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DOMINUS Stewardship and Training Manual

1. 9 9 9 9 9 9 9 1 Date of Application 2 Farm Grower Location 4 Applicator Name 5 Applicator Phone 5 Application Method C Raised Bed Shank C Raised Bed Drip Flat Fume 6 Crop 7 Rate or Ibs A broadcast acre Our 9 Planting Date EM 20 a Target Soil Pests Weeds Fungi Nematodes 11 DOMINUS Acres Treated 12 Field Size acres Prior to application you must submit form to Isagro USA Chris Leon cleon isagro usa com CLEAR Daren Sapp dsapp isagro usa com and Taylor Ivy tivy isagro usa com EM 6 6 9 9 9 9 9
2. 11 1 The Right Choice for Pre Plant Soil Treatment 11 2 COMPO SON 6 4 aun SCR RUE ae bee oh ea 11 3 Physical Chemical 12 my NWIGSeOLACHUOI dhil arae hehe 12 5 Product Compballbilii s sx x na ae ee Ab a 13 DOMINUS Dose Rates 1 14 1 Broadcast Acre Application Rates For Pre Plant 14 2 Application Rates for Raised Bed Fumigation 14 wissen c 16 Wace DIOS 222222222226 16 i is rr 16 Product Container Labeling s auro cee HER GRECE Sed eG Far PR ESI ES 17 1 General Requirements Keg Cylinder IBC and ISO Tank 0 17 2 General Requirements for Hazard 0 17 a General specification for 17 b Visibility and display of the 17 CHAPTER 2 DOMINUS USER SAFETY
3. 18 Hazard Identification eeeeee ee ee ee ee RN ees ne eee TREES 18 1 Hazards to Humans and Domestic 18 2 19 3 Physical and Chemical 19 Transport Incident 4 83 des EGER SEXIES 20 General Use PFeCSUIIOTIS 21 Personal Protective Equipment PPE for 5 21 1 Portable Gas Detection 21 2 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 AN USK 2 SKI IIO HOS scans actes uar eee wena neh BCC ag RENTE SES 23 a Body Protection tases 23 b Hand 23 C FOOL FIOCCO sh een 24 3 Respiratory Protection 1 24 4 Eye Protection eo en en a 25 5 Emergency Response eek bee aah INTER E
4. DOMINUS is a trademark of Isagro USA 2014 Isagro USA All Rights Reserved DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014
5. Rus Re dO 53 3 Turning the Monitor 54 Calibration for DOMINUS Detection 54 1 Turning the Monitor OIN 24 abecess 4299329995 54 Entry RAE Use For DOMINUS Application 57 1 During the Application anana aa _ 57 2 Once the Application is Completed 57 3 Data 57 4 Charging the Entry RAE te needs teehee NOS 57 Calibration of Entry PGM RAE Setting Up of the Limit of Detection 58 RAE SYSTEMS TECHNICAL NOTE 106 61 RAE SYSTEMS ToxiRAE PrO 1 oe oy rir a3 OR QE Oe ewe es oe dr x 74 APPLICATION LOG domo inm 77 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 DOMINUS STEWARDSHIP PROGRAM INVH9OOHd dIHSQHVM3lS USK INTRODUCTION 1 The DOMINUS Soil Fumigant Stewardship and Training Program This application manual is to be used in accordance with all label requirements In all cases the approved and registered labels take preced
6. NR NR 15 11 79 ne Tetraethyl lead TEL 78 00 2 CaH2oPb 0 4 0 3 0 2 11 1 0 008 Tetraethyl orthosilicate Ethyl silicate TEOS 78 10 4 CaH2004SI 07 02 98 10 Tetrafluoroethane 1 1 1 2 HFC 134A 811 97 2 CoH F4 NR NR ne Tetrafluoroethene TFE Tetrafluoroethylene 116 14 3 CoF4 mdi o 10 12 ne Perfluoroethylene Tetrafluoromethane CFC 14 Carbon tetrafluoride 75 73 0 NR gt 153 Tetrahydrofuran THF 109 99 9 C4HaO 19 1 7 10 941 200 Tetramethyl orthosilicate Methyl silicate TMOS 681 84 5 C4H12048I 10 19 10 1 Therminol amp 0 12 Hydrotreated heavy naphtha 64742 48 9 m w 160 0 8 0 51 0 33 Therminol amp VP 1 Dowtherm A 3 1 Diphenyl oxide 101 84 8 C42H490 0 4 1 Biphenyl 92 52 4 C42H10 Toluene Methylbenzene 108 88 3 0 54 0 50 0 51 8 82 50 RAE Systems Inc 4 Re 10 3775 First St San Jose CA 95134 1708 USA n 5 Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com 70 DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 Synonym Abbreviation Tolylene 2 4 diisocyanate diisocyanate Trichlorobenzene 1 2 4 1 2 4 TCB Trichloroethane 1 1 1 1 1 1 TCA Methyl chloroform Trichloroethane 1 1 2 1 1 2 TCA Trichloroethene Trichloromethylsilane Trichlorotrifluoroethane 1 1 2 Triethylamine Triethyl borate Triethyl phosphate Trifluo
7. Buffer Zone Period begins at the start of the application and lasts for a minimum of 24 hours after the application is complete Ensure that unprotected workers and bystanders do not enter the buffer zone from the start of the application until 24 hours after the end of the application Ensure that the buffer zone distance is at least 100 feet from occupied sensitive sites e g nursing homes hospitals or prisons and occupied schools day care facilities and assisted living facilities Conditions present at each individual treatment site should be considered when determining the most protective buffer zone distance and should include Presence and location of occupied structures Wind direction and environmental conditions at the time of application and for a period 24 hours after the end of the application Distance to sensitive sites Activities of field workers near or adjacent to treatment areas during the first 24 hours post application The Restricted Entry Period REP Entry by any person other than a correctly trained and PPE equipped handler who is performing a handling task listed on the label is PROHIBITED from the start of the application until one of the following occurs Treated area 5 days or 120 hours from the end of the application Buffer Zone 24 hours from the end of the application It is important to also heed the Tarp Perforation and Removal section of the product label to determine requireme
8. RAE Systems Inc 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 63 64 mm Compound Name Acetaldehyde Acetic acid Acetic anhydride Acetone Acetone cyanohydrin Acetonitrile Acetylene Acrolein Acrylic acid Acrylonitrile Allyl alcohol Allyl chloride Ammonia acetate alcohol Aniline Anisole Arsine Benzaldehyde Benzenamine N methyl Benzene Benzonitrile Benzyl alcohol Benzyl chloride Benzyl formate Boron trifluoride Bromine Bromobenzene 2 Bromoethyl methyl ether Bromoform Bromopropane 1 Butadiene Butadiene diepoxide 1 3 Butanal Butane Butanol 1 Butanol t Butene 1 Butoxyethanol 2 Butoxyethanol acetate Butoxyethoxyethanol Butyl acetate n Butyl acrylate n Butylamine n Butyl cellosolve Butyl hydroperoxide t Butyl mercaptan Carbon disulfide Carbon tetrachloride Carbonyl sulfide Cellosolve see 2 Ethoxyethanol Synonym Abbreviation Ethanoic Acid Ethanoic Acid Anhydride 2 Propanone 2 Hydroxyisobutyronitrile Methyl cyanide Cyanomethane Ethyne Propenal Propenoic Acid Propenenitrile 3 Chloropropene mix of n Pentyl acetate amp 2 Methylbutyl acetate 1 Pentanol Aminobenzene Methoxybenzene Arsenic trihydride N Methylphenylamine Cyanobenzen
