CHIRALPAK® AS
Contents
1. 4 0 10 00011 CHIRALPAK AD AS OP OT CHIRALCEL OA OB OC OD OF 0G OJ OK CROWNPAK CR CR CHIRALPAK AGP CBH HSA P202. 8 3um 5um 10um 20um 3 um CHIRALPAK AD 3 AD H AD CHIRALPAK AS 3 AS H AS CHIRALPAK _ AY 3 AY H CHIRALPAK AZ 3 AZ H 10070 07100 10070 0 100 CHIRALCEL OD 3 OD H OD CHIRALCEL 0J 3 0J H 0J CHIRALCEL OX 3 OX H CHIRALCEL 0Z 3 0Z H 1 CHIRALPAK AD
3. 20mm ID 20 X mg 5 mp x 20 AX EE 35mn 1 4 6min Benzoin ethyl ether J SE 0 0 0 20 SO A 0 G0 0 Time min EE 71min 2 59min 3 8 7min 0 Time min Time min 1 4 6mm 1 D X250mmL 5um Hexane Ethyl acetate 40 60 v v 10ml min 40 254nm UV 1 0mg ml 1 0ul 0 001mg 2 CHIRALPAK IA 4 6mm ID X250mmL 5um Hexane Ethyl acetate 40 60 v v 0 5m min 40 310nm UV 65
4. CHIRALPAK AGP CHIRALPAK AGP 1 CHIRALPAK CBH CBH CHIRALPAK HSA
5. CROWNPAK CHIRALPAK OP OT CHIRALPAKe OT 0 5 P 21 CROWNPAK CR CR CHIRALPAK ON AX OD AX CROWNPAK CR CR mm 4 MA PAK CR 8 18 crown 6 ether 10 150 5 27734 coated on silca gel 70 4 150 5 28714 CR 10 150 5 28734 WI 4 10 5 GA CROWNPAK CR CR CR R 18 crown 6 ether coated on silica gel coated on silica gel CHIRALPAK ON AX
6. 2 DMF DMSO THF CHIRALPAK AZ 3 AZ H P05 CHIRALPAK AD 3 em ur CHIRALPAK AD 3 a 19594 250 3 19595 4 6 50 3 19522 4 6 100 3 19523 4 6 150 5 19524 4 6 250 3 19525 2 4 10 3 IM 1 1 3 CHIRALPAK AD FH 8 rm 2 P24 CHIRALPAK AD H ER 5 19394 4 1 250 1
7. nk 1 P15 CHIRALPAK IA Solvent versatility of immobilized 3 5 dimethylphenyIcarbamate of amylose in enantiomeric separations by HPLC Journal of Chromatography A 1075 2005 65 5 CHIRALPAKY IB Cellulose 3 5 dimethylphenylcarbamate immobilized on silica A new chiral stationary phase for the analysis of enantiomers Analytica Chimica Acta 557 2006 221 228 CHIRALPAK IC Cellulose tris 3 5 dichlorophenyIcarbamate immobilised on silica A novel chiral stationary phase for resolution of enantiomers Journal of Pharmaceutical and Biomedical Analysis 46 2008 882 891 Common approaches for efcient method development with immobilised polysaccharide derived chiral stationary phases Journal of Chromatography B 875 2008 48 56 Enantiomer resolution screening strategy usind multiple immobilised polysaccharide based chiral stationary phases Journal of Chromatography A 1191 2008 2
8. SFC SFC POR SFC SFC SFC P25 CHIRALPAK IA 3 SFC 1A SFC HB 3 SFC 1B SFC 1C 3 SFC IC SFC CHIRALPAK IA 3 SF C mm hm 5
9. 10mg MI IA 3 CPI e mail Chiral jp daicel com P34 tox 0120 780 104 I el lt IANlhs SE Di IE S JI NE Nw MI NN wl NN EA NE A JI NN EA iI EY 3um CHIRALPAK IA 3 5
10. mm 2 50 5 34792 2 100 5 34793 2 150 34794 2 2 10 5 34791 9 50 5 34782 3 100 5 34783 3 150 34784 2 3 10 5 34781 4 50 34712 4 100 5 34713 4 150 5 34714 12 4 10 5 34711 10 100 5 34733 10 150 5 34734 CHIRALPAK AGP CBH HSA 10 um 00081 20 2mm 3mm 4mm 8 Nd nA nas lo Nt w MI 4S uy NEA NE Nr lt
