neck area Oxygen cylinders shall never be placed near highly combustible materials especially oil and grease or near stocks of carbide and acetylene or other fuel gas cylinders nor near any other substance likely to cause or accelerate a fire Systems and components used for other gases and purposes must never be used for oxygen or interconnected with oxygen Cylinders should have current hydrostatic test date normally less than 5 years old for steel and 3 years old for aluminum engraved on the cylinder Cylinders should be returned to the supplier for servicing prior to the expiration date Do not place cylinders near heat sparks or flames or where they might become part of an electrical circuit Do not store cylinders in exit corridors or hallways HANDLING AND USE 1 Only Compressed Gas Association fittings and compo
123. rvice To determine if used oils are on specification off specification or regulated as a hazardous waste samples of used oils can be submitted for analyses which includes EPA 6010 arsenic cadmium chromium and lead content EPA 1010 flashpoint ASTM D808 total halogens EPA 8080 polychlorinated biphenyls Used Oil Specifications Arsenic 5 ppm maximum o Cadmium 2 ppm maximum o Chromium 10 ppm maximum o Lead 100 ppm maximum o Flash point 100 minimum o TotalHalogens 4 000 ppm maximum Used oil containing more than 1 000 ppm total halogens is presumed to be a hazardous waste under the rebuttable presumption provided under 279 10 b ii Such used oil is subject to subpart H of part 266 of the Code of Federal Regulations rather than this part when burned for energy recovery unless the presumption of mixing can be successfully rebutted Call EH amp S Risk Management for more information An alternative test for total halogens can be performed on site by using the Dexsil Chlor d tect 1000 test kit 14 UNIVERSAL WASTE BATTERIES INFORMATION Background An alternative set of management standards in lieu of regulation under 40 CFR parts 260 272 hazardous waste regulations are identified in 40 CFR part 273 Standards for Universal Waste Management This part establishes requirements for managing batteries as described in 273 2 pesticides as described in 273 3 thermostats as described in 273 4
124. s is on Open windows when appropriate to increase ventilation o Secure the area and notify others about the spill Evacuate all nonessential personnel from the spill area Notify responsible parties e g Chemical Hygiene Offier instructors department head supervisors etc o Ifthe chemical nature of the spill is unknown treat the spill as you would a highly toxic hazardous material take all safety precautions and evacuate the area If the spilled material is flammable turn off all ignition and heat sources o Consult reference materials including but not limited to the MSDS material safety data sheet for information regarding the spilled material s The material safety data sheet will provide information on the potential hazard involved sections 1 through 6 spill and disposal procedures section 7 protective equipment and measures section 8 storage handling data section 9 and transportation data o MSDS s for most products are available on line at http www ilpi com msds 19 The Sigma Aldrich Library of Chemical Safety Data contains procedures for mitigating hazardous materials spills This information is available from UAF EH amp S RM o Secure cleanup supplies and the appropriate personnel protective equipment Ensure protective apparel is resistant to the spill material o Confine or contain the spill to the smallest area as possible o Utilize methods and procedures as described in the referenc
125. s generated at plants that use creosote formulations This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and or pentachlorophenol EPA HAZARDOUS WASTE CODES e Continued Code F035 F037 F038 Waste description Wastewaters process residuals preservative i drippage and spent formulations from wood preserving processes generated at plants that use inorganic preservatives containing arsenic or chromium This listing does not include K001 bottom sediment sludge from the treatment of wastewater from wood preserving processes that use creosote and or pentachlorophenol Petroleum refinery primary oil water solids separation sludge Any sludge generated from the gravitational separation of oil water solids during the storage or treatment of process wastewaters and oily cooling wastewaters from petroleum refineries Such sludges include but are not limited to those generated in oil water solids separators tanks and impoundments ditches and other conveyances sumps and stormwater units receiving dry weather flow sludge generated in stormwater units that do not receive dry weather flow sludges generated from non contact once through cooling waters segregated for treatment from other process or oily cooling waters sludges generated in aggressive biological treatment units as defined in 5261 302 including sludges g
