Varta V319
Contents
1. Appendix 1 No 1443 and 766 Other information Note Date of issue of the transport regulations ADR 2009 IATA 2008 IMDG 2006 DOT 49 CFR 2008 Issued by VARTA Microbattery GmbH Quality Environmental Management Contact person Dr Rainer Jostes Tel 49 7961 921 680 Fax 49 7961 921 73680 E Mail rainer jostes varta microbattery com 5 of 5 VARTA Microbattery GmbH Daimlerstra e 1 27 11 08 Electronically generated document no signature required 73479 Ellwangen German 01 i Fo_1752. Material Safety Data Sheet W VARTA MSDS 2 001 010 Primary zinc silver oxide button cell series V 1 Identification of the product and of the company undertaking Product details Trade name Primary Silver oxide battery button Voltage 1 55 V or multiples of this in case of multi cell configurations Electrochemical system Zinc mercury NaOH KOH electrolyte silver oxide manganese dioxide Anode negative electrode Zinc mercury Cathode positive electrode Silver oxide manganese dioxide Supplier details Address VARTA Microbattery GmbH Daimlerstr 1 D 73479 Ellwangen Jagst Germany Emergency telephone number 49 7961 921 211 Legal Remark U S A Material Safety Data Sheets MSDS are a sub requirement of the Occupational Safety and Health Administration OSHA Hazard Communication Standard 29 CFR Subpart 1910 1200 This Hazard Communication Standard does not apply to various subcategories including anything defined by OSHA as an article OSHA has defined article as a manufactured item other than a fluid or particle i which is formed to a specific shape or design during manufacture ii which has end use function s dependent in whole or in part upon its shape or design during end use and iii which under normal conditions of use does not release more than very small quantities e g minute or trace amounts of a hazardous chemical and does not pose a physical hazard or health risk to employees Beca
3. amaging of the cell or if exposed to fire 3 Composition information on ingredients Ingredients Contents CAS No Hazard Symbols R Phrases Material 13 34 20667 12 3 O C Xi R 8 34 44 Silver oxide 0 14 1313 13 9 Xn R20 22 Manganese dioxide 5 10 7440 66 6 N R50 53 Zinc 0 3 1310 58 3 Cc R22 35 Potassium hydroxide 0 2 1310 73 2 Cc R35 Sodium hydroxide 0 5 1 33 7439 97 6 T N R 23 33 50 53 Mercury in zinc alloy lt 25 mg cell Heavy Metals Contents CAS No Material 20 60 mg kg 7439 92 1 Lead lt 5 mg kg 7440 43 9 Cadmium Other Ingredients Contents CAS No Material 27 70 Nickel plated steel 2 5 Copper 2 7 Polymers Hazard Symbols Xn Harmful T Toxic Xi Irritating O Oxidising Cc Corrosive N Dangerous for the environment R Phrases 8 Contact with combustible material may cause fire 20 22 Harmful by inhalation and if swallowed 22 Harmful if swallowed 23 Toxic by inhalation 33 Danger of cumulative effects 34 Causes burns 35 Causes severe burns 44 Risk of explosion if heated under confinement 50 53 Very toxic to aquatic organisms may cause long term adverse effects in the aquatic environment Page no 2o0f5 VARTA Microbattery GmbH Daimlerstra e 1 73479 Ellwangen Germany Edition 27 11 08 Electronically generated document no signature required Fo_175 Version 01 W VARTA 4 First aid measures Measures at accidental r
4. ay leak Pack the battery including ingredients as described above Then clean with water diluted acetic acid may be helpful Always follow the warning information on the batteries and in the manuals of devices Only use the recommended battery types Keep batteries away from children For devices to be used by children the battery casing should be protected against unauthorized access Unpacked batteries shall not lie about in bulk In case of battery change always replace all batteries by new ones of identical type and brand Do not swallow batteries Do not throw batteries into water Do not throw batteries into fire Do not short circuit batteries Do not recharge primary batteries Storage preferably at room temperature approx 20 C Avoid large temperature changes Avoid direct sunlight At higher temperature the electrical performance may be reduced Storage of unpacked batteries can cause short circuit and heat generation VARTA Microbattery GmbH Daimlerstra e 1 73479 Ellwangen Germany Fo_175 Material Safety Data Sheet M VARTA MSDS 2 001 010 10 11 12 13 Page no Edition Version Storage of large amounts If possible store the batteries in original packaging short circuit protection A fire alarm is recommended For automatic fire extinction consider chapter 5 Fire fighting measures VCI storage category It is recommended to consider the VCI Guideline for the mix
5. ed storage of chemicals and to handle primary zinc air button cells according to storage category 11 combustible solids Exposure controls personal protection Under normal conditions discharge avoid prolonged deep discharge release of ingredients does not occur Physical and chemical properties Not applicable if closed Stability and reactivity Dangerous reactions When heated above 70 C the risk of rupture occurs Toxicological information Under normal conditions during charge and discharge release of ingredients does not occur If accidental release occurs see information in section 2 3 and 4 Swallowing of a battery can be harmful Call the local Poison Control Centre for advice and follow up Ecological information Primary zinc silver oxide button cells do contain mercury and lead and do not contain cadmium as defined by the European directive 2006 66 EC Article 21 The mercury content is in accordance with the Mercury Containing and Rechargeable Battery Management Act U S A Disposal considerations USA Primary zinc silver oxide button cells are classified by the federal government as non hazardous waste and are safe for disposal in the normal municipal waste stream In the European Union manufacturing handling and disposal of batteries is regulated on the basis of the DIRECTIVE 2006 66 EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 6 September 2006 on batteries and accumulators and was