9. Treated area numbers of beds length of the drip line width of the beds For broadcast application number of beds is equal to one Step3 Calculation of the quantity of DOMINUS to be applied during the application Quantity of DOMINUS to be applied gal Dose Rate gpa x Treated area acres 44 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USK Step 4 Calculation of the quantity of water to be applied during the application process Wetting phase Delivery of DOMINUS and Flushing phase a Determinate the flow rate of the water into your main irrigation line Value shown by the flow meter is ft hour b Convert the read flow meter into gal minutes Water flow rate gal min Water flow rate read ft hour X 1000 60 c Calculate the total quantity of water to be applied Total qty water gal height of water established via diagram 1 inch x area ft otep5 Calculation of the quantity of water to flush the irrigation system Parameters from Irrigation system needed Diameter of the main irrigation line Length of the main irrigation lines Number of drip lines Length of the drip lines Diameter of the drip lines in the soil bed To ensure a complete flushing of the irrigation system after DOMINUS product application rinse your System 5X the amount of water to fill the irrigation system Quantity of water for flushing gal length main
10. 05 Row Spacing inches Bed Width inches If the row spacing and bed width to be used do not appear in the table above calculate the field rate modifier by dividing the average bed width inches by the row spacing inches as in the example below The Field Rate Modifier is not to exceed 0 75 How to determine Field Rate Modifier Bed Width in Row Spacing in 2 96 of Acre Treated 43 Beds 66 Row Spacing 0 65 conversion factor for Field Rate Modifier FRM DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 15 m m 2 Em Al Em Product Storage Outdoor storage of DOMINUS soil fumigant should be under ambient conditions and in a secure locked area Provide overhead protection of the cylinder storage area Indoor storage of DOMINUS soil fumigant should be under lock and key and in a well ventilated area All storage areas must be posted with appropriate warning signs for pesticides Pesticide Disposal Pesticide wastes are acutely hazardous Improper disposal of excess pesticide spray mixture or rinsate is a violation of Federal Law Return of Containers This pesticide container whether full or partially used is the property of the manufacturer or distributor where it was purchased and must be returned to the distributor of origin Do not ship containers without safety caps or if applicable valve protection bonnets Containers shall
11. 238 13 0 0326 23382 2381 2286 DOMINUS 9 255 30 00 25500 0 0059 285 76 0 0391 28058 28 58 2743 DOMINUS 90 298 35 00 29750 0 0068 333 39 0 0456 32735 3334 3201 DOMINUS 9 3540 4000 340 00 0 0078 381 02 0 0521 374 11 3810 3658 Formulated Product 2 Application Rates for Raised Bed Fumigation Dose rates listed in fumigation tables ABOVE for drip and raised bed shank applications are given in weight or volume of DOMINUS per Broadcast Acre For raised bed fumigations the amount applied or Rate per Treated Acre will be proportional percentage of the broadcast rate to the row spacing and width of raised beds To calculate the amount of product to be applied per treated acre multiply the application rate in gallons or pounds of DOMINUS broadcast per acre by the appropriate modifier from the Field Rate Modifier FRM table provided below Examples for determining Rate per Treated Acre DOMINUS 30 Gal A broadcast x 0 65 FRM 19 5 gallons actually applied DOMINUS 255 Lbs A broadcast x 0 65 FRM 165 75 lbs actually applied 14 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 AN 7 ES gt CLE M EZ o 4 F Field Rate Modifier Treated Area Table for Common Raised Bed Applications Field Rate Modified Treated Area __ 82 28 054 8 28 17 08 4 4
12. Jet fuel JP 5 Jet fuel JP 8 Jet fuel A 1 JP 8 Jet Fuel TS Limonene D Synonym Abbreviation Methyl iodide Isopentyl acetate 2 Methylpropane 2 Methyl 1 propanol Isobutylene Methyl butene Isobutyl 2 propenoate 1 Chloro 2 2 2 trifluoroethyl difluoromethyl ether forane 2 2 4 Trimethylpentane lsoparaffinic hydrocarbons Photocopier diluent lsoparaffinic hydrocarbons lsoparaffinic hydrocarbons lsoparaffinic hydrocarbons 2 Methylbutane 2 Methyl 1 3 butadiene Isopropyl alcohol 2 propanol IPA Diisopropyl ether Jet B Turbo B F 40 Wide cut type aviation fuel Jet 5 F 44 Kerosene type aviation fuel Jet A 1 F 34 Kerosene type aviation fuel F 34 Kerosene type aviation fuel Thermally Stable Jet Fuel Hydrotreated kerosene fuel R Limonene Kerosene C10 C16 petro distillate see Jet Fuels MDI see 4 4 Methylenebis phenylisocyanate Maleic anhydride Mesitylene 2 5 Furandione 1 3 5 Trimethylbenzene Methallyl chloride see 3 Chloro 2 methylpropene Methane Methanol Methoxyethanol 2 Methoxyethoxyethanol 2 Methoxyethyl ether 2 Methyl acetate Methyl acrylate Methylamine Methyl amyl ketone Methyl bromide Methyl t butyl ether Methyl cellosolve Methyl chloride Methylcyclohexane Methylene bis phenyl isocyanate 4 4 _ 5 TE E an e 68 Natural gas Methyl alcohol carbinol Methyl cellosolve Ethylene glycol mo
13. flows out around the probe The first two cylinder methods are the most efficient in terms of gas usage while the bag and T methods give slightly more accurate results because they match the pump flow better b Pressure Pressures deviating from atmospheric pressure affect the readings by altering gas concentration and pump characteristics It 1s best to calibrate with the instrument and calibration gas at the same pressure as each other and the sample gas Note that the cylinder pressure 15 not relevant because the regulator reduces the pressure to ambient If the instrument 15 calibrated at atmospheric pressure in one of the flow configurations described above then 1 pressures slightly above ambient are acceptable but high pressures can damage the pump and 2 samples under vacuum may give low readings if air leaks into the sample train c Temperature Because temperature effects gas density and concentration the temperature of the calibration gas and instrument should be as close as possible to the ambient temperature where the unit will be used We recommend that the temperature of the calibration gas be within the instrument s temperature specification typically 14 to 113 F or 10 to 45 C Also during actual measurements the instrument should be kept at the same or higher temperature than the sample temperature to avoid condensation in the unit d Matrix The matrix gas of the calibration compound and VOC sample 15