126. s indicate that each lamp or the container holding the lamps must be labeled with the words Universal Waste Lamps or Waste Lamps or Used Lamps Accumulation limitations indicate that handlers may accumulate universal waste for one year Mark the date on the container to identify when the first lamp has been packaged Regulations for release of universal waste are found at 273 17 and 273 37 For SOHUW s immediately cleanup and containerize accidentally broken lamps containerize in structurally sound compatible packaging that prevents the leakage of mercury into the environment Employee training requirements are found at 40 CFR 273 16 and 273 36 The training requirements indicate all employees that handle or have responsibility for the management of universal waste are informed of the proper handling and emergency procedures appropriate to the type s of universal waste handled at the facility Land Disposal Restriction information is found at 40 CFR part 268 17 The prohibition on treatment includes crushing operations Note There is some discussion that may allow RCRA CESQG s conditionally exempt small quantity generators to crush lamps at the point of generation This would not apply to UAF campus Standard Procedures e Segregate fluorescent lubes by length and style i e 4 ft 8 ft HID and U shaped tubes e Package all lamps to comply with requirements Reuse packaging provided with the new replacement lamp
127. s until further notice If needed alternative packaging is also available from EH amp S RM e Document the type of lamp the quantity and the packaging date on the labels provided e Tape both ends and all openings of the packaging shut Apply the label to the end of the package Broken Lamp Procedures The Final Rule indicates that handlers must contain any universal waste lamps that show evidence of breakage leakage or damage that could cause a release of mercury or other hazardous constituents to the environment Utilize protective eyewear and puncture resistant gloves to pick up and containerize all glass shards end caps and phosphors resulting from unintentionally broken lamps Accidentally broken lamps must be placed in the sealable containers Hazardous Waste Minimization Waste minimization is always a priority It can and should occur by a variety of means such as e Product substitution e Surplus chemical exchange programs Contact EH amp S RM for a listing of surplus chemicals which are available to approved campus laboratories e Distillation recovery Microscale chemistry techniques Information regarding waste minimization is available from EH amp S RM the Environmental Protection Agency and the Alaska Department of Environmental Conservation 18 Chemical Spills Chemical leaks or spills must be promptly reported to your Chemical Hygiene Officer the UAF Fire Department Dispatch Center 907 4
128. sting does not apply to wastes generated from the manufacture of ite ada n butylcarbamate Wastewaters including scrubber waters condenser waters washwaters and separation waters from the production of carbamates and carbamoyl oximes This listing does not apply to wastes generated from the manufacture of 3 iodo 2propyn n butylcarbamate Bag house and filter separation solids from the production of carbamates and carbamoyl oximes This listing does not apply to wastes generated from the manufacture of 3 iodo 2propynl n butylcarbamate Organics from the treatment of thiocarbamate wastes Code K161 K169 K170 K171 K172 Waste description Purification soilids including filtration evaporation and centrifugation soilds bag house dust and floor sweepings from the production of dithiocarbamate acids and their salts This listing does not include K125 or K126 Crude oil tank sediment from petroleum refining operations Clarified slurry oil tank sediment and or in line filter separation solids from petroleum refining operations Spent hydrotreating catalyst from petroleum refining operations including guard beds used to desulfurize feeds to other catalytic reactors This listing does not include inert support media Spent hydrorefining catalyst from petroleum refining operations including guard beds used to desulfurize feeds to other catalytic reactors This listi
129. t 1 gallon 1 gallon CONTAINER SIZE Glass 500 mi 1 liter 4 liters 4 liters Metal or approved a plastic 1 gallon 5 gallons 5 gallons 5 gallons deme Safety cans 2 p 5 gallons 5 gallons 5 gallons EEE TE Metal drums DOT N A 5 gallons 5 gallons 60 gallons VOUS HI ke es tS poe ae ee NFPA is the acronym for the National Fire Protection Association NFPA 704 Standard System for the Identification of the Fire Hazards of Materials provides University Of Alaska Fairbanks Chemical Hygiene Plan planning guidance to fire departments for safe tactical procedures in emergency e operations and gives on the spot information to safeguard the lives of fire fighting personnel and the others who may be exposed The Hazard Identification System is not intended to identify the nonemergency health hazards of chemicals STORAGE REQUIREMENTS 1 Flammable and or combustible liquids stored in the open in a laboratory work area or inside any building shall be kept to the minimum necessary for the work being done 2 Maximum quantity permitted in labs and other areas of use is limited to a total of 10 gallons all classifications combined outside of a flammable storage cabinet or approved flammable storage room Please refer to the table above 3 Quantities stored in flammable storage cabinets shall be limited to 60 gallons of class or Il liquids and the total of all liquids shall no
