化学物質教育訓練
Contents
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3. http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08 3
4. 9 1
5. ERIRE WAR Yay http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08
6. A4 3 PRTR CAS A 1 1 1 1 3 2 1979 6 1 2 2 1 1979 10 7 3 1 7 107 13 1 2 1 2 3 1 11 75 07 0
7. http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 IMO UN No 1888 Proper Shipping CHLOROFORM Class 6 1 Packing Group III Marine Pollutant Not applicable ICAO IATA UN No 1888 Proper Shipping Chloroform Class 6 1 Packing Group 1888
8. 9 14 14 pH http www jaish gr jp anzen gmsds 0597 html 2010 05 14 14 14 08 RA REAA 41 5 1 121 C 1 4 4 6 4 kPa 20 1 1 2 2 1 1 4 1 90 9g L 25 5 log
9. 1 0 8 2005 2ppm 5 2mg m3 ACGIH 2005
10. IMO 2031 NITRIC ACID 8 5 1 Not applicable ICAO IATA 2031 Nitric acid http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08 Class 8 Sub Risk 5 1 Packing Group 2031 8 5 1 2031 8 5 1
11. 11 430mg kg 9 LCsp 5 0 05 0 5mg 2 2 6 8 1A 1A http www jaish gr j
12. LD5so 450mg kg 35 LD50 1200mg kg 35 LD5so 908mg kg 35 050 2000mg kg 35 LD5so 450mg kg 35 LD50 1117mg kg 35 4 35 1A 4 2 3 1 3 35
13. 15 5 7 2 1 8 2 9 307 3 2 1 6 3 2 6 7 5 2 3 5 1 2 4 2 2 2 6 2 7 1 2 1 2 3 1 1 9 4 1 1
14. 6 8
15. MSDS MSDS MSDS Material Safety Data Sheet MSDS PRTR 1 MSDS MSDS ag gt gt lt lt gt a CO N
16. 1 3 2 3 5 1 CE O L HEIE 1 E 1 150
17. ChemFinder CROCUS GHS MSDS 2010 4 CROCUS 8 31
18. 8
19. 3 2 1A 1 http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08 1 1
20. lt qa crocus ado osaka cu ac jp gt 1 2 3 CAS Q A CAS No MSDS GHS
21. http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 3 CASS Chloroform
22. 559 0034 1 14 16 WTC 33 06 6615 7523 06 6615 7690 530 8201 1 3 20 06 6208 8181 9 00 17 30 12 29 1 3 Copyright C City of Osaka All rights reserved http 7www city 0saka g jp kensetsu page 0000010310 html 2010705 14 14 32 51 TA 3 JE EE MSDS Lir Material Safety Data Sheet Power sear ERSE E EEA Last Update Oct 2009
23. 4 3 2 1 PRTR 2 3
24. PRTR PRTR o o p HP Federal Register 1994 Code of Federal Regulations CFR GPO Access USA 21 POPs UNEP PIC PRTR UNEP OECD LO United Nations Economic Commission for Europe GHS
25. 8 8 CCa 1 0 http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08
26. 9 10 20 14 6 1 1 10 10 20 1 Tes 1 10 1 1
27. http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 5
28. 6 7
29. E E p 4 8 13 4 F1 50 3 50 11215 3 53
30. 14 64 C 1 62 D 21 2kPa 20 1 4 12 1 4835 20 20 6 0 8g 100mL 20 2 1 97 5 http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 1 10 1 11 9
31. CAS 4600 6220 6 PRTR MSDS MSDS 0 2 PRTR PRTR Pollutant Release Transfer Register KRKA K R PRTR 2002 4 PRTR