6. elease After inhalation After skin contact After eye contact After ingestion 5 Fire fighting measures Suitable extinguishing media Material Safety Data Sheet MSDS 2 001 010 Fresh air Seek for medical assistance Flush affected areas with plenty of water Remove contaminated cloth immediately Seek for medical assistance Flush the eye gently with plenty of water at least 15 minutes Seek for medical assistance Drink plenty of water Avoid vomiting Seek for medical assistance No trials for neutralization Use foam water or COs as appropriate Extinguishing media with limited none suitability Special protection equipment during Contamination cloth including breathing apparatus fire fighting Special hazard none 6 Accidental release measures Person related measures Environment protection measures Treatment for cleaning 7 Handling and storage Guideline for safe handling Storage Page no 3o0f5 Edition 27 11 08 Electronically generated document no signature required Version 01 Wear personal protective equipment adapted to the situation protection gloves cloth In the event of battery rupture prevent skin contact and collect all released material in a plastic lined container Dispose off according to the local law and rules Avoid leached substances to get into the earth canalization or waters If battery casing is dismantled small amounts of electrolyte m
7. is cracked are not subject to the requirements of RID ADR provided the batteries are securely packed and protected against short circuits Examples of such batteries are alkali manganese zinc carbon nickel metal hydride and nickel cadmium batteries USA 49 CFR 172 102 Special Provision 130 For other than a dry battery specifically covered by another entry in the 172 101 Table Batteries dry are not subject to the requirements of this subchapter when they are securely packaged and offered for transportation in a manner that prevents the dangerous evolution of heat for example by the effective insulation of exposed terminals and protects against short circuits Regulatory information Marking consideration VARTA primary zinc silver oxide button cells conform with the requirements of the Medical Devices Directive 93 42 EEC class 1 and are thus marked with the CE symbol According to DIRECTIVE 2006 66 EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 6 September 2006 on batteries and accumulators and waste batteries and accumulators and repealing Directive 91 157 EEC all batteries have to be marked with the crossed bin according to Article 21 of this directive primary zinc silver oxide button cells have to be marked with the element symbols Hg and Pb International safety standards IEC 60086 5 Water hazard class according to German Federal Water Management Act non water pollution according to VwVwS
8. te batteries and accumulators and repealing Directive 91 157 EEC Customers find detailed information on disposal in their specific countries using the web site of the European Portable Batteries Association http www epbaeurope net legislation national html Importers and users outside EU should consider the local law and rules In order to avoid short circuit and heating used zinc silver oxide button cells batteries should never be stored or transported in bulk Proper measures against short circuit are e Storage of batteries in original packaging e Coverage of the terminals 4of5 VARTA Microbattery GmbH 2 N 5 i DaimlerstraBe 1 5 27 11 08 Electronically generated document no signature required 73479 Ellwangen K German 01 i W VARTA 14 15 16 Page no Edition Version Material Safety Data Sheet MSDS 2 001 010 Transport information VARTA primary zinc silver oxide button cells are considered to be dry cell batteries and are unregulated for purposes of transportation by the U S Department of Transportation DOT International Civic Aviation Administration ICAO International Air Transport Association IATA the International Maritime Organization IMO and the Accord Europe n Relatif au Transport International des Marchandises Dangereuses par Route ADR EU Special Provision 304 ADR Batteries dry containing corrosive electrolyte which will not flow out of the battery if the battery case
9. use all of our batteries are defined as articles they are exempted from the requirements of the Hazard Communication Standard Legal remark EU These batteries are no substances or preparations according to Regulation EC No 1907 2006 EC Instead they have to be regarded as articles no substances are intended to be released during handling Therefore there is no obligation to supply a MSDS according to Regulation EC 1907 2006 Article 31 General remark This Safety Information is provided as a service to our customers The details presented are in accordance with our present knowledge and experiences They are no contractual assurances of product attributes Page no 1of5 VARTA Microbattery GmbH Daimlerstra e 1 73479 Ellwangen Germany Edition 27 11 08 Electronically generated document no signature required Version 01 Fo_175 Material Safety Data Sheet M VARTA MSDS 2 001 010 2 Hazards identification A sealed zinc silver oxide button cell is not hazardous in normal use as defined in chapter 7 In case of mistreatment prolonged deep discharge charge reverse charge external short circuit and in case of fault some electrolyte can leak from the cell In these cases refer to the risk of potassium hydroxide solution or sodium hydroxide solution corrosive pH gt 14 Charging may cause rupture The electrode materials are only hazardous if the materials are released by mechanical d
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