11. CHIRALPAK IA IB IC ID IE IF 6 THF DMSO HPLC
12. 1 CHIRALPAK WH 2 CHIRALPAKe MA 3 CHIRALPAK OP CHIRALPAK OT N N IE SS mM
13. P24 CHIRALCEL OD E mm Fam er 4 6 250 10 14025 4 6 50 10 14022 10 250 10 14035 CHIRALCEL 10 50 10 14032 0 5 20 250 10 14045 20 50 10 14042 50 500 20 14256 50 100 20 14253 P09 CHIRALCEL OJ 3 0J H OJ CHIRALCEL 0J 2A EE EDC CHIRALCEL OJ 3 2 1 150 3 17594 2 1 250 3 17595 4 6 50 3 7522 4 6 100 3 17523 4 6 150 3 17524 4 6 250 3 17525 0 4 10 3 SM 1 1 3 CHIRALCEL OJ H 2 EE EN We CHIRALCEL 0 2 P24 2 1 150 9 17394 2 1 250 5 17395 4
14. P24 CHIRALPAK Em Cellulose tris 3 5 dichlorophenylcarbamate immobilized to silica gel N CI H EK 83394 2 250 63395 4 6 150 63324 4 6 250 63325 CHIRALPAK7 NAS UM 2 4 10 83311 10 250 63335 nl 20 250 5 83345 10 20 83337 mlHK 2 50 500 20 83256 50 100 20 83253 1 1 3 2 P24 CHIRALPAK ID 3 mm Rs mm IEEE rr 2 150 3 84594 21 250 3 84595 CHIRALPAKe 4 6 50 3 84522 ID 3 4 6 100 3 84523 4 6 150 3 84524 4 6 250 3 84525 2 4 10 3 84511 1 1 3 2
15. CHIRALPAK WH CHIRALPAK MA P35 Ds Ne J 4 Ca i 4 es 22 ck LS 0 mg s LON lt mg g HPLC j Kg SFC c GMP SMB B Kg ton SMB P SMB C S
16. P 24 150 3 86394 2 250 66395 4 6 150 5 86324 4 6 250 86325 9 4 10 5 86311 10 250 66335 nA 20 250 3 86345 10 20 86337 1 1 3 P04 2 P24 Amylose tris 3 chloro 4 methylphenylcarbamate immobilized to silica gel INNIh NNIET J lo dt i iin S ir IE 2 9IGN JI S MI a 4 mI NEN t I NE AN NEN Nr kt
17. 00M07 00M08 00M09 Di NIE mI EY I EN S mi NE DiI IE S I EY lt Iyl NN EA mI NE Nr tt APPLICATION GUIDE Version 4 700 Search EET mo Compound Name 7 results Bn CHIRALFLASH
18. 10070 85 15 40 60 0 100 2 CHIRALCEL OC H OG OF CHIRALPAK AD 3 AD H AD CHIRALPAK AS 3 AS H AS CHIRALPAK AY 3 AY H CHIRALCELY OD 3 OD H OD CHIRALCEL Y 0J 3 0J H 0J CHIRALCEL 0Z 3 0Z H 1 2
19. P24 CHIRALCEL 0Z RH n Cellulose derivative coated on silica gel ED mm um ET TE 6 MT ls CI CHIRALCEL CHs 7 1 1 3 2 P24 P18 NB ir NIE S Yio Nt Di NIE dA S MI ii EN do ll NN TEA mir IE Nr tt CHIRALPAK AGP CHIRALPAKY CBH CHIRALPAK AGP CHIRALPAK HSA CHIRALPAK AGP
20. P24 CHIRALPAK ID_ KB 1 5 5 84394 21 250 5 84395 4 6 150 5 84324 1 46 250 5 84325 4 10 5 84311 10 250 5 84335 20 250 5 84345 10 20 5 84337 1 1 3 2 P24 Amylose tris 3 chlorophenylcarbamate immobilized to silica gel RO OR OZ Amylose derivative immobilized to silica ge P03 CHIRALPAK IE 3 1E IF 3 IF CHIRALPAK IE mm CHIRALPAK IE 3 mm 150 2 1 250 4 6 50 4 6 100 4 6 150 4 6 250 2 4 10 um CO Ww wl uo ll uw ll CO 65594 65595 85522 65523 85524 85525 8551 1 1 1 3 CHIRALPAK IE m
21. mi in NIE 1 1 3 2 P24 CHIRALPAK AS mm f 2 2 1 cr 46 CHIRALPAK gt AMg AS 3 4 6 46 46 2 4 CHIRALPAK AS H R 2 1 4 6 CHIRALPAK 4 6 AS H 2 4 10 20 10 7 CHIRALPAK AS 2 TR 8 4 6 8 10 R76 10 P AS 20 20 50 i 50