130. t exceed 120 gallons Please refer to the table above for maximum allowable container size for each class Not more than three cabinets shall be located in the same room 1 Quantities exceeding the above must be stored in an approved flammable storage room meeting the requirements of the Uniform Building and Fire Codes 2 Flammable and combustible liquids shall not be stored near exit doorways stairways in exit corridors or in a location that would impede egress from the building 3 Flammable aerosols and unstable liquids shall be treated as class l A liquids e Please refer to the table above 4 Materials which will react with water or other liquids to produce a hazard shall be segregated from flammable and or combustible liquids HANDLING AND DISPENSING 1 Class liquids shall not be transferred from one vessel to another in any exit passageway 2 Transfer of flammable liquids from 5 gallon containers or less to smaller containers shall be done in a laboratory fume hood or in an approved flammable liquid storage room e Conditionally Exempt Small Quantity Generator Hazardous Waste Management Environmental Health amp Safety and Risk Management Box 758145 Fairbanks Alaska 99775 8145 Offices University Park Building Rooms 155 157 and 159 1000 University Avenue Office Phone 474 5413 Office Fax 474 5489 www uaf edu safety Conditionally Exempt Small Quantity Generator Hazardous
131. t limited to waste streams with a closed cup flashpoint of less than 140 degrees Fahrenheit 60 degrees Celsius using the test methods specified in 40 CFR 261 21 Wastewater having a pH less than 5 0 or more than 10 or otherwise causing corrosive structural damage to the POTW or equipment Solid or viscous substances in amounts which will cause Obstruction of the flow to and within the POTW resulting in interference Pollutants including oxygen demanding pollutants BOD etc released in a discharge at a flow rate and or pollutant concentration which either singly or by interaction with other pollutants will cause interference with the POTW Wastewater having a temperature which will inhibit biological activity in the treatment plant resulting in interference but in no case wastewater Which causes the temperature at the introduction into the treatment plant to exceed 104 degrees Fahrenheit 40 degrees Celsius unless the approval authority upon the request of the POTW approves alternate temperature limits Petroleum oil nonbiodegradable cutting oil or products of mineral oil origin in amounts that will cause interference or pass through Pollutants which result in the presence of toxic gases vapors or fumes within the POTW in a quantity that may cause acute worker health and safety problems 8 9 10 11 12 13 14 15 16 17 Trucked or hauled pollutants except
132. te generated satellite accumulation start date e Labor shop location and contact name phone number e Material origin i e research academic or support activities A sample copy of the Non Radioactive Hazardous Material Transfer Request form is found at Attachment 3 Retain the pink copy of the three part form and send the white and yellow copies to UAF Environmental Health amp Safety 1000 University Avenue P O Box 758145 Fairbanks Alaska 99775 8145 Upon receipt of the Non Radioactive Hazardous Material Transfer Request Form EH amp S RM will complete the regulatory review and compile an inventory of the materials that have been listed on the form s UAF maintains a contract for hazardous waste removal services EH amp S RM will coordinate with the contractor for the timely removal of hazardous wastes There is currently no charge for these services to the originating department Primary RCRA Concerns The eight primary RCRA concerns involve Appropriate labeling Appropriate accumulation start date Less than maximum storage time Less than maximum storage volumes Lids caps are securely fastened Materials are properly segregated VVVVVV gt Compatible containers and closure are used for waste storage gt Spills overfills and general mismanagement are absent General rules for proper management of surplus hazardous materials and wastes include but are not limited to the following A container holding hazard