32. 1 4 1 2 1 1 oc N N 2 4 6 CO OO A Ne A CD 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 232 236 240 241 243 244 252 253 254 259 266 270 283 285 294 299 304 306 310 311 312 313 320 354 55 63 0 98 95 3 75 15 0 88 89 1 302 01 2 123 31 9 110 86 1 108 95 2 84 74 2 353 59 3 71 43 2 1336 36 3 50 00 0 85 44 9 108 31 6 80 62 6 126 73 8
33. CASS Nitric acid HNO 7697 37 2 1 394 4 R 5
34. CROCUS MSDS 6 CROCUS MSDS http www j shiyaku or jp home msds 7 Web gt http www nihs go jp hse link webguide html 8 CROCUS FAQ Q A 1 21 1 gt 2
35. 2 CROCUS 1 DNA 1g 2 Ready to use 1g 3 1 50ml 4 L 5 3 1 amp 2
36. CROCUS CROCUS WEZ IT gt PR ESLAR E 84 2010 3 11 15 36 30 1 1
37. EHC CICAD INCHEM IPCS ECETOC o PNTP ATSDR Toxicological Profile Toxline Medline 2007 11 29 03 3700 1141 Ex 573 1 2 3 1 1
38. cE tn eaz bft e gt 4 ID si k Hia HF 6 PCB 1 2 1 1 1 2 1 1 1 1 1 2 1 3 BOD SS 13 0 1mg L 1mg L 1mg L 0 1mg L 0 5mg L 0 1mg L 0 005mg L
39. nm PCB n A CO NO DD N CS Advanced Information center of Safety Health gt GHS MSDS 1 FAX 2 GH S u oooo 2001 03 12 2006 03 13
40. IiD AB AB 2 4 STCABYAKUHINNKANNRI 16 ID E MARE TA A
41. 22 4 15 vs gt 1 BA RA RE CROCUS Chemical Registration system at Osaka City University Sites CERHO XID ESF Chemical Abstracts Service Registry File
42. 1
43. 1 3 3 O 53 1 LC5o 1 24 2 03mg L 96H 43 2 BOD 0 51 BCF 13 51 2
44. 8 1 0 3ppm 2008 3ppm 14 7mg m3 ACGIH 2009 TLV TWA 10ppm A3
45. g JETOC OECD SIAP JETOC piPCS EHC EHC CICAD CICAD INCHEM Environmental Health Criteria Concise International Chemical Assessment Document CICAD Health and Safety Guides HSGs International Chemical Safety Cards ICSC JECFA Monographs and Evaluations JMPR Monographs of toxicological evaluations Pesticide Data Sheets PDSs Poison Information Monographs PIMs IPCS INTOX
46. 6 2 3 k 4 T 5 1
47. 3 3 H ARH YW H 1 1 ARH YR H Bem 13
48. http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 Advanced Information center of Safety Health gt GHS MSDS 1 FAX 2 GH S 2003 5 6 2006 7 31 OOO oooo 03 1234 5678 03 1234 5678 03 1234 5678 TDI
49. 6 1 1888 6 1 15 5 7 2 1 8 2 9 160 1 6 2 1 1 3 1 8 2 8 3 7 5 2 3 5 1 2 4 2 2 5 1 PRTR 2 2
50. 68 471 MSDS 5 E 2 GE E DS J E m 2 J manmanan HP
51. 59 22 3
52. lt tr gt M CSC EHC CICAD JECDB CHRIP k o CERI 7 o o o PRTR WebKis Plus kis net GHS MSDS
53. 7 1 0 http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35
54. ID ee 1 2 HOER H 3 4
55. STCsen kan 01 8 1 S A 2 L G S M N R 3 4 5 E ABf SHAAB AB 1 SHAAB 01 16 1 S A 2 L S T H M N 2 1E
56. 1 in vivo in vivo in vivo 50 23 27 35 20 2 NTP R 45 IARC 2B 40 EU 3 36 ACGIH A3 54 EPA B2 32 2B 30 2 IARC 2B ACGIH A3 50 31 http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35