22. P24 CHIRALPAK AY IL RS mm 7 Cm CHIRALPAK AY H 2 1 150 9 47394 2 1 250 47395 4 6 150 47324 4 6 250 47325 12 4 10 9 47311 10 250 47335 IES HU24 20 250 9 47345 10 20 9 47337 1 1 3 CHIRALPAK AZ 3 2 P 24 mm mm Cm CHIRALPAK AZ 3 re 2 150 3 61594 250 3 61595 4 6 50 3 061922 4 6 100 3 61523 4 6 150 3 61524 4 6 250 3 61525 2 4 10 3 61511 1 1 3 2 P24 CHIRALPAK AZ H mn 8
23. 2 1mm LC MS CHIRALCELY OD 3R OD RH OD R CHIRALPAK _AD 3R AD RH CHIRALCEL 0J 3R 0J RH CHIRALPAK AS 3R AS RH CHIRALCEL Y OX 3R OX RH CHIRALPAK AY 3R AY RH CHIRALCEL 0Z 3R 0Z RH CHIRALPAK AZ 3R AZ RH 60 40 v v pH2 60 40 V V pH2 60 40 v v 20mM pH9 60 40 v v 0 1M KPFe 20mM pH9 60 40 v v 60 40 v v 1 20mM pH9 P1 4 Ne pH pH
24. P15 CHIRALPAK AD 3R CHIRALPAK AD RH CHIRALPAK AD 3R AD RH AS 3R AS RH AY R AY RH 1 2556 6 5 1 Mm 1 lt 6 so 3 1 1 3 CHIRALPAK AD RH_ ET 46 5 5 mm mm um 2 P24 um 1 1 3 CHIRALPAK AS 3 R 1 1 3 mm mm 2 P24 a CHIRALPAK AS 3R um 2 P 24 CHIRALPAK AS RH_ um a CHIRALPAK AD 3R_ Amylose tris 3 5 dimethylphenylcarbamate coated on silica del Amylose tris ez methylbenzylcarbamate coated on silica gel mii IE
25. 20um HPLC HPLC 20um 4 6X100mm CHIRALFLASH X mm 30X100 mm 38X150 IA 20um IC 20um 9 40 MPa 1 5 gt as EE THF 1 CHIRALFLASH IA IC P31 CHIRALFLASH IA IC mm mm um 9 Amylose tris 3 5 dimethylphenylcarbamate immobilized to silica gel G CHs CHIRALFLASH 30 100 20 40 80M73 9 A A
26. CHIRALPAK IE SFC CHIRALPAKe IE SFC 30 lp 20 mm um 86S94 86595 CHIRALPAKe IF 3 SFC PE 86S25 4 6 86424 CHIRALPAK IF SFC 2 2 P27 CHIRALPAK AD 3 SFC AD H SFC AS 3 SFC AS H SFC AY 3 SFC AY H SFC CHIRALPAK AD 3 SFC mm f 21 150 3 19594 21 250 3 19595 CHIRALPAK AD 3 SFC 46 150 3 19524 46 250 3 19525 CHIRALPAK AD H SFC 2 mm Rmm 4 em 150 5 19424 250 19425 CHIRALPAKe AD H SFC a CHIRALPAK AS 3 SFC mm mm SE 21 150 3 21 250 3 CHIRALPAKS AS 3 SFC 4 6 150 3 20524 4 6 250 3 20S25 CHIRALPAK AS H SFC
27. P 24 NIA MI EE 4 NII NII AT ul Pi9IGN 4 SS 3 nhn JI A bail I NN EA Nr lt St do NE SFC eg SFC 2 CO2 CO02 CO2
28. 21 5 63394 21 5 63395 46 150 5 63324 GIITNKGH 4 6 250 5 63325 6 2 4 5 63311 10 5 63335 20 250 5 63345 10 5 63337 1 1 3 2 P24 CHIRALCEL 0Z 3 8 2 1 150 3 42594 2 1 250 3 42595 Cellulose tris 3 chloro 4 methylphenylcarbamate CHIRALCEL 4 6 50 3 42522 coated on silica gel 0 4 3 4 6 100 3 42523 4 6 150 3 42524 4 6 250 3 42525 4 10 3 42511 1 1 3 2 P24 CHIRALCEL 0Z H PB 150 5 42394 2 250 5 42395 4 6 150 5 42324 CHIRALCEL
29. mm mm um 150 5 20424 250 5 20425 CHIRALPAK AS H SFC 10 250 5 20435 20 250 5 20445 ET PER 2 1 150 250 47S95 CHIRALPAKe AY 3 SFC 22 4 6 150 47S24 CO CD uw Lu CHIRALPAK AY HFC CHIRALPAKe AY H SFC 9 5 47424 250 5 47425 VR 5 20 250 5 47445 P28 Nir NE gt nmi IT W NB m I MI MI Y vieT MiT EE 3 Nr lt NB ute EER a Fudsut SS MI 4