133. ted in puncture and leak resistant containers prior e to decontamination disposal Yes No N A 15 Is broken glass collected in puncture resistant containers marked with the words Broken Glass and sealed before disposal Yes No N A 16 Are empty containers marked with the words empty or the initials MT Note that empty containers that held P listed substances are still regulated as a RCRA regulated waste 24 Attachments EPA Lists of Hazardous Wastes a 40 CFR 261 24 Toxicity Characteristic TCLP b 40 CFR 261 30 261 33 F K U and P listed wastes Sewer Discharge Limitations Golden Heart College Utilities Non Radioactive Hazardous Material Transfer Request Form Sample 4 UAF Oil and Hazardous Substances Spill Reporting Form Document Conditionally Exempt Small Quantity Generator Hazardous Waste Management Prepared by Bill Krause Last revised May 10 2005 Files CESQG Hazardous Waste Management doc 25 Code Waste description CHARACTERISTICS OF HAZARDOUS WASTE SEE 40 CFR 261 24 D001 Ignitable waste D002 Corrosive waste D003 Reactive waste D004 Arsenic D005 Barium D006 Cadmium D007 Chromium D008 Lead D009 Mercury D010 Selenium 0011 Silver 0012 Endrin D013 Lindane 0014 Methoxychlor 0015 Toxaphene D016 24 D017 2 4 5 TP Silvex D018 Benzene D019 Carbon tetrachloride D020 Chlordane D021 Chlorobenzene D022 Chloroform D023 o Cresol D024 m
134. thyl P U038 Benzeneacetic acid 4 chloro alpha 4 chloropheny alpha hydroxy ethyl ester 0055 Cumene 1 0038 Chlorobenzilate 0056 Benzene hexahydro 1 U039 p Chloro m cresol U056 Cyclohexane I U039 Phenol 4 chloro 3 methyl 0057 Cyclohexanone 1 0041 Epichlorohydrin U058 2H 1 3 2 Oxazaphosphorin 2 amine N N bis 2 chloroethyl tetrahydro 2 oxide 0041 Oxirane chloromethyl 0058 Cyclophosphamide U042 2 Chloroethyl vinyl ether 0059 5 12 Naphthacenedione 8 acetyl 10 3 U042 Ethene 2 chloroethoxy amino 2 3 6 trideoxy alpha L lyxo e hexopyranosyl oxy 7 8 9 10 tetrahydro 0043 Ethene chloro 6 8 11 trihydroxy 1 methoxy 8S cis U043 Vinyl chloride U059 Daunomycin U044 Chloroform U060 Benzene 1 t 2 2 dichloroethylidene bis 4 chloro U044 Methane trichloro U060 DDD 0045 Methane chloro LT 2t 0061 Benzene 1 1 2 2 2 0045 Methyl chloride 1 T trichloroethylidene bis 4 chloro 0046 Chloromethyl methyl ether DDT U046 Methane chloromethoxy 0062 Carbamothioic acid bis 1 methylethyl S D 2 3 dichloro 2 propenyl ester U047 beta Chloronaphthalene T U062 Dialate 0047 Naphthalene 2 chloro 0063 Dibenz ah anthracene U048 o Chlorophenol 0064 Benzo rst p nt phene 0048 Phenol 2 chloro UM U064 Dibenzo a i pyrene 17049 4 Chloro o toluidine hydrochloride U066 1 2 Dibromo 3 chloropropan
135. ttom sediment sludge from the treatment of wastewaters from wood preserving processes that use creosote and or pentachlorophenol Refer to 40 CFR 261 32 U listed wastes include materials such as U001 acetaldehyde U listed wastes are toxic wastes and typically have lethal dose 5096 LDso of between 50 500 mg kg oral rat Refer to 40 CFR 261 33 P listed wastes are also discarded commercial chemical products manufacturing chemical intermediates off specification species and container or spill residues P listed wastes include materials such a P105 sodium azide P listed wastes are acutely hazardous wastes and typically have lethal dose 50 LDso of lt 50 mg kg oral rat Refer to 40 CFR 261 33 Listed wastes are found at Attachment 1 Three requirements supplement the technical specifications for hazardous waste identification o Mixture Rule o Derived from Rule o Contained in Policy The mixture rule indicates that a mixture of characteristic hazardous waste and a non hazardous waste is a regulated hazardous waste unless the resultant mixture does not exhibit any hazardous waste characteristics A mixture of a listed waste and a non hazardous waste remains the listed waste unless the listed waste is only designated because of it s ignitable corrosive or reactive characteristics The intentional dilution of hazardous wastes with non hazardous wastes is considered waste treatment and typically requires an EPA treatment per
136. uch as parenteral injection phlebotomy or aspiration of fluids from laboratory animais and diaphragm bottles Plasticware should be substituted for glassware whenever possible Yes No N A 10 Only needie locking syringes or disposable syringe needle units i e needle integral to the syringe are used for injection or aspiration of infectious materials Used disposable needles rnust not be bent sheared or broken recapped removed from disposable syringes or otherwise manipulated by hand before disposal rather they must be carefully placed in conveniently located puncture resistant containers for sharps disposal Non disposable sharps must be placed in hard wailed container for transport to a processing area for decontamination preferably by autoclaving Yes No N A 11 Appropriate sharps containers are available or in use Yes No N A 12 Syringes which re sheathe the needle needleless systems and other safety devices are used when appropriate Yes No N A 13 Broken glassware is not handled directly by hand but is removed by mechanical means such as a brush and dustpan tongs or forceps Containers of contaminated needles sharp equipment and broken glass are decontaminated before disposal according to local state or federal regulations Yes No N A 14 Cultures tissues specimens of bodily fluids or potentially infectious wastes are placed in a Page 5 of 8 container with a cover that prevents leakag