14. never be refilled by the consumer end user or reused for any other product or purpose Waste Disposal Pesticide wastes are acutely hazardous Improper disposal of excess pesticide spray mixture or rinsate is a violation of Federal Law If the pesticide wastes cannot be disposed of by use according to label instructions at an approved waste disposal facility refer to pesticide disposal statement on approved label For additional information or guidance contact the State or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance The pesticide container whether full or partially used is the property of the manufacturer or distributor where it was purchased and must be returned to the distributor of origin Do not ship containers without safety caps or if applicable valve protection bonnets FOR MORE DETAILS PLEASE REFER TO THE TRAINING MANUAL FOR DOMINUS STORAGE AND HANDLING Transportation Placard Descriptions FLAMMABLE LIQUID 16 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA Product Container Labeling 1 General Requirements on Keg Cylinder IBC and ISO Tank Labeling DOMINUS kegs cylinder IBC and ISO tanks must have Registered label the label approved by the authorities of the country is the only one which can be placed on each package type used for DOMINUS transportat
15. nose and throat Continued exposure after irritation is evident or higher concentrations may cause painful irritation to the eyes or temporary blindness Liquid will cause chemical burns to skin or eyes Do not get on skin in eyes or on clothing Chloropicrin fumigant has the capacity to cause marked irritation to the upper respiratory tract and is a strong lachrymator tear producing eye irritant Low concentrations below those necessary to cause serious systemic intoxication are capable of causing severely painful eye irritation hence will not be voluntarily tolerated However the effect may be so powerful that a person may become temporarily blinded and panic stricken and that in turn may lead to accidents 18 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 AN 2 Environmental Hazards Toxic to marine animals birds and wildlife Do not discharge into bodies of water without government approved permit s 3 Physical and Chemical Hazards Do not use or store near heat open flames or sparking electrical equipment Do not allow contact with foams copper or magnesium alloys First Aid Measures DOMINUS Formulated Product After contact with the eyes rinse with water or saline solution If present remove contact lenses after at least 5 minutes of rinsing then continue rinsing for another 10 15 minutes with the eyelids open Consult an ophthalmologist immediatel
16. 0 67 m w 165 09 06 03 0 33 8 2 C4H205 10 8 CoH42 0 36 035 0 3 8 41 NR NR 12 61 CH4O NR 25 10 85 gt 48 24 14 10 1 7 1 2 3 1 2 09 lt 10 14 0 64 0 54 0 44 lt 9 8 2 66 14 1027 4 3 7 t 1 2 9 9 CH5N 1 2 8 97 C H440 09 0 85 05 9 30 CHaBr 110 17 13 10 54 0 9 t 9 24 CH3CI NR NR 074 11 22 7 14 16 0 97 0 53 9 64 C45H40N202 Very slow ppb level response RAE Systems Inc 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 TWA 2 100 ne 50 Ne Ne Ne 30 34 30 Ne Ne 200 Ne Ne 50 400 0 005 Compound Name Methylene chloride Methyl ether Methyl ethyl ketone Methylhydrazine Methyl isoamyl ketone Methyl isobutyl ketone Methyl isocyanate Methyl isothiocyanate Methyl mercaptan Methyl methacrylate Methyl nonafluorobutyl ether Methyl 1 5 pentanediamine 2 coats lamp Methyl propyl ketone Methyl 2 pyrrolidinone N Methyl salicylate Methylstyrene a Methyl sulfide Mineral spirits Mineral Spirits Viscor 120B Calibration Fluid b p 156 207 Synonym Abbreviation Dichloromethane Dimethyl ether MEK 2 Butanone Monomethylhydrazine Hyd
17. Characteristics a Flow Configuration PID response is essentially independent of gas flow rate as long as it 15 sufficient to satisfy the pump demand Four main flow configurations are used for calibrating a PID 1 Pressurized gas cylinder Fixed flow regulator The flow rate of the regulator should match the flow demand of the instrument pump or be slightly higher 2 Pressurized gas cylinder Demand flow regulator A demand flow regulator better matches pump speed differences but results in a slight vacuum during calibration and thus slightly high readings 3 Collapsible gas bag The instrument will draw the calibration gas from the bag at its normal flow rate as long as the bag valve 15 large enough The bag should be filled with enough gas to allow at least one minute of flow 0 6 L for a MiniRAE 0 3 L for MultiRAE E M 5 T E I Y amp Technical Note 106 Revised 08 2010 4 T or open tube method The T method uses a T junction with gas flow higher than the pump draw The gas supply 1s connected to one end of the T the instrument inlet is connected to a second end of the T and excess gas flow escapes through the third open end of the T To prevent ambient air mixing a long tube should be connected to the open end or a high excess rate should be used Alternatively the instrument probe can be inserted into an open tube slightly wider than the probe Excess gas
18. Factor multiply by reading to get corrected value for the compound when calibrated to isobutylene NR No Response IE Ionization Energy values in parentheses are not well established C Confirmed Value indicated by in this column all others are preliminary or estimated values and are subject to change ne Not Established ACGIH 8 hr TWA C Ceiling value given where 8 hr TWA is not available Disclaimer Actual readings may vary with age and cleanliness of lamp relative humidity and other factors For accurate work the instrument should be calibrated regularly under the operating conditions used The factors in this table were measured in dry air at room temperature typically at 50 100 ppm CF values may vary above about 1000 ppm Updates The values in this table are subject to change as more or better data become available Watch for updates of this table on the Internet at http www raesystems com IE data are taken from the CRC Handbook of Chemistry and Physics 73rd Edition D R Lide Ed CRC Press 1993 and NIST Standard Ref Database 19A NIST Positive Ion Energetics Vers 2 0 et al U S Dept Commerce 1993 Exposure limits 8 h TWA and Ceiling Values are from the 2005 ACGIH Guide to Occupational Exposure Values ACGIH Cincinnati OH 2005 Equations for exposure limits for mixtures of chemicals were taken from the 1997 TLVs and BEIs handbook published by the ACGIH 1997