30. NAN NE Ni Nr lt CHIRALPAK AZ 3 SFC AZ H SFC CHIRALCEL OD 3 SFC OD H SFC 0J 3 SFC 0J H SFC CHIRALPAK AZ 3 SFC EE EHP 150 3 61594 2 1 250 3 61S95 CHIRALPAK AZ 3 SFC 46 150 3 61S24 4 6 250 3 61S25 CHIRALPAK AZ H SFC EE hm 150 5 61424 5 CHIRALPAK AZ SFC 6 5 CHIRALCEL CHIRALCELe OD 3 SFC uum 3 14S94 250 3 14595 3 250 3 14525 CHIRALCEL EZ 4 6 150 5 14424 4 6 250 5 14425 CHIRALCEL OD H SFC 10 250 5 14435 20 250 5 14445 CHIRALCEL 0J 3 SFC mm mm um 3 17S94 3 17595 CHIRALCEL OJ 3 SFC 7323 250 3 17S25 CHIRALCEL 0J H SFC 9 CHIRALCEL 0J H SFC 2929 17424 17425 99 2 17435 OW ww P29
31. MDAICEL CHIRAL COLUIMNS eh F 3 Le ee a Vol 5 CHIRALPAK IA 3 IA CHIRALPAK IB 3 1B CHIRALPAK IC 3 1C CHIRALPAK ID 3 ID CHIRALPAK IE 3 IE CHIRALPAK IF 3 IF CHIRALPAK AD 3 AD H AD CHIRALPAK AS 3 AS H AS CHIRALPAK AY 3 AY H CHIRALPAK AZ 3 AZ H CHIRALCEL 0D 3 OD H OD CHIRALCEL 0J 3 0J H 0J CHIRALCEL 0X 3 0X H CHIRALCEL 0Z 3 0Z H CHIRALCEL 0B H OB CHIRALCEL OC H OC CHIRALCEL OA CHIRALCEL OF CHIRALCEL OG CHIRALCEL OK CHIRALPAK AD 3R AD RH CHIRALPAK AS 3R AS RH CHIRALPAK AY 3R AY RH CHIRALPAK AZ 3R AZ RH CHIRALCEL 0D 3R OD RH OD R CHIRALCEL 0J 3R 0J RH CHIRALCEL 0X 3R 0X RH CHIRALCEL 0Z 3R 0Z RH CHIRALPAKS AGP CHIRALPAK CBH CHIRALPAK HSA CROWNPAK CR CROWNPAK CR CHIRALPAK QN AX CHIRALPAK QD AX
32. W mm 150 250 50 100 150 250 10 250 150 250 10 250 250 20 50 250 50 250 50 500 100 Wlwl ww wl oO Wg HEEHO OO WO 10 10 10 10 10 20 20 u EEE 20594 20595 20522 20523 20524 20525 20511 1 1 3 2 P24 20394 20395 20324 20325 20311 20335 20345 20337 20025 20022 20035 20032 20045 20042 20256 20253 e methylbenzylcarbamate Amylose derivative coated on sillcagel P07 CHIRALPAK AY 3 AY H AZ 3 AZ H CHIRALPAK AY 3 CHIRALPAK A mm mm um 7 150 3 47594 2 1 250 3 47595 4 6 50 3 47522 4 6 100 3 47523 4 6 150 3 47524 4 6 250 3 47525 2 4 10 3 47511 1 1 3 2
33. HSA CHIRALPAK AGP EEE CHIRALPAK CBH CHIRALPAK HSA yy New approaches of LC MS compatible method development on o1 acid glycoprotein based stationary phase for resolution of enantiomers by HPLC J Sep Sci 2010 33 3627 363 P19 CHIRALPAK AGP CHIRALPAK AGP 0 1 2 CHIRALPAK AGP CBH HSA NE mm 2 50 5 30792 2 100 5 30793 2 150 5 30794 2 2 10 5 30791 3 50 5 30782 3 100 5 30783 3 150 5 30784 wy 2 3 10 5 30781 az 4 50 5 30712 4 100 5 3071
34. Se a HE MI S nn 3 dt AN MiT EE gt Nr lt ii MI S ii NIE 7 S 3 n NN IiNl Mit NE lt SFC CHIRALPAK ID 3 SFC ID SFC IE 3 SFC IE SFC IF 3 SFC IF SFC CHIRALPAK ID 3 SFC 84S94 64S595 CHIRALPAK ID 3 SFC 84524 84S25 sn 84424 64425 CHIRALPAKe ID SFC ogjg CHIRALPAK IE 3 5FC CHIRALPAKe IE 3 SFC 57E
