Kidde 466727 Data Sheet
Contents
1. Bioaccumulative Potential No relevant studies identified Other adverse effects No relevant studies identified DISPOSAL CONSIDERATIONS Disposal Methods Dispose of container in accordance with all applicable local and national regulations Do not cut puncture or weld on or near to the container If spilled contents will vaporize to the atmosphere TRANSPORT INFORMATION Safety Data Sheet information is intended to address a specific material and not various forms or states of containment Specific volumes pressures or hardware configurations containing such materials can dictate various different hazard classifications for transportation and labelling requirements Under Federal Regulations only trained and qualified individuals are permitted to label and ship products following the applicable Department of Transportation DOT Federal Aviation Administration FAA Transport Canada TC International Maritime Dangerous Goods IMDG or International Air Transport Association IATA requirements Revision Date April 10 2015 Page 7 of 9 BA Ki d d e SAFETY DATA SHEET A Halotron 1 15 16 h Fire Extinguishing Agent with Expellant REGULATORY INFORMATION United States TSCA Inventory All components of this product are in compliance with the inventory listing requirements of the US Toxic Substance Control Act TSCA Chemical Substance Inventory Canada DSL Inventory All ingredients in this product have been verif2. ETY DATA SHEET r Halotron 1 h Fire Extinguishing Agent with Expellant 16 OTHER INFORMATION Prepared By EnviroNet LLC The information and recommendations presented in this SDS are based on sources believed to be accurate Kidde Residential amp Commercial assumes no liability for the accuracy or completeness of this information It is the user s responsibility to determine the suitability of the material for their particular purposes In particular we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY EXPRESS OR IMPLIED with respect to such information and we assume no liability resulting from its use Users should ensure that any use or disposal of the material is in accordance with applicable Federal State and local laws and regulations Revision Date April 10 2015 Page 9 of 9
3. a confined space are provided on the label of the extinguisher Appropriate engineering controls Use with adequate ventilation There should be local procedures for the selection training inspection and maintenance of this equipment When used in large volumes or odor becomes apparent use local exhaust ventilation Individual protection measures Respiratory Protection Not normally required under conditions of use as a portable fire extinguisher In oxygen deficient atmospheres use a self contained breathing apparatus as an air purifying respirator will not provide protection Skin Protection Neoprene PVC or PVA gloves Eye Face Protection Chemical goggles or safety glasses with side shields Body Protection Normal work wear 9 PHYSICAL AND CHEMICAL PROPERTIES Agent Halotron 1 Appearance Physical State Liquefied gas under pressure Color Colorless Odor Slight ether like Odor Threshold No data available Revision Date April 10 2015 Page 4 of 9 g Kidde r United Technologies SAFETY DATA SHEET Halotron 1 Fire Extinguishing Agent with Expellant PHYSICAL AND CHEMICAL PROPERTIES pH Relative Density Air 1 Liquid Density Gas Density Boiling Range Point C F Melting Point C F Flash Point PMCC C F Vapor Pressure of liquid Evaporation Rate BuAc 1 Solubility in Water Vapor Density Air 1 VOC Partition coefficient n octanol water Viscosity Auto ignition Temper
4. amines such as adrenaline or similar compounds can increase susceptibility to heart irregularities caused by excessive exposure to these types of compounds 5 FIRE FIGHTING MEASURES Suitable Extinguishing Media Halotron 1 is used as an extinguishing agent and therefore is not a problem when trying to control a fire Use extinguishing agent appropriate to other materials involved Keep containers and surroundings cool with water spray as containers may rupture or burst in the heat of a fire The concentrated agent when applied to fire can produce toxic by products specifically hydrogen halides which can cause damage Avoid inhalation of these materials by evacuating and ventilating the area Specific hazards arising from the chemical Containers may explode in heat of fire Special Protective Actions for Fire Fighters Wear full protective clothing and self contained breathing apparatus as appropriate for specific fire conditions 6 ACCIDENTAL RELEASE MEASURES Personal precautions protective equipment and emergency procedures Remove leaking cylinder to a safe place Ventilate the area Vapors can accumulate in low areas Leaks inside confined spaces may cause suffocation as oxygen is displaced and should not be entered without a self contained breathing apparatus Manufacturers Recommended 1 Hr Emergency Exposure Limit 1000ppm v v Manufacturers Recommended 1 Min Emergency Exposure Limit 2500ppm v v Environmental Precautions N