137. ufacturing formulation and loading of lead based initiating compounds K047 Pink red water from TNT operations K048 Dissolved air flotation DAF float from the petroleum refining industry K049 Slop oil emulsion solids from the petroleum refining industry K050 Heat exchanger bundle cleaning sludge from the petroleum refining industry KOSI separator sludge from the petroleum refining industry K052 Tank bottoms leaded from the petroleum ut refining industry K060 Ammonia still lime sludge from coting Operations K061 Emission control dust sludge from the primary production of steel in electric furnaces K062 Spentpickle liquor from steel finishing operations of plants that produce iron or steel Acid plant blowdown slurry studge resulting from the thickening of blowdown slurry from primary copper production Surface impoundment solids contained in and dredged from surface impoundments at primary lead smelting facilities Sludge from treatment of process wastewater and or acid plant blowdown from primary zinc production Emission control dust sludge from f secondary lead smelting ps w y Code Waste description K071 K073 _ K083 K084 K085 K086 K087 K088 K090 K091 K093 K094 K095 K096 Brine purification muds from the mercury _ cell process in chlorine production in which separately prepurified brine is not used Chl
138. uipment Wearing two pair of gloves may be appropriate Gloves are disposed of when overtly contaminated and removed when work with infectious materials is completed or when the integrity of the glove is compromised Disposable gloves are not washed reused or used for touching clean surfaces keyboards telephones etc and they are not worn outside of the lab Alternatives to powdered latex gloves are available Hands are washed following removal of gloves e Biosafety Level 2 Laboratory Facilities Secondary Barriers Page 6 of 8 Revised 12 7 04 University Of Alaska Fairbanks Chemical Hygiene Plan Yes No N A 23 Lockable doors are provided for facilities that house restricted agents as defined in 42 CFR 72 6 Yes No N A 24 Each laboratory contains a sink for handwashing Foot knee or automatically operated sinks are recommended Yes No N A 25 The laboratory is designed so that it can be easily cleaned Carpets and rugs are not present Yes No N A 26 Bench tops impervious to water and resistant to moderate heat and organic solvents acids alkalis and chemicals used to decontaminate the work surface and equipment Yes No N A 27 Laboratory furniture is capable of supporting anticipated loading and uses Spaces between benches cabinets and equipment are accessible for cleaning Chairs and other furniture used in laboratory work are covered with a non fabric material that can
139. ures that are carcinogenic to humans Group2A The agent mixture is probably carcinogenic to humans The exposure circumstance entails exposures that are probably carcinogenic to humans Group2B The agent mixture is possibly carcinogenic to humans The exposure circumstance entails exposures that are possibly carcinogenic to humans Group 3 The agent mixture or exposure circumstances is unclassifiable as to carcinogenicity in humans Group 4 The agent mixture exposure circumstance is probably not carcinogenic to humans NTP National Toxicity Program Anticipated Human Carcinogen HC Known Human Carcinogen OSHA Occupational Safety and Health Administration 13 OSHA Regulated carcinogens
140. y around and beneath d Manipulations within the hood should be performed at least 6 inches inside the face of the hood or as far towards the back of the hood as possible This minimizes the possibility of contaminants escaping from the hood e Things which cause air turbulence across the face of the hood such as fans window air conditioning units or excessive movement should be avoided f Exhaust hoods do not provide adequate protection for all operations involving toxic materials A higher level of containment should be used for procedures where minor contamination can be serious If you are in doubt about the level of containment needed for your operation ask your Pl Lab Supervisor or contact the CHO Fume hoods should be performed annually to verify adequate airflow is maintained through the hood face Departments can do this themselves by borrowing EHS amp RM s testing equipment or call EHS amp RM to schedule an appointment Face velocities should be between 80 and 125 feet per minute fpm Contact EHS amp RM at x5413 if you suspect the hood is not working properly In the event of a fume hood failure or low flow alarm discontinue all fume hood operations and only if it is safe to do so place lids on open containers lower the hood sash and secure reactions that may be generating hazardous emissions Contact Facilities Services Dispatch x7000 to report the alarm after following the steps listed above After work hours this

Chemical Hygiene Plan h - University of Alaska Fairbanks

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