35. 3 80S94 3 80S95 G CHIRALPAK IA 3 SFC 46 150 3 80524 46 250 3 805S25 CHIRALPAK IA SFC EE mm ylPZjp 4 6 150 5 250 80424 80425 CHIRALPAKe IA SFC 2 10 250 80435 2 CHIRALPAK IB 3 SFC mm 2 150 3 81S94 2 1 250 3 81S595 CHIRALPAK IB 3 SFC UP 4 6 150 3 81S24 4 6 250 3 81525 CHIRALPAK IB SFC EE TE EE RS 150 5 81424 4 6 250 5 81425 G CHIRALPAK IB SFC 2 OHK ali 250 5 81435 20 250 5 81445 CHIRALPAK 1IC 3 SFC 5 mm HH 150 3 83S94 21 250 3 83S95 G UTU RS 7 9 46 150 3 83S24 4 6 250 3 83S25 CHIRALPAK 1IC SFC EE EET EE 4 6 150 5 83424 46 250 5 83425 Gy CHIRALPAK IC SFC 10 250 5 83435 20 250 5 83445 P26 4
36. Nia NIE JI 0 mI NE 3 4 S mi IE mI EN I a NE mI NIE NENA iI NE Oi NIE CHIRALPAK AZ 3R AZ RH CHIRALCEL OD 3R OD RH OD R mm ED GND ET MCT ov eo 1 1 3 2 P24 CHIRALPAK AZ RH A CHIRALPAK AZ RH 5 61744 TE CHIRALPAK AZ 3R Amylose tris 3 chloro 4 methylphenylcarbamate coated on silica gel 1 1 3 2 P24 CHIRALCEL OD 3R Pe EE 5 gt 2 1 1 3 2 P24
37. CHIRALCEL OG 4 CHIRALCEL OK CHIRALPAK AGP ol CHIRALPAK CBH CHIRALPAK HSA CROWNPAK CR S 18 6 CROWNPAK CR R 18 6 CHIRALPAK ON AX CHIRALPAK QD AX CHIRALPAK OP o CHIRALPAK OT
38. I NN EA NE A lt JI I InNNIh NIET3 4 3 H Es AI MI A I NN EIN JI lt CHIRALCEL OX 3 OX H 0Z 3 0Z H CHIRALCEL OX 3 2 mm Rm Cm 2 150 3 63594 f 2 1 3 63595 Cellulose tris 4 chloro 3 methylphenylcarbamate CHIRALCELS 4 6 3 G3522 coated on silica gel 0 3 4 6 100 3 63523 4 6 150 3 63524 46 3 63525 2 4 3 63511 1 1 3 2 P24 CHIRALCEL OX H TTY mm mm pm Rn HX
39. mI NE DN NE S iI IE S 3 mI NE MI CHIRALPAK L222 4e to 5 AS RH 2 2 650 5 1 1 3 2 P24 MI CHIRALPAK AY 3R CHIRALPAK AY R Lo2 4e 5 2 6 0 mm mm um Amylose tris 5 chloro 2 methylphenylcarbamate coated on silica gel DiI NE 1 1 3 2 P24 CHIRALPAK AY RH mm mm um Ah 1 1 3 2 P24 P16 NE NA iI NE
40. CHIRALCEL OD RH mm mm um 150 5 14724 150 5 14744 ieH OD RH 1 1 3 2 P24 Cellulose tris 3 5 dimethylphenylcarbamate coated on silica gel n Cellulose derivative Coated on silica del CHs CHIRALCEL OD R mm um CHIRALCEL 5 1 2 14611 1 1 3 2 P24 P17 CHIRALCEL 0J 3R 0OJ RH OX 3R OX RH 0Z R 0Z RH CHIRALCEL OJ 3R mm TB _ 26 ee so MM Cellulose tris 4 methylbenzoate coated on silica gel i ETT 4 9 3 1 1 3 2
41. 201203AP5K w gt a m Nn GG gt
42. P24 CHIRALCEL 0J RH mm CHIRALCEL a 6 mw OJ RH uum 1 1 3 2 P24 CHIRALCEL OX 3R mm um CHIRALCEL mm Pd LPC ss 111 3 2 P24 CHIRALCEL OX RH mm um Cellulose tris 4 chloro 3 methylphenylcarbamate coated on silica gel CHs CHIRALCEL 2 fp2A 6 eo 3 G OX RH 637 6 2 2 20 eo 5 a 1 1 3 2 P24 um a EE ET EE Cellulose tris 3 chloro 4 methylphenylcarbamate coated on silica gel 0 4E 1 1 3 2