19. GAL 3785 TREATMENT AREA INCHES On Center BASE AVE DRIP LINES PER BED TOTALFT2 REP TOTALFT2 TRT ACRESTRT PRODUCT QUANTITIES IRF135 10 3 TRT 8 3 250 Date Applicator TRT LIST PRODUCT UOM Application ENTER INTO CLEAR CELLS ONLY 8 16 2013 urce NA NANA 255 LBS A sipoMNUS s4o iBs A 4 274650 1 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 RATE UOM LBS GALFP ENGLISH UNITS TARGET INCHES FT2 ACRE 43560 GAL FLUSHTIME 45 MIN WATER GAL GAL FLUSH VOL GAL BE I TIME CALCULATIONS MINUTES TRT HRS TRT PER TREATEMENT TOTAL TRT L DRIP TAPE FLOW GAL MIN 100 TOTAL GAL MIN TRT DEM TOTAL ML MIN TRT GAL WATER TRT i FLUSH VOLUME GAL WATER TRT GAL TRT WATER and FLUSH E GAL PRODUCT FLOW ML MINUTE LBS MIN LBS 10MIN gal hr Amount of product to deliver per unit of time DOMINUS DOMINUS PIC CHLOR 60 IRF135 10 Gal Mix 326 77 0 7338 7 338 Gal Hr check 188 23 Lbs trt gal Min PPM TARGET CONCENTRATION CONCENTRATION PPM TARGET PIC CHLOR 60 DOMINUS Fumigation Management Program Stewardship and Training Manual Jul
20. Low alarm 2 beeps and flashes per second STEL and TWA 1 beep and flash per second Additional diagnostic alarm and display message for low battery and fan stall JEN EINE Continuous datalogging with a three month capacity at one minute intervals User configurable datalogging interval from 1 to 3 600 seconds Communication and Data Download Wireless Network Data download and instrument set up on PC via charging and PC comm cradle Data download via AutoRAE 2 Automated Test and Calibration Station Wireless data and status transmission 2 via built in RF modem optional RAE Systems Dedicated Wireless Network Wireless Frequency ISM license free bands Wireless Range 2 Typical Operating Temperature Humidity 300 feet 100 meters 4 to 131 F 20 to 55 C 096 to 9596 relative humidity non condensing Dust and Water Resistance IP 54 rating for dust and water ingress protection validated by an independent test laboratory Hazardous Location Approvals US Canada 6 Class Division 1 Groups A B C and D T code T4 Class Zone 0 A Exia T4 Europe ATEX II 1G Ex ia Ga 4 IECEx Ex ia Ga T4 China Ex ia IIC T4 CE Compliance European Conformity EMC directive 2004 108 EC R amp TTE directive 1999 5 EC ATEX directive 94 9 EC Warranty Two years on non consumable components One year on sensor fan battery and other consumabl
21. Only minor modifications to the flow divider system should be necessary and these modifications will be dependent upon the nature and capacities of the existing equipment Use only with inert gaseous propellants such as nitrogen or compressed air dry DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 37 EE HE b A4 Y m 1 DOMINUS does not readily boil and make its own back pressure as it passes through equipment and into the soil The boiling point of AITC is between 298 309 F 148 154 C DOMINUS will be used at rates similar to conventional fumigant products however the product density is much lower and flow meter size and calibration may need to be adjusted prior to use Care in preventing drips from shank ends must be addressed with use of check valves or similar devices All lines must be long enough to equilibrate pressure and equal length to ensure equal flow of DOMINUS to each shank Uneven flow to one or more shanks in a raised bed application will result in erratic control of disease and pests Calibration and inspection of the delivery system is necessary prior to application to correct any potential problems with product distribution Calibration worksheets provided see below are designed to allow the applicator to set up the application equipment to deliver DOMINUS properly to the treated area
22. Reporting form is available from your ISAGRO USA representative Distributor and or electronically the DOMINUS folder www isagro usa com password protected DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 5 p ro Al 1 DOMINUS Qualified Applicator Responsibilities 4 Stewardship and Training Program Overview ISAGRO USA has developed the DOMINUS Stewardship and Training Program for applicators handlers and distribution personnel These individuals are required to have a high level of knowledge and proficiency in the application and handling of DOMINUS 5 Objectives of the DOMINUS Biofumigant Stewardship Program Promote the safe handling of DOMINUS Ensure that DOMINUS products are used in a manner consistent with all label restrictions and use directions Scope of the ISAGRO USA training program is to provide comprehensive training to buyers and end users of DOMINUS product s 6 Requirements for ISAGRO USA Qualification Reading Requirements Stewardship and Training Manual Application Equipment Technical Data Sheet Product Labels Material Safety Data Sheet MSDS Training Course Requirements Course participation presentations focused on attention to requirements for safe use and handling e Hand out materials at training and available on line 9 www isagro usa com ISAGRO USA Standards for Qualificatio
23. STATES CALL Pn na 6 Basic PPE Requirements Start of Application until end of Anytime with Liquid 48 hr Restricted Entry Period and Contact Potential in the Buffer Zone during the 24 hr Buffer Zone Period PPE Always Refer to Product Label Loose fitting or well ventilated long sleeve shirt and long pants Shoes plus socks Yes Chemical resistant gloves Chemical resistant apron chemical resistant footwear socks Full face mask or half mask in combination with safety goggles with Approved cartridges for AITC Readily available Full face shield or safety glasses with brow temple and side protection Vee Do NOT wear goggles without side ventilation IMPORTANT In emergencies such as a spill or leak or when corrective action is needed to reduce air concentrations to acceptable levels wear a Self Contained Breathing Apparatus SCBA In addition wear PPE required for potential contact with a liquid fumigant If no one on site has been trained or certified in the use of SCBA and or no SCBA is maintained on site contact the local fire department or emergency responder immediately Have a copy of the Label and MSDS available at all times Additional protective measures may be necessary if at any time any user experiences sensory irritation of the eyes or nose or if air monitoring results detect persistent i e ppm concentrations are determined to remain stable and not be reducing over a period of 15 minutes or more
