Sharp MX-4111N MSDS
Contents
1. Europe Italy Sharp Electronics Italy S P A Via Lampedusa 13 20141 Milano Telephone number 02895951 Spain Sharp Electronics Espana S A Calle Sena 2 10 Poligono Industrial Can Sant Joan Parcela 8 08174 Sant Cugat Del Valles Telephone number 93 581 97 00 Netherlands Sharp Electronics Benelux B V P B 900 Meidoornkade 10 3992 AE Houten Telephone number 30 6359500 Sweden Sharp Electronics Nordic AB Box 14098 Gustavslundsvagen 12 SE 167 14 Bromma Telephone number 08 634 36 00 Switzerland Sharp Electronics Schweiz AG Moosstrasse 2 Postfach 321 8803 Ruschlikon Telephone number 01 846 6111 Middle U A E Sharp Middle East FZE l l East P O Box 17115 Jebel Ali Dubai Telephone number 04 8815311 SHARP MATERIAL SAFETY DATA SHEET Page 2 5 Date Issued Nov 5 2010 MSDS No F 01991 2 COMPOSITION INFORMATION ON INGREDIENTS Substance Preparation X Ingredient CAS No Proportion OSHAPEL ACGIHTLV MAK TWA NOHSC TWA Polyester resin Confidential 80 90 Not listed Not listed Not listed Not listed Carbon black 1333 86 4 5 10 3 5mg m 3 5mg m Not listed 3mg m Wax Confidential 1 5 Not listed Not listed Not listed Not listed Iron Oxide 1309 38 2 1 5 Not listed Not listed Not listed Not listed Amorphous silica 68909 20 6 1 5 80mg m 2mg m Not listed Not listed 3 HAZARDS IDENTIFICATION Most Important Hazards and Effects of the Products Human Health Effects There are no anticipated carcinogenic effe2. is released It like most finely divided organic powders is capable of creating a dust explosion SHARP MATERIAL SAFETY DATA SHEET Page 3 5 Date Issued Nov 5 2010 MSDS No F 01991 7 HANDLING AND STORAGE Handling Technical Measures None Precautions None Safe Handling Advice Use of a dust mask is recommended when handling a large quantity of toner or during long term exposure as with any non toxic dust Try not to disperse the particles Storage Technical Measures None Storage Conditions Keep container closed and Store in a cool and dry place Keep out of the reach of children Incompatible Products None 8 EXPOSURE CONTROLS PERSONAL PROTECTION Engineering Measures Ventilation Not required under intended use Exposure limit values OSHA PEL USA 15mg m Total Dust 5mg m Respirable Dust ACGIH TLV USA 10mg m Total Dust 3mg m Respirable Dust Personal Protective Equipment Respiratory Protection None required when used as intended in Sharp equipment Hand Protection None required when used as intended in Sharp equipment Eye Protection None required when used as intended in Sharp equipment Skin Protection None required when used as intended in Sharp equipment Other Protective Equipment Use of a dust mask and goggles are recommended when handling a large quantity of toner or during long term exposure as with any non toxic dust 9 PHYSICAL AND CHEMICAL PROPE
3. 5 2010 MSDS No F 01991 15 16 REGULATORY INFORMATION US Information TSCA Toxic Substances Control Act All chemical substances in this product comply with all applicable rules or order under TSCA SARA Superfund Amendments and Reauthorization Act Title III 302 Extreme Hazardous Substance None 311 312 Hazard Classification None EU Information 1999 45 EC and 67 548 EEC Symbol amp Indication Not required R Phrase Not required 76 769 EEC All chemical substances in this product comply with all applicable rules or order under 76 769 EEC OTHER INFORMATION NFPA Rating USA Health 1 Flammability 1 Reactivity 0 WHMIS Legislation Canada This product is not a controlled product References IARC 1996 IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans Vol 65 Printing Process And Printing Inks Carbon Black and Some Nitro Compounds Lyon pp 149 261 H Muhle B Bellmann O Creutzenberg C Dasenbrock H Ernst R Kilpper J C MacKenzie P Morrow U Mohr S Takenaka and R Mermelstein 1991 Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats Fundamental and Applied Toxicology 17 pp 280 299 The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions However all materials may present unknown hazards and should be used with caution Although certain hazards are described herein
4. RTIES Appearance Physical State Solid Form Powder Color Black Odor odorless Ph Not applicable Boiling Melting Point Not applicable Softening Point C 100 130 Flash Point C Not applicable Ignition Point C No data Explosion Properties No data Density g cm Approx 1 1 bulk density Approx 0 4 Solubility in water Negligible 10 STABILITY AND REACTIVITY Stability Stable Hazardous Reactions Dust explosion like most finely divided organic powders Conditions to Avoid Electric discharge throwing into fire Materials to Avoid Oxidizing Materials Hazardous Decomposition Products CO CO and NOx Further Information None SHARP MATERIAL SAFETY DATA SHEET Page 4 5 Date Issued Nov 5 2010 MSDS No F 01991 11 TOXICOLOGICAL INFORMATION 12 Acute Toxicity Ingestion oral Inhalation Eye irritation Skin irritation Skin sensitizer Mutagenicity Carcinogenicity Chronic Effect Ecotoxicity LDs9 gt 2000mg kg Rats LCso gt 5 00mg I Rat 4hr Not an irritant Rabbits Not an irritant Rabbits Not sensitized Negative Ames Test In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen possible human carcinogen This classification is given to chemicals for which there is inadequate human evidence but sufficient animal evidence on which to base an opinion of carcinogenicity The classification is based upon the development of lung tumors in