43. 20 250 5 80345 10 20 5 80337 50 500 20 80256 50 100 20 80253 1 1 3 2 P24 CHIRALPAK 1IB 3 CHIRALCELS OD 3 5 mm um C 21 150 3 81594 EE io RE a CHIRALPAK a 4 6 50 3 81522 immobilized to silica gel IB 3 4 6 100 3 81523 lt 4 6 150 3 81524 oR M 4 6 250 3 81525 gt 2000MO IA 4 10 8 81511 Cellulose d erivativ 1 1 3 2 P24 Nmmobilized to silica gel e CHIRALPAK IB 2 CHIRALCEL OD H RR mm uF Cm 21 150 5 81394 21 250 5 81395 lt 5 4 6 150 5 81324 WS 46 250 5 813
44. Cm 7B 2 150 CHIRALPAK AZ H 5 61394 4 250 61395 4 6 150 5 61324 4 6 250 61325 2 4 10 61311 10 250 61335 20 250 5 61345 10 20 61337 1 1 3 P08 2 P24 Amylose tris 5 chloro 2 methylphenylcarbamate coated on silica gel Amylose derivative coated on silica gel _ Amylose tris 3 chloro 4 methylphenylcarbamate coated on silica gel Amylose derivative coated on silica gel _ Dm INNIN NNIET3 S Al S Nr S n I NJ ilk pIE I NN EAN A Nr tA di Yl I EEE NB NB i mB S mie
45. NE 9S 3 n il eb Yio do Iy9ll NN IN MI UIEYRHHNI Nr At CHIRALPAK WH MA OP OT CHIRALPAK WH 4 6 250 10 25625 CHIRALPAK WH 4 6 0 10 25622 CHIRALPAK MA 4 6 50 3 21822 CHIRALPAK MA silica ge mm PER 4 6 250 10 22025 CHIRALPAK OP Poly diphenyl 2 pyridyImethy methacrylate CHIRALPAK OP 4 6 50 10 22022 CHIRALPAK OT poly triphenylmethyl methacrylate SE GE EA CHIRALPAK 4 6 250 10 23025 OT 4 6 50 10 33022 P23
46. 0 58 OD cROWNPAK CR CR 18 6 NH3 qaq DL CHIRALPAK QN AX QD AX CHIRALPAK QN AX CHIRALPAK QD AX N N CHIRALPAK WH MA 0 1 2mM Cu
47. CHIRALCEL OX 3 SFC OX H SFC 0Z 3 SFC 0Z H SFC CHIRALCEL OX 3 SFC 2 mm JE 21 150 3 63S94 21 250 3 63595 de 4 6 150 3 63524 4 6 250 3 63S25 0 CHIRALCEL OX HFC 3 4 6 63424 4 6 5 63425 CHIRALCEL OX H SFC 10 250 5 63435 II CHIRALCEL 0 3 FC _ PE 7 150 3 42S94 21 250 3 dil1KddL0 2k7 0 5 8 8 3 C HIRALCEL 0Z HFC 8 mm mm um 7782 46 150 5 42424 sa 4 6 250 5 42425 F C CHIRALCEL OZ H SFC 5 20 250 5 42445 Nr lt P30 IRQuaLAS 1AVI C
48. JI NB lA I NE AN dl Nr tt CHIRALCEL OD 3 OD H OD CHIRALCEL OD 3 mm mm pm 5 150 3 14594 250 3 14595 Cellulose tris 3 5 dimethylphenylcarbamate CHIRALCEL 50 3 II4522 coated on silica el or 100 3 14523 150 3 14524 250 3 14525 10 3 14511 1 1 3 2 P24 CHIRALCEL OD H my Cm f1 150 5 14394 2 250 5 14395 4 6 150 5 14324 CHIRALCEL 4 6 250 5 14325 OD H 2 4 10 5 14311 10 250 5 14335 20 250 5 14345 10 20 5 14337 1 1 3 2
49. 4 6 250 5 42325 0 4 10 5 42311 10 250 5 42335 20 250 5 42345 10 20 5 42337 1 1 3 2 P24 Pl CHIRALCEL OA OB H OB OC H OC CHIRALCEL OA eili7Keds 0A Zoo mm 11025 Cellulose triacetate coated on silica gel mm um PER 2 1 150 5 12394 2 1 250 5 12395 Cellulose tribenzoate dd fed on sg da OB H 46 150 12324 lm 4 6 250 5 12325 2 4 10 5 12311 1 1 3 2 P24 CHIRALCEL OB mm um ddd 4 6 250 10 12025 OB 46 50 10 12022 CHIRALCEL OC H E mm r
50. IMA IPA 2K SO 72 TE A A 2 2 IPA PO1 04 P 05 13 P 15 18 P 19 20 P 21 23 Uo gt FC _ Dir NE 0 MI EERHNNEHh MI EIDRGNWNEHhoT MI S 3 mi NE T iPNINS dl Di NE ml NN EA ii NIE Nr tt i CHIRAL 6 77