24. St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 TWA 25 Ne 200 0 01 50 50 0 02 ne 0 5 100 ne ne 200 ne ne ne 100 100 0 0005 10 0 001 600 ne 25 100 69 Technical Note 106 Revised 08 2010 Compound Name Synonym Abbreviation CAS No Formula 98 10 6 117 CIE eV TWA PGMEA Propylene glycol methyl ether 108 65 6 CgH1203 1 65 10 08 ne acetate 1 Methoxy 2 acetoxypropane 1 Methoxy 2 propanol acetate Phenol Hydroxybenzene 108 95 2 CeHeO 1 0 10 09 8 51 5 Phosgene Dichlorocarbonyl 75 44 5 NR NR 85 112 0 1 Phosgene Nitrogen Dichlorocarbonyl 75 44 5 NR NR 68 112 0 1 Phosphine coats lamp 7803 51 2 PH3 28 39 11 987 03 Photocopier Toner Isoparaffin mix 05 03 Picoline 3 3 Methylpyridine 108 99 6 0 9 9 04 Pinene a 2437 95 8 C40H46 0 31 0 47 8 07 Pinene 18172 67 3 C4oH16 0 38 0 37 0 37 8 100 isomer mix 1 3 Pentadiene 504 60 9 5 0 76 069 0 64 8 6 100 74 98 6 NR 18 10 95 2500 Propyl alcohol 71 23 98 5 1 7 10 22 200 Propylene 115 07 1 15 14 16 973 Propionaldehyde Propanal 123 38 6 1 9 9 95 Propyl acet
25. ToxiRAE Pro PID can promptly detect and accurately monitor over 300 VOCs With an onboard library of 190 correction factors the ToxiRAE Pro PID can be programmed to automatically read in concentrations of the specified compound ToxiRAE Pro ER World s smallest photoionization detector Wireless elevates worker protection to the next level Cutting edge PID with 0 1 to 2 000 ppm range 0 1 ppm resolution and 190 built in correction factors Available in Industrial Hygiene advanced or Safety basic configurations KEY FEATURES Wireless Personal Proven e Wireless access to real time instrument readings and alarm status from any location e Unmistakable five way local and remote wireless notification of alarm conditions e Reliable rugged and intrinsically safe Largest display its class e Continuous datalogging e Fully automated bump testing and calibration with AutoRAE 27 e User replaceable sensor filter fan and Lithium ion battery APPLICATIONS e Industrial hygiene and safety Oil and gas Chemical plants Pharmaceutical plants Government health safety security and environmental agencies Hazardous materials teams first responders e Environmental applications Environmental consulting Worker exposure monitoring with ToxiRAE Pro PID Soil remediation AutoRAE Compatible GE FES
26. adjacent to and surrounding the treated area The buffer zone is to be extended from the edge of the treated area in all directions 2 Buffer Zone Requirements Before applying DOMINUS soil fumigant the treatment area must comply with the following criteria A25 buffer zone is to be established from the edge of the treated area and any occupied structure that is NOT a Sensitive Site Sensitive site recommendation Do not apply within 100 feet from the edge of the treated area to an occupied sensitive site such as Hospital Nursing home e School Prison Day care facilities Playground Do not apply if an occupied structure s is located within the buffer zone during the application or restricted entry interval Maintain 25 foot buffer zone from edge of Treated Area The Supervising Applicator for the soil fumigation is responsible for the following Ensure that the buffer zone is maintained from the start of the application until 24 hours following the end of the application Ensure the buffer zone is well secured to prevent disturbance from animals and to keep unauthorized non fumigant persons from staying in the treated area and or buffer zone during the buffer zone period Determining that the 25 mandated buffer zone is sufficient to secure safety for workers and bystanders If deemed necessary the supervising applicator may increase the buffer zone distance as an added measure of protec
27. charged alone or while it is installed in the monitor To charge an installed battery simply plug the transformer into the cradle and into an outlet Place the monitor in the cradle DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 57 I The monitor is still charging when he LED on the charging cradle is red he Monitor Charging message appears on the display battery segments are scrolling The monitor is fully charged when The Fully Charged message appears on the display gt e The LED on the charging cradle is green ener The set of battery segments are blinking Calibration of Entry PGM RAE Setting Up of the Limit of Detection Min Max 1 Push the switch Mode and 2 Fresh air calibration gt 3 Span Calibration gt N 4 Span calibration gt N 5 Zero calibration gt N 6 Calib due day 9 7 Set type gt N 8 Set run silence gt 9 Set run silence gt 10 Adjust High gt Y a Then push on switch N until arriving to VOCppm 58 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 wA AYA Ky b Once on VOC ppm push Mode c As a maximum value of detection put 999 ppm Pushon Y until you get the number 9 Push on mode then you can enter the second number
28. if less than 3 in length or by placing a new section of plastic tarp over the torn area and ensuring the new tarp edges are buried in the soil and seams of the new plastic are taped to the existing plastic beyond the impacted area Weather Conditions Note National Weather Service Forecasts should be checked by the supervising applicator prior to the start of the application Forecasts for the local weather conditions can be found at http Awww nws noaa gov 1 Temperature Inversion Temperature inversion is a phenomenon whereby cold air which is heavier accumulates near the ground and then is present under a layer of warm air This can cause an abnormal accumulation of DOMINUS at or near the surface of the soil and above the tarp Under these conditions the air mass containing DOMINUS may move off site in unpredictable directions DOMINUS cannot be applied in the presence of a persistent temperature inversion 2 Wind Force The application of DOMINUS requires a wind speed greater than 2 miles hour This minimum wind speed will allow for mixing of air within the treated area The measurement of wind speed can be done with use of an anemometer It is equally important to identify and determine the prevailing wind direction in the field and to take necessary actions to protect against exposure from potential downwind movement of DOMINUS 3 Fog Do not apply DOMINUS in the presence of persistent ground fog or if it is likely to