57. 2 1 1 12 1975 5 8 1 4 1 15 62 53 3 2 1 3 3 1 1 24 1 1 26 1332 21 4 1 2 1 40 100 41 4 4 1 1 42 75 21 8 1 1 3 3 1 43 107 21 1 1 46 107 15 3 4 1 2 1 47 60 00 4 1 4 1 58 111 87 5 1 2 1 60 1 2 1 1 1 63 1330 20 7 4 4 4 1 1 64 1 1 1 68 3 3 3 1 1 1 69 6 1 1 3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 77 95 100 102 104 108 112 113 116 117 145 159 171 172 175 176 177 179 181 182 205 206 207 219 222 227 230 1975 1 4 67 66 3 108 05 4 1990 2 8 56 23 5 123 91 1 107 06 2 75 35 4 1975 9 2 122 39 4 119 93 7 1968 12 2 100 42 5 62 56 6 108 98 5 100 21 0 120 61 6 118 96 7 75 25 2 108 88 3
58. 2
59. 0 003mg L 0 3mg L 0 1mg L 0 2mg L 0 02mg L 0 04mg L 0 2mg L 0 4mg L 3mg L 0 06mg L 0 02mg L 0 06mg L 0 03mg L 0 2mg L 0 1mg L 0 1mg L 8mg L 10mg L 10pg TEQ L 45 40 5 9 5 7 8 7 600 300 mg L 600 300 mg L 5mg L 4 3mg L 30mg L 20 10mg L 220mg L 5mog L 2mg L http 7www city osaka g jp kensetsu page70000010310 html 2010705 14 14 32 51 2009 3 16 3mg L 2mg L 10mg L 10mg L 2 600mg L
60. M S D S MSDS PRTR MSDS MSDS MRIDS Finder Internet Edition Produced by Maxmalla Systems http www j shiyaku or jp home msds 2010 05 14 15 00 41 Web EINECS
61. IARC Monographs Programme on the Evaluation of Carcinogenic Risks to Humans IARC Supplements IARC Monographs on the Evaluation of Carcinogenic Risks to Humans and their Supplements A complete list o Lists of IARC Evaluations o O IARC Some recent and forthcoming IARC Monographs IARC pdf Monographs available in PDF format US National Toxicology Program Report on Carcinogens RoC TOXNET CCRIS Chemical Carcinogenesis Research Information System NCI TOXNET GENE TOX Genetic Toxicology Cancer Literature in PubMed NCI ECOTOX Database IRIS Database for Risk Assessment PHSDB Hazardous Substances Data Bank
62. J Zn Fe Mn C N O S C N O S PCB
63. LT x 2 FE E 7 2 EHA gj
64. 4 1A 1C 1 2 2 2 1 3 1 2 2
65. 1 1 95 2 2 2 1 2 3 1 http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 1 9 4 1 16 1 ICSC 2004 Merck 13th 2001 IMDG 2004 2 3 4 1991 5 SRC KowWin 2005 6 HSDB 2005 7 Lange 16th 2005 8 PATTY 4th 1994 9 IUCLID 2000 10 ACGIH 7th 2001 11 RTECS 2005 12 HSFS 2000 a SITTIG 4th 2002 ICSC J 2000 Chapman 2005 Lange 16th 2005 GESTICS 2005 Howard 1997 Weiss 2nd 1986 DFGOT vol 14 2000 Verschueren 4th 2003 22 CERI 97 9 1998 23 IARC 73 1999 24 SIDS 2004 25 ECETOC TR48 1992 26 ATSDR 1999 27 CaPSAR 2001 28 SIAR 1997 29 Sax 8th 1992 30 2005 4 5 6 7 8 i 31 IRIS 2001 20 21 32 IR
66. ID TD 5 8 adm 15 S 227 f RARS X L G S T ESM N R kan f SSkan adm SSkan 1955505 adm 01 5 8 TID kan Oii ID IIRA V 1 S A 2 L G S L T E M N R 3 sen STCsen kan