51. 14 222 PO1 CHIRALPAK IA 3 1A 1B 3 1B CHIRALPAK 1A 3 CHIRALPAK _AD 3 INNIN NNIE TI mm mm um 2 150 3 80594 5 2 1 250 3 80595 ou CHIRALPAK WAR 4 6 50 3 80522 immobilized to silica gel IA 3 4 6 100 3 80523 46 150 3 80524 46 250 3 80525 2 4 10 3 80511 h 1 1 3 2 P24 CHIRALPAK IA CHIRALPAK AD H sb mm um 21 150 5 80394 21 250 5 80395 46 150 5 80324 A 4 6 250 5 80325 2 4 10 5 80311 0 IA 10 250 5 80335
52. 25 IB 2 4 10 5 81311 7 10 250 5 81335 20 250 5 81345 10 20 5 81337 1 1 3 2 P24 a Nr tt P02 INNIh NNIET3 a Di NE ININ SNIET 7 JI S 8 n MI I NIE do i I NAN NB Nr lt CHIRALPAK IC 3 1C 1D 3 1D CHIRALPAK IC 3 5 83594 x 250 3 83595 CHIRALPAK 4 6 50 3 83522 IC 3 4 6 100 3 83523 4 6 150 3 83524 4 6 250 3 63525 2 NAS UM 4 10 3 83511 1 1 3 2
53. 3 4 150 5 30714 12 4 10 5 30711 10 100 5 30733 10 150 5 30734 CHIRALPAK CBH CHIRALPAK CBH 4 mm mm um a 2 50 5 33792 2 100 5 33793 2 150 9 33794 2 2 10 5 33791 3 50 5 33782 3 100 5 33783 3 150 5 33784 2 3 10 5 33781 4 50 5 5372 4 100 5 33713 4 150 8 33714 2 4 10 5 33711 23 ODN 10 100 5 33733 10 150 5 33734 1 1 2 2 CHIRALPAK HSA CHIRALPAK HSA 1 1 2 2
54. 6 150 5 17324 4 6 250 5 17325 2 4 10 17311 10 250 5 17335 20 250 5 17345 10 20 5 17337 1 1 3 CHIRALCEL 0 CHIRALCEL OJ P10 IE 0NHN gl 4 6 4 6 10 10 20 20 50 50 250 3 3 9 5 9 250 9 9 S 0 100 4 mY 3 2 P24 17025 17022 17035 17032 17045 17042 17256 17253 Cellulose tris 4 methylbenzoate coated on silica gel MI I lo S mm NE Nw JI nN NE 3S 3 MI 1 Ji Ji A et ha
55. 6mg ml 25ul 16 4mg 3 20mm ID X250mmL 5um Hexane Ethyl acetate 40 60 v v 9 4ml min 40 310nm UV 656mg ml 500ul 328mg P14 mili aii SIEIENNRHh NE bi Nr eitihe MI mean JI ii NE do H NE ml Nr lt oc dt oo Ei h G 5 br a
56. 9395 4 6 150 19324 4 6 250 19925 2 4 10 9 10 250 19335 2 20 250 5 19345 10 20 9 19337 1 1 3 CHIRALPAK AD fF Am 2 P 24 CHIRALPAK AD a 10 19025 4 6 50 10 19022 I02S2nIHD iss 10 250 10 19035 10 50 10 19032 IE2S2IHN2N 20 250 10 19045 20 50 10 19042 50 500 20 19256 50 100 20 19253 P06 CHIRALPAK AD 3 AD H AD Amylose tris 3 5 dimethylphenylcarbamate coated on silica gel NE W I Nl MI 43 Ps JI wiE ejp h JI MI 4 NN EAN Nl RT In 9r MI MI CHIRALPAK AS 3 AS H AS
57. ALPAKY AD CHIRALPAK AD 3R CHIRALPAK AD RH 3 5 CHIRALPAK AS 3 CHIRALPAK AS H CHIRALPAK AS CHIRALPAK AS 3R CHIRALPAK AS RH v CHIRALPAK AY 3 CHIRALPAK AZ 3 CHIRALPAK AY H CHIRALPAK AZ H CHIRALPAK AY 3R CHIRALPAKY AZ 3R CHIRALPAK AY RH CHIRALPAKY AZ RH 5 2 3 4 CHIRALCEL OD 3 CHIRALCEL OD H CHIRALCEL OD CHIRALCEL OD 3R CHIRALCEL OD RH CHIRALCEL OD R 3 5 CHIRALCEL 0J 3 CHIRALCEL 0J H CHIRALCEL OJ CHIRALCEL 0J 3R CHI