29. line 1 ft x diameter main line 1 inches x 4000 length main line 2 ft x diameter main line 2 inches x 4000 length main line 3 ft x diameter main line 3 inches x 4000 number drip lines x length lines ft x diameter drip lines inches x rv4000 5 Step6 Calculation of the flow of the emitters Estimated emitter flow Water Flow ft h X 1000 number drip lines x length drip lines ft space between emitters ft otep7 Calculation of the quantity of water to deliver during the flushing of the irrigation system Quantity of water brought during wetting phase gal flow rate of water gal min X Time for wetting phase min Time for the wetting phase is determined by taking into account the initial soil moisture Step8 Calculation of the quantity of water to deliver during the injection phase Quantity of water to bring during injection phase gal 2 Quantity total of water during application gal Quantity of water for wetting phase gal Quantity of water for flushing phase gal Step9 Calculation of the height of water to be bring during Injection Phase Height of water to apply during injection inches quantity of water to bring during injection gal treated area ft DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 45 46 Step 10 Calculation of DOMINUS injection dilution Dilution Obtained Dose Rate x Area quantity of water applied du
30. methylpropene 3 Chloropicrin Chlorotoluene o Chlorotoluene p Chlorotrifluoroethene Chlorotrimethylsilane Cresol m Cresol o Cresol p Crotonaldehyde Cumene Cyanogen bromide Cyanogen chloride Cyclohexane Cyclohexanol Cyclohexanone Cyclohexene Cyclohexylamine Cyclopentane 8596 2 2 dimethylbutane 15 Cyclopropylamine Decamethylcyclopentasiloxane Decamethyltetrasiloxane Decane Diacetone alcohol Dibromochloromethane Synonym Abbreviation Monochlorobenzene PCBTF OXSOL 100 p Chlorobenzotrifluoride Chloroprene HCFC 142B R 142B HCFC 22 R 22 Ethyl chloride Ethylene chlrohydrin bis 2 chloroethyl ether Methyl 2 chloroethyl ether Trichloromethane Methallyl chloride Isobutenyl chloride o Chloromethylbenzene p Chloromethylbenzene CTFE Chlorotrifluoroethylene Genetron 1113 m Hydroxytoluene o Hydroxytoluene p Hydroxytoluene trans 2 Butenal Isopropylbenzene Cyclohexyl alcohol Aminocyclpropane 4 Methyl 4 hydroxy 2 pentanone Chlorodibromomethane Dibromo 3 chloropropane 1 2 DBCP Dibromoethane 1 2 Dichlorobenzene o Dichlorodifluoromethane Dichlorodimethylsilane Dichloroethane 1 2 Dichloroethene 1 1 Dichloroethene c 1 2 Dichloroethene t 1 2 Dichloro 1 fluoroethane 1 1 Dichloromethane e By Am m M EDB Ethylene dibromide Ethylene bromide 1 2 Dichlorobenzene CFC 12 EDC 1 2 DCA Ethylene dichloride 1 1 DCE V
31. occur as this may result in product being concentrated in water vapors within the fog layer and cause potential drifting of DOMINUS outside the treated and buffer zone areas 4 Rainfall Rainfall within a 12 hour period prior to fumigation should be considered due its effect on soil moisture and or accumulation on the soil surface prior to fumigation for open field applications In the case of raised bed applications rainfall that accumulates in the furrows of raised beds can sub or create saturation along the edges of the beds and reduce the movement of gas vapors to effectively treat the edges or shoulders of the beds Consult local weather conditions for the period 12 hours before fumigation and 24 hours post fumigation when fumigating open fields DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 35 p 4 T er E Irrigation System Considerations 1 Drip Line Considerations On raised bed drip applications ensure that tubing size drip emitter spacing and spacing between drip lines are sufficient to cover the fumigant area evenly and without over saturation Follow label instructions for emitter spacing and procedures and or restrictions regarding sources of water that can be used to connect to injection devices as well as use of back flow check valve prevention devices The number of drip lines depth 1 5 typically and spacing of each drip
32. reduce and or eliminate all leaks or spills if safe to do so Overhead water spray sprinklers may be used to reduce air concentrations Contain or absorb spill by covering the area with sand earth or vermiculite Use only spark free shovels and explosion proof equipment Collect recoverable product into labeled containers for safe transport and handling away from the area Collect all solid residues into seal able labeled containers for proper disposal Wash area with chemical detergent and water being sure to prevent runoff into drains and or from expanding the incident area After clean up operations dispose of all contaminated protective clothing and decontaminate all equipment if possible otherwise dispose of in accordance to all Federal and State regulations 20 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 General Use Precautions Always refer to product labels general use precautions include the following Follow all local government instructions for posting as per label requirements of treated areas with warning signs Comply with all local ordinances and regulations Do not apply within 30 m 100 feet of Sensitive Sites that are defined as nursing homes hospitals or prisons or licensed schools playgrounds state licensed day care centers any child care facility other than a family day care home including infant centers preschools extended day ca
33. target flow meter setting that is less than 15 or greater than 8596 is out of range and will require a different size flow meter not listed above 40 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA 2 Filtration Device Use of filters in line with the system will help support even flow of product from containers to the shank end Filters can be made of inert materials stainless steel polyethylene and or glass wool Avoid if possible mild steel or plastics PVC and rubber o rings as they may not be durable for long term use and or may become brittle 3 Fumigant Delivery to Start a Row The reduced density and the lower volatility of DOMINUS may present a challenge to achieve an adequate delivery at the beginning of each row At the end of the previous pass all hoses and manifold forward of the on off valve become void of fumigant due to gravity and the Venturi effect of the chisel being pulled through the soil Care must be taken when starting the next pass to achieve full flow of the system before proceeding down the row We recommend the manifold system for DOMINUS be constructed using the following criteria This method will assure a full flow and an even distribution for the entire pass 1 Use a manifold with sufficient outlets for each chisel See photo example below Mount the manifold in a secure level position and as close to the center of the applic