5. SHARP MATERIAL SAFETY DATA SHEET Page 1 5 Date Issued Nov 5 2010 MSDS No F 01991 1 PRODUCT AND COMPANY IDENTIFICATION Product Name MX 51NT BA MX 51GT BA MX 51FT BA MX 51AT BA MX 51BT BA Black Toner Supplier Identification Sharp Corporation 22 22 Nagaike cho Abeno ku Osaka Japan Local suppliers are listed below Please contact the nearest supplier for additional information Area Country Local suppliers U S A Sharp Electronics Corporation Sharp Plaza Mahwah New Jersey 07495 1163 Telephone number 800 237 4277 North Emergency telephone number 800 255 3924 America Canada Sharp Electronics of Canada Ltd 335 Britannia Road East Mississauga Ontario L4Z 1W9 Telephone number 905 890 2100 Emergency telephone number 1 800 255 3924 Australia Sharp Corporation of Australia PTY Ltd Oceania No1 Huntingwood Drive Huntingwood Blacktown N S W Telephone number 1800 13 50 22 Germany Sharp Electronics Europe GMBH Sonninstrasse 3 20097 Hamburg Telephone number 040 2376 2185 United Sharp Electronics U K Ltd Kingdom 4 Furzeground Way Stockley Park Uxbridge Middlesex UB11 1EZ Telephone number 08705 274 277 France Sharp Electronics France S A 22 Avenue des Nations Paris Nord 2 BP 52094 95948 Roissy Charles de Gaulle Cedex Telephone number 01 49 90 34 00 Austria Sharp Electronics Europe GmbH Handelskai 342 1020 Wien Telephone number 01 727 19 0
6. cts from exposure based on animal tests performed using toner When used as intended according to instructions studies do not indicate any symptoms of fibrosis will occur Environmental Effects Not toxic to aquatic organisms Specific hazards Dust explosion like most finely divided organic powders Directive 1999 45 EC Europe Not classified as dangerous Australian Information Not classified as hazardous according to criteria of NOHSC 4 FIRST AID MEASURES Route s of Eniry Inhalation Skin Ingestion Yes No Possible but very unusual Inhalation Remove to fresh air If symptoms occur consult medical personnel Skin Contact Wash with soap and water for 15 minutes or until particle is removed If irritation does occur consult medical personnel Eye Contact flush eyes immediately with water for 15 minutes If irritation does occur consult medical personnel Ingestion Rinse with water and drink several glasses of water If irritation or discomfort does occur consult medical personnel 5 FIRE FIGHTING MEASURES Extinguishing Media Water COs foam and dry chemicals Special Fire fighting Procedures None Fire and Explosion Hazards Toner material like most finely divided organic powders may form an explosive mixture 6 ACCIDENTAL RELEASE MEASURES Personal Precautions None Environmental Precautions None Methods for Cleaning Up Wipe off with paper or cloth Do not use vacuum cleaner when a large amount
7. rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung Studies performed in animal models other than rats did not show any association between carbon black and lung tumors Moreover a two year cancer bioassay using a typical toner preparation where carbon black is bound in a resin matrix demonstrated no association between toner exposure and tumor development in rats In a study in rats of chronic inhalation exposure to a typical toner a mild to moderate degree of lung fibrosis was observed in 92 of the rats in the high concentration 16mg m exposure group and a minimal to mild degree of fibrosis was noted in22 of the animals in the middle 4mg m exposure group but no pulmonary change was reported in the lowest 1 mg m exposure group the most relevant level to potential human exposures ECOLOGICAL INFORMATION On available data toner is not harmful to aquatic organisms DISPOSAL CONSIDERATIONS Waste from residues Waste material may be dumped or incinerated under conditions which meet all federal 13 14 state and local environmental regulations Contaminated Packaging Waste may be disposed or incinerated under conditions which meet all federal state UN Classification and local environmental regulations TRANSPORT INFORMATION None Not classified as hazardous for transport SHARP MATERIAL SAFETY DATA SHEET Page 5 5 Date Issued Nov
8. we do not guarantee that these are the only hazards which exist
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