67. PubMed TOXLINE PNIEHS US National Toxicology Program NTP Search All Reports Report on Carcinogens RoC 11th Report on Carcinogens Publications Technical Reports amp Abstracts Environmental Health Perspectives EHP PATSDR Toxicological Profile Information Sheet X Toxicological Profile ATSDR ToxFAQs NIOSH NIOSH Pocket Guide NIOSH Critical Documents PEPA Chemicals In EnvironmentOPPT Chemical Fact Sheets o Envirofacts Master Chemical Integrator EMCI IRIS Database for Risk Assessment PStates of New Jersey Right to Know Hazardous Substance Fact Sheets New Jersey Department of Health PCAS EINECS ICSC pHSDB Hazardous Substances Data Bank ECB European Chemicals Bureau EC Joint Research Centre Classification amp Labelling EHO ESIS IARC o IARC
68. Trichloromethane Trichloroform CHCIs CI CI 67 66 3 2 37 4 99
69. 2009 09 18 03 1234 5678 03 1234 5678 03 1234 5678 http www jaish gr jp anzen gmsds 0024 html 2010 05 14 14 18 35
70. 4 2 CROCUS
71. B 1 S 2 A AEBREN H21 4 8 2 1 1 2 2 kenane gt z E Eb 3
72. 6 1 ICSC 1994 2 Merck 13th 2001 3 IMDG 2004 4 1991 5 SRC 2006 http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08 6 7 8 9 HSDB 2005 Lange 16th 2005 Patty 5th 2001 IUCLID 2000 ACGIH 2001 RTECS 2004 0 1 2 HSFS 2000 1 1 1 z SITTIG 47th 2002 ICSC J 1994 Chapman 2005 Lange 16th 2005 GESTICS 2005 Howard 1997 4 5 6 7 8 Weiss 2 1985 20 DFGOTvol 3 1991 21 Verschueren 4th 2003 22 CERI 2002 23 IARC Monographs Vol 71 1999 24 PHYSPROP Database 25 Ullmanns E 5th 1995 p325 327 26 Gangolli vol 1 1st 1992 p456 459 27 SRC Access on Oct 2005 28 IRIS 2005 MSDS GHS MSDS http www jaish grJp anzen gmsds 0597 html 2010 05 14 14 14 08 XART OSAKA CITY Pl English A py M Fran ais Espa ol M Portugu s 20249
73. INTOX Global assessment of the state of the science of endocrine disruptors IPCS ILO International Chemical Safety Cards ICSC OECD OECD Integrated Database Published OECD SIDS initial assessments of chemicals UNEP Chemicals o Screening Information Dataset SIDS for High Volume Chemicals European Commission Joint Research Centre JRC o ESIS European chemical Substance Information System EINECS ELINCS IUCLID NLM National Library of Medicine TOXNET HSDB Hazardous Substances Data Bank NLM IRIS Integrated Risk Information System CCRIS Chemical Carcinogenesis Research Information System Genetic Toxicology
74. IS 2005 33 2 2003 ALGY 35 163 1994 36 EU Annex 2005 37 Gangolli 2 1999 38 39 40 1 2 43 34 NICNAS 2000 1991 IARC 73 1999 J Occup Health 45 137 139 2003 Eur Respr J 25 1 201 204 2005 CICAD 58 2004 44 NTP DB Access on Dec 2005 45 NTP RoC 11th 2005 46 ACGIH 2001 47 1996 48 49 50 51 52 A Ullmanns 5th 1995 IRIS Access Aug 2005 CERI NITE No 16 2004 NFPA 2001 http www jaish grJp anzen gmsds 0024 html 2010 05 14 14 18 35 53 NITE No 16 2005 54 ACGIH TLV 2005 55 Dean 15th Ed 1 2 MSDS GHS MSDS
75. Pow 0 21 EST 5 4 1 10 NOx
76. TLV TWA 2ppm TLV STEL 4ppm
77. p anzen gmsds 0597 html 2010 05 14 14 14 08 13 14 UN No Proper Shipping Class Sub Risk Packing Group Marine Pollutant UN No Proper Shipping 10 1A 1 1 in vitro 20 in vivo 2 20 9 IARC
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