34. unauthorized people will enter the buffer zone area or inside the treated area Not respecting any or all of these requirements will increase the potential of personal exposure to humans and or the environment with DOMINUS soil fumigant Before leaving the site ensure that All entrances are adequately placarded to inform and prevent access by unauthorized personnel Warning tape if used is properly installed e Warning placards see below in place and Completed with all the required information o Date of application o Date and hour of Re Entry 5 days or 120 hrs from the end of the application o Contact name and phone number of the supervising applicator o Additional contact information phone number if required by local regulatory agencies Posted at all entrances or access points to the treated area as necessary to inform and prevent access Drip Application Equipment 1 Introduction DOMINUS is approved for application by drip injection Typically a drip injection system allows mixing and injecting of 1 or 2 different products For the purposes of this manual DOMINUS will be applied alone and directly into the irrigation system at a predetermined and prescribed concentration ppm Injection of DOMINUS with another fumigant product is not prohibited but for the purposes of this manual the details are specific to the physical and chemical properties of DOMINUS Care must be taken if this product is co injected wit
35. 11 48 0 5 10 57 0 1 906 10 lt 9 6 25 10 12 0 ne 12 2 1000 10 97 100 10 52 C1 5 ne 11 37 10 976 ne 0 1 8 83 50 8 69 ne 976 5 10 83 ne 8 29 5 8 50 8 35 973 2 873 50 11 84 ne 12 34 0 3 986 300 9 75 50 9 14 25 8 95 300 8 62 10 10 33 600 lt 10 2 9 65 50 10 59 0 001 10 37 908 25 11 75 1000 210 7 ne 11 04 10 9 79 5 9 66 200 965 200 3775 First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 66 Dichloropentafluoropropane Dichloropropane 1 2 Dichloro 1 propene 1 3 Dichloro 1 propene 2 3 Dichloro 1 1 1 trifluoroethane 2 2 Dichloro 2 4 6 trifluoropyridine 3 5 Dichlorvos Dicyclopentadiene Diesel Fuel Diesel Fuel 42 Automotive Diethylamine Diethylaminopropylamine 3 Diethylbenzene Diethylmaleate Diethyl sulfide Diglyme Diisobutyl ketone Diisopropylamine Diketene Dimethylacetamide N N Dimethylamine Dimethyl carbonate Dimethyl disulfide Dimethyl ether Dimethylethylamine Dimethylformamide N N Dimethylhydrazine 1 1 Dimethyl methylphosphonate Dimethyl sulfate Dimethyl sulfide Dimethyl sulfoxide Dioxane 1 4 Dioxolane 1 3 Dowtherm A see Therminol Synonym A
36. 2 Dichloro 1 1 1 trifluoroethane HCFC 141B see 1 1 Dichloro 1 fluoroethane HCFC 142B see 1 Chloro 1 1 difluoroethane 134 see 1 1 1 2 Tetrafluoroethane HCFC 225 see Dichloropentafluoropropane Heptane n Heptanol 4 Hexamethyldisilazane 1 1 522257 Hexamethyldisiloxane Hexane n Hexanol 1 Hexene 1 Dipropylcarbinol HMDS HMDSx Hexyl alcohol HFE 7100 see Methyl nonafluorobutyl ether Histoclear Histo Clear Hydrazine Hydrazoic acid Hydrogen Hydrogen cyanide Hydrogen iodide Hydrogen peroxide Hydrogen sulfide Hydroxypropyl methacrylate lodine 9 159 M Im uU Limonene corn oil reagent Hydrogen azide Synthesis gas Hydrocyanic acid Hydriodic acid 687 47 8 97 64 3 75 08 1 352 93 2 50 00 0 75 12 7 64 18 6 98 01 1 98 00 0 8006 61 9 8006 61 9 111 30 8 106 91 2 151 67 7 142 82 5 589 55 9 999 97 3 107 46 0 110 54 3 111 27 3 592 41 6 302 01 2 1333 74 0 74 90 8 10034 85 2 7722 84 1 7783 06 4 27813 02 1 923 26 2 7553 56 2 Formula CgHi0 C10H2002 C2H8N2 C2H602 C5HaO3 C4H1002 CaH46O3 CHOS C4H4100 C7H1403 C3HeO C44H2002 8 CoH12 C5H4003 C2HeS 105 CH3NO CH20O2 5 2 m w 72 m w 93 5 8 2 CoHBrCIF3 7 C7H160 CeH49NSIP CeH18O8Si2 CoHia CeH44O 12 1836 H4N2 H2 HCN HI H202 H2S C7H1203 l2 RAE
37. 48O3 C6H1202 C7H1202 C4H44N C4H1002 109 CS2 CCl COS RAE Systems Inc Technical Note TN 106 Revised 08 2010 9 8 NR NR NR 1 2 42 4 5 NR 11 0 50 0 89 0 55 1 4 0 7 0 9 NR NR 150 25 70 1 8 1 1 2 0 0 55 NR T T T T 10 6 6 22 6 1 1 1 1 1 1 6 0 52 1 2 NR 4 11 7 0 9 0 5 0 66 0 74 0 5 0 6 0 7 0 44 1 7 C IE eV 10 23 10 66 10 14 4 O o 15 5 10 51 8 98 10 10 48 9 07 10 9 84 10 53 9 90 9 58 lt 10 lt 10 6 lt 10 6 10 8 71 lt 10 9 14 10 07 11 47 11 18 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 TWA C25 10 5 500 5 40 0 1 2 2 2 1 25 100 0 05 0 5 0 1 0 5 800 100 25 150 10 5 a Compound Name Chlorine Chlorine dioxide Chlorobenzene Chlorobenzotrifluoride 4 Chloro 1 3 butadiene 2 Chloro 1 1 difluoroethane 1 Chlorodifluoromethane Chloroethane Chloroethanol Chloroethyl ether 2 Chloroethyl methyl ether 2 Chloroform Chloro 2
38. 52 5 79 46 9 111 84 2 64771 72 8 64771 72 8 556 67 2 107 51 7 111 65 9 111 66 0 109 66 0 79 21 0 79 21 0 127 18 4 Propylene glycol methyl ether 1 107 98 2 Methoxy 2 propanol Technical Note TN 106 Revised 08 2010 Formula 98 C 106 C gt NR NR 48 31 C4HaO 0 86 09 CoHeNo 1 4 1 2 C7H140 08 0 76 CeH420 09 08 CoH3NO NR 46 CoH3NS 05 045 CH4S 0 65 0 54 C5HaO2 27 15 CsHsFoO NR C6H16N2 06 C5H420 0 93 C5Ho9NO 10 08 13 09 CoH1o 0 5 C2HeS 0 49 044 m w 144 1 0 0 69 m w 142 10 0 7 C4HaCl2S 0 6 0 45 0 42 0 18 C40H44N2 2 0 NO 6 52 5 2 6 19 C2H5NO2 23 16 NR 2 C3HzNO2 1 4 161 3 2 11 m w 189 27 10 24 45 0 21 0 17 24 253 0 23 0 18 13 18 CaH4e 09 075 C5H42 80 84 NR 2 50 C2Cl4 0 69 0 57 C6H4203 24 15 RAE Systems Inc 11 7 0 89 2 5 1 1 1 3 0 79 0 9 0 9 0 46 0 38 0 3 0 28 0 14 0 17 0 4 2 3 2 5 0 31 1 1 C IE eV 11 32 10 03 9 51 7 7 9 28 9 30 10 67 9 25 9 44 9 7 9 0 9 38 9 17 9 8 18 8 69 8 13 8 8 lt 10 6 10 88 13 0 11 02 10 71 9 72 lt 10 0 9 82 co D gt 10 35 9 32 3775 First
39. AE 26 6 Basic PPE 26 Buffer Zone PP 28 1 Buffer Zone Definition 28 2 Buffer Zone 28 The Restricted Entry Period 29 CHAPTER 3 FACTORS AFFECTING FUMIGATION 30 Evalualionl 30 1 OWT VOC epee os Tau RESET eee 30 SOl MOSU a sus ERR SR RS EUER aon REG REGERE E E 31 Loamy fine and sandy soils 31 b Sandy loam and fine sandy loam 5 32 c Sandy clay loam loam and silt loam 15 32 d Clay clay loam and silt clay loam soils 33 3 Soil Temperature dou bo ER RA eo ee EE Sri s 33 4 DOMINUS Compatibility with Other Plant Protection Products 33 33 WAGON Wan 34 2 Good Sealing Of the 2545 2 34 Weather 5 eee ru Ep