5. ature Decomposition Temperature Upper explosive limit Lower explosive limit Flammability solid gas Expellant Argon Appearance Physical State Color Odor Odor Threshold pH Specific Gravity Boiling Range Point C F Melting Point C F Flash Point PMCC C F Vapor Pressure Evaporation Rate BuAc 1 Solubility in Water Vapor Density Air 1 VOC g l VOC Partition coefficient n octanol water Viscosity Auto ignition Temperature Decomposition Temperature Upper explosive limit Lower explosive limit Flammability solid gas Revision Date April 10 2015 Not applicable 5 14 92 3 Ib ft 77 F 1 48 kg l 25 C 0 385 Ib ft 6 17 kg m 27 C 80 6 F No data available Not flammable 11 2 psig 68 F 77 kPa 20 C Faster than water slower than ether 0 39 wt 25 C 77 F 1 atm No data available No data available No data available Not applicable No data available No data available No data available No data available Not flammable Compressed gas Colorless None No data available Not applicable No data available No data available No data available Not flammable No data available No data available No data available Not applicable None None No data available Not applicable No data available No data available Not explosive Not explosive Not flammable Page 5 of 9 BA Ki d d e SAFETY DATA SHEET A Halotron 1 10 11 h Fire Extinguishi
6. bon Agent This product is a mixture Component CAS Number Concentration 2 2 dichloro 1 1 1 trifluoroethane 306 83 2 85 95 Proprietary gas mixture NA 1 10 Note The expellant is argon 4 FIRST AID MEASURES Description of necessary first aid measures Eyes Immediately flood the eye with plenty of warm water for at least 15 minutes holding the eye open Obtain medical attention if soreness or redness persists Skin Flush with water Obtain medical attention if frostbite or blistering occurs or redness persists Revision Date April 10 2015 Page 2 of 9 BA Ki d d e SAFETY DATA SHEET A Halotron 1 h Fire Extinguishing Agent with Expellant 4 FIRST AID MEASURES Ingestion Ingestion is not considered a potential route of exposure Inhalation Remove from exposure If there is difficulty in breathing give oxygen Obtain medical attention immediately Most important symptoms effects acute and delayed Aside from the information found under Description of necessary first aid measures above and Indication of immediate medical attention and special treatment needed no additional symptoms and effects are anticipated Indication of immediate medical attention and special treatment needed Notes to Physicians In case of frostbite place the frostbitten part in warm water If warm water is not available or impractical to use wrap the affected parts gently in blankets DO NOT USE HOT WATER The use of catechol
7. g Kidde r United Technologies IDENTIFICATION Product Name Other Names Recommended use of the chemical and restrictions on use Identified uses Restrictions on use Company Identification Customer Information Number Emergency Telephone Number CHEMTREC Number Issue Date Supersedes Date SAFETY DATA SHEET Halotron 1 Fire Extinguishing Agent with Expellant Halotron 1 Fire Extinguishing Agent with Expellant HCFC Blend B Halocarbon Agent Fire Extinguishing Agent Consult applicable fire protection codes Kidde Residential amp Commercial 1016 Corporate Park Drive Mebane NC 27302 USA 919 563 5911 919 304 8200 800 424 9300 703 527 3887 International April 10 2015 February 9 2015 Safety Data Sheet prepared in accordance with OSHA s Hazard Communication Standard 29 CFR 1910 1200 and the Globally Harmonized System of Classification and Labelling of Chemicals GHS HAZARD IDENTIFICATION Hazard Classification Gas under pressure liquefied gas Simple Asphyxiant Specific Target Organ Toxicity Single Exposure Category 2 Specific Target Organ Toxicity Repeat Exposure Category 2 Label Elements Hazard Symbols Signal Word Warning Hazard Statements Contents under pressure may explode if heated May displace oxygen and cause rapid suffocation May cause damage to organs liver central nervous system through inhalation May cause damage to organs liver through p
8. ied for inclusion on the Domestic Substance List DSL SARA Title IIl Sect 311 312 Categorization Immediate Acute Health Hazard Delayed Chronic Health Hazard Pressure hazard SARA Title Ill Sect 313 This product contains a chemical which is listed in Section 313 at or above de minimis concentrations 2 2 dichloro 1 1 1 trifluoroethane 306 83 2 OTHER INFORMATION NFPA Ratings NFPA Code for Health 1 NFPA Code for Flammability 0 NFPA Code for Reactivity 1 NFPA Code for Special Hazards None HMIS Ratings HMIS Code for Health 1 HMIS Code for Flammability 0 HMIS Code for Physical Hazard 1 HMIS Code for Personal Protection See Section 8 Chronic Legend ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstracts Service IARC International Agency for Research on Cancer LCLo Lethal concentration low N A Denotes no applicable information found or available NTP National Toxicology Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit SDS Safety Data Sheet STEL Short Term Exposure Limit TLV Threshold Limit Value Revision Date April 10 2015 Replaces February 9 2015 Changes made Updated to GHS Classification Information Source and References This SDS is prepared by Hazard Communication Specialists based on information provided by internal company references Revision Date April 10 2015 Page 8 of 9 BA Ki d d e SAF