58. MB C gt gt y LeYczmm P36 i NE AI IN S SN bavihe ININ IET 3S 3 hn I Al I NN i A Nr tt OAICEL The Best Solution for You CPI 108 8230 2 18 1 JR 14F TEL 03 6711 8222 FAX 03 6711 8228 530 0001 3 4 5 20F TEL 06 6342 6161 FAX 06 6342 6168 http www daicelchiralcom E mailchiral jp daicel com E mail chiral chiraltech com E mail cte chiral fr TEL 65 6327 2038 TEL 86 21 5046 0086 TEL 91 40 2348 0103
59. OD AX um 4 6 150 5 32324 II 2 4 10 5 32311 CHIRALPAK QN AX 88 9R ON AX 21 150 5 32394 EBM 20 150 5 32344 4 6 150 5 31324 II 2 4 10 5 31311 QD AX 150 5 31394 20 150 5 31344 1 1 3 2 P24 22 MI 0 NAN JI INNIN NNIET3 S MI NI SU Mit NN EAN dio Ni lt NB MI do S iiihe mI
60. OK CHIRALCEL OF EE 4 6 250 10 CHIRALCEL OF 15025 4 6 50 10 15022 10 250 10 15035 10 50 10 15032 1 9NHO2 2 20 250 10 15045 20 50 10 15042 CHIRALCEL 0 C mm jm 4 6 250 10 16025 46 50 10 16022 Cellulose tris 4 chlorophenylcarbamate coated on silica del O RO OR n Cellulose derivative Cellulose tris 4 methylphenylcarbamate coated on silica gel O RO O Cellulose de O R n rivative coated on sil ica 9el CHIRALCEL OK CHIRALCEL J TE EE 4 6 250 10 18025 4 6 50 10 18022 Cellulose tricinnamate coated on silica gel O RO O Coated on sil Cellulose derivative ica gel
61. RALCEL 0J RH 4 CHIRALCEL 0X 3 CHIRALCELY OX H CHIRALCEL 0X 3R CHIRALCEL OX RH 4 3 CHIRALCEL 0Z 3 CHIRALCELY 0Z H CHIRALCEL 0Z 3R CHIRALCEL Y 0Z RH 3 4 CHIRALCEL OB H CHIRALCEL OA CHIRALCEL OB CHIRALCEL OC H CHIRALCEL OC CHIRALCEL OF 4
62. m 1 SE 2 150 5 13394 2 1 250 5 13395 Cellulose tris dd ienearb OC H 46 150 5 13324 I 4 6 250 5 13325 2 4 10 5 13311 1 1 3 2 P24 CHIRALCEL OC CHIRALCEL mm 13025 P12 I lo mE 4 Nl NejE wa h JI MI MI N AN MI Nr tt NE I No Nt NEN A S JI Nt I NN EA Nr tt CHIRALCEL OF OG
63. m CHIRALPAK IE 2 P24 mm 150 5 85394 2 250 5 85395 4 6 150 5 85324 4 6 250 5 85325 2 4 10 5 85311 10 250 5 85335 20 250 5 85345 10 20 5 85337 1 1 3 2 P24 Amylose tris 3 5 dichlorophenylcarbamate immobilized to silica gel O RO OR OZ Amylose derivative Immobilized to silica ge CHIRALPAK IF 3 CHIRALPAK IF 3 mm um l 150 3 86594 2 1 250 3 86595 4 6 50 3 86522 4 6 100 3 86523 4 6 150 3 86524 4 6 250 3 86525 yl ga 2 12 4 10 3 86511 1 1 3 CHIRALPAK IF CHIRALPAK IF 2
64. mylose derivative O Immobilized to silica ge R os N CHs Cellulose tris 3 5 dichlorophenylcarbamate immobilized to silica gel CHIRALFLASH e 30 100 20 40 HPLC mm um 100 20 100 20 hn HN i i dB AS M 20 26 S 00M10 M 00M11 00M12 1 4 28UNF 1 4 28UNF 1 4 28UNF 1 4 28UNF 00M07 2 2 00M05 1 4 28UNF 00M08 1 4 28UNF 00M09 5 00M13 M 00M14 a 00M15 00M04 00M05 00MO6
65. um CHIRALPAK IA 10um 3um 5um 10um 3 5 CHIRALPAK IB 3 CHIRALPAK IB 3 5 CHIRALPAK IC 3 CHIRALPAK IC 3 5 CHIRALPAK ID 3 CHIRALPAKYID 3 CHIRALPAK IE 3 CHIRALPAK IE 3 5 CHIRALPAK IF 3 CHIRALPAK IF 3 4 CHIRALPAK AD 3 CHIRALPAK AD H CHIR
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