9. lrritation 2 2 dichloro 1 1 1 trifluoroethane In rabbit study mild to moderate conjunctival irritation with no corneal or iritic involvement was observed in an unwashed rabbit eye An eye dosed with the test substance and promptly washed had mild to slight transient corneal opacity and mild to moderate conjunctival irritation with no iritic involvement Both eyes were normal within 3 7 days Skin Corrosion Irritation 2 2 dichloro 1 1 1 trifluoroethane Dermal exposure in rabbits did not result in any irritation Revision Date April 10 2015 Page 6 of 9 PB Ki d d e SAFETY DATA SHEET r Halotron 1 11 12 13 14 Fire Extinguishing Agent with Expellant r United Technologies TOXICOLOGICAL INFORMATION Respiratory or Skin Sensitization No relevant studies identified Carcinogenicity Not considered carcinogenic by NTP IARC and OSHA Germ Cell Mutagenicity 2 2 dichloro 1 1 1 trifluoroethane Not considered genotoxic based on animal and test tube studies Reproductive Toxicity 2 2 dichloro 1 1 1 trifluoroethane No affects to reproductive performance were seen in rats or harm to the unborn animals in rats or rabbits at 5000 and 10 000ppm Aspiration Hazard Not an aspiration hazard ECOLOGICAL INFORMATION Ecotoxicity 2 2 dichloro 1 1 1 trifluoroethane LC50 Fathead minnow 77mg l 96hr Mobility in soil No relevant studies identified Persistence Degradability No relevant studies identified
10. ng Agent with Expellant STABILITY AND REACTIVITY Reactivity Containers may rupture or explode if exposed to heat Chemical Stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to Avoid Extremely high temperatures flames Incompatible Materials Incompatible with alkali or alkaline earth metals and powdered metals Al Zn Be etc Hazardous Decomposition Products Hydrochloric and hydrofluoric acids possibly carbonyl halides TOXICOLOGICAL INFORMATION Acute Toxicity 2 2 dichloro 1 1 1 trifluoroethane Simple asphyxiant Inhalation 4 hour LC50 rat 32 000 ppm Oral Approximate Lethal Dose rat 9000 mg kg Dermal Approximate Lethal Dose rat gt 2000 mg kg Cardiac LOAEL 2 vol Cardiac NOAEL 1 vol Argon Simple asphyxiant Specific Target Organ Toxicity STOT single exposure 2 2 dichloro 1 1 1 trifluoroethane Adverse effects to the liver and central nervous system were observed in animal studies inhalation Argon Exposure to argon gas at high concentrations can cause suffocation by reducing oxygen available for breathing Breathing very high concentrations can cause dizziness shortness of breath unconsciousness or asphyxiation Specific Target Organ Toxicity STOT repeat exposure 2 2 dichloro 1 1 1 trifluoroethane Adverse effects to the liver were observed in animal studies inhalation Serious Eye damage
11. one Methods and materials for containment and cleaning up None Revision Date April 10 2015 Page 3 of 9 BA Ki d d e SAFETY DATA SHEET A Halotron 1 h Fire Extinguishing Agent with Expellant 7 HANDLING AND STORAGE Precautions for safe handling Wear appropriate protective clothing Prevent skin and eye contact Conditions for safe storage Pressurized containers should be properly stored and secured to prevent falling or being knocked over Do not drag slide or roll pressurized containers Do not drop pressurized containers or permit them to strike against each other Never apply flame or localized heat directly to any part of the pressurized or plastic container Store pressurized containers away from high heat sources Storage area should be cool dry well ventilated under cover out of direct sunlight 8 EXPOSURE CONTROLS PERSONAL PROTECTION Control parameters Exposure limits are listed below if they exist Workplace Environmental Exposure Level chronic handling WEEL AIHA 8 hrs 50 ppm v v based on the primary component Manufacturers Recommended 1 Hr Emergency Exposure Limit 1000ppm v v Manufacturers Recommended 1 Min Emergency Exposure Limit 2500ppm v v Exposure Level When Using Halotron in a Fire Extinguisher Exposure when using this material as a fire extinguishing agent the exposure should not exceed 20 000 ppm v v Guidelines for the safe minimum volume when this agent is used in
12. rolonged or repeated exposure inhalation Revision Date April 10 2015 Page 1 of 9 BA Ki d d e SAFETY DATA SHEET A Halotron 1 h Fire Extinguishing Agent with Expellant 2 HAZARD IDENTIFICATION Precautionary Statements Prevention Do not enter confined space unless adequately ventilated In case of inadequate ventilation wear respiratory protection Do not breathe fume gas mist vapors spray Wash hands thoroughly after handling Do not eat drink or smoke when using this product Response Get medical advice attention if you feel unwell If exposed or concerned Call a poison center or doctor Storage Keep container tightly closed Protect from sunlight and store in well ventilated place Store locked up Disposal Dispose of contents container is accordance with local and national regulations Other Hazards Direct contact with the cold gas or liquid can cause freezing of exposed tissues Avoid direct inhalation of undiluted gas Can cause suffocation by reducing oxygen available for breathing Breathing very high concentrations can cause dizziness shortness of breath unconsciousness or asphyxiation Specific Concentration Limits The values listed below represent the percentages of ingredients of unknown toxicity Acute oral toxicity 1 10 Acute dermal toxicity 1 10 Acute inhalation toxicity 1 10 Acute aquatic toxicity 1 10 3 COMPOSITION INFORMATION ON INGREDIENTS Synonyms HCFC Blend B Halocar
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