40. Automatic Calculation of Correction Factors TLVs and Alarm Limits for Mixtures Calculations performed using Excel version of this database available on request CF CF CF Mol Conc TLV STEL Compound 9 8 eV 10 6 eV 11 7eV Frac ppm ppm Ppm Benzene 0 55 0 53 0 6 0 01 1 0 5 2 9 Toluene 0 54 0 5 0 51 0 06 10 50 150 Hexane n 300 4 3 0 54 0 06 10 50 150 Heptane n 45 2 8 0 6 0 28 50 400 500 Styrene 0 45 0 4 0 42 0 06 10 20 40 Acetone 1 2 1 1 1 4 0 28 50 750 1000 Isopropanol 500 6 2 7 0 28 50 400 500 1 1 1 0 00 0 1 Mixture Value 2 1 1 5 0 89 1 00 181 56 172 TLV Alarm Setpoint when ppm ppm ppm Calibrated to Isobutylene 26 37 62 ppm ppm ppm STEL Alarm Setpoint same Calibration 86 115 193 ppm ppm ppm RAE Systems Inc 12 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com 72 DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 73 N 74 The ToxiRAE Pro PID is the world s smallest wireless volatile organic compounds VOC monitor The ToxiRAE Pro PID takes worker protection to the next level by providing safety professionals wireless access to real time instrument readings and alarm status from any location for better visibility and faster response Featuring RAE Systems next generation PID sensor the
41. E ad 35 1 Temperature Inversion 35 2 2 252242 35 35 35 Irrigation System 36 1 Drip Line Considerations 36 2 Drip Emitter Checking ua x acoge nex ee ee ee ee ee se ee ee ee ee ee 36 3 Irrigation System Compatibility with DOMINUS 36 Product Compatibility with Application 36 CHAPTER 4 APPLICATION EQUIPMENT CALIBRATION AND 37 Application Equipment General Information 37 Shank Application 1 37 DOMINUS Shank Equipment Calibration 38 uou saddest eee eee AE ERES 38 2 Filtration Device ee 41 3 Fumigant Delivery to Start 41 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 3 DOMI
42. GASTEC Tube is able to detect potentially dangerous levels of AITC from 5 to 200ppm the GASTEC Tube detection limit of 5 parts per million ppm is insufficiently sensitive to reliably detect lower concentrations of AITC in the breathing space of a worker at a level of potential health concern gt 2 Therefore when determining the concentration of AITC in the breathing space of a worker another more sensitive device that can detect 2ppm or less such as the Entry RAE monitor should be used Tube Data Methyl methacrylate Allyl isothiocyanate 5 200 2 For production information and purchase of manual electronic detection devices contact Email Nextteq at info nextteg com or call us toll free at 877 312 2333 ext 20 for information on an authorized distributor in your area For use of the Entry Rae Mini Rae or Toxi Rae type electronic gas detection devices contact RAE Systems Inc 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Website www raesystems com Note An electronic device or other monitor capable of detecting AITC down to 2ppm or less must be present where workers handle or use AITC containing products Any air detection device that has been used for any other fumigant will first need to be qualified and approved by ISAGRO USA before use with AITC containing products User notice please refer to the technical data sheet for this device and its use direc
43. HCls CH3Cls5Si CeH45N CeH45O3B 5 C2HsF3 CsHoN C3H903B C3H904P C10H16 C11H24 4 CoHsBr CaH12 CeHo9NO m w 111 CaH10 CaH10 CaH10 9 8 1 4 0 7 NR 0 62 NR 0 95 0 37 1 7 0 50 0 56 0 48 1 1E 6 5 1 8 0 1 1 0 30 0 8 0 97 0 44 0 46 0 39 1 1E 6 Technical Note TN 106 Revised 08 2010 11 7 CIE eV TWA 2 0 0 002 9 04 C5 1 T 11 350 0 9 11 0 10 0 43 947 50 1 8 11 36 11 99 1000 0 65 7 3 1 1 1 10 0 60 9 79 34 12 9 7 82 5 25 1 2 10 1 1 3 9 99 8 5 2 0 29 8 20 9 56 ne 10 919 10 9 80 5 06 9 99 5 9 83 0 1 0 9 300 0 40 856 100 0 43 8 56 100 0 38 844 100 1 1 6 adsorption or EntryRAE Response on multi gas meters can give an indication of relative concentrations but may not be quantitative and for some chemicals no response is observed Therminol amp is a registered Trademark of Solutia Inc m 11 RAE Systems Inc 3775 First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 T1 C Technical Note 106 Revised 08 2010 Appendix l Example of
44. NUS 4 Fumigant Rig Operation at the Beginning of a 42 5 Prior to Leaving the Injection 43 Drip Application eee en woes RR RE RE ER RR Pu ES SEES ae REG 43 DEM 43 2 Equipment Use and Determination 44 3 DOMINUS Product 46 a Equipment leaks lt 46 b Beginning 46 c Ending 255254555 as Ce i c aod 46 d Prior to leaving the injection site 46 Re entry 50 APPENDIX A 51 ENTRY RAE USER MANUAL 284555555 Gentoo ee ee ee ee ee ee ee ee ee ee ee nee nee ee nee ee ee nee ee 53 Entry RAE User Notice code ee X cx Rod EU a od Ree HOSES REDS eo o Rae dae x edis ne 53 1 Physical 53 2 Display and LCGCNG
45. Push on Y until reaching the number 9 Push on mode then you can enter the third number Push on Y until reaching the number 9 You get now 999ppm as high value of detection High Push on mode he following signage comes Push on Y and mode on same time to validate the value 999ppm 11 Adjust Low a Make the same procedure as describe before b Set the Low value to the AITC detection limit of 2ppm by entering 002 ppm DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 59 60 DOMINUS Fumigation Management Program Stewardship Technical Training Manual July 2014 Technical Note TN 106 Revised 08 2010 Correction Factors lonization Energies And Calibration Characteristics Correction Factors and Ionization Energies RAE Systems PIDs can be used for the detection of a wide variety of gases that exhibit different responses In general any compound with ionization energy IE lower than that of the lamp photons can be measured The best way to calibrate a PID to different compounds is to use a standard of the gas of interest However correction factors have been determined that enable the user to quantify a large number of chemicals using only a single calibration gas typically isobutylene In our PIDs correction factors can be used in one of three ways 1 Calibrate the monitor with isobutylene the usual fashion to read isobu
46. S in pipes constructed with clay or porous materials where fumigant can be trapped adsorbed and or not successfully purged from the system DO NOT APPLY DOMINUS IN PIPE OR IRRIGATION LINES THAT MAY COME IN CONTACT WITH DRINKING WATER SUPPLIES OR NON TARGETED AREAS THE SYSTEM MUST CONTAIN A FUNCTIONAL SYSTEM COMPRISED OF A CHECK VALVE VACUUM RELIEF VALVE INSPECTION PORT AND LOW PRESSURE DRAIN APPROPRIATELY LOCATED ON THE IRRIGATION PIPELINE TO PREVENT WATER SOURCE CONTAMINATION FROM BACK FLOW Product Compatibility with Application Equipment Please refer to Chapter 1 Product Description Section 5 Product Compatibility in this manual 36 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 DOMINUS APPLICATION METHODS SGOHLAW NOILVOl 1ddV USA CHAPTER 4 APPLICATION EQUIPMENT CALIBRATION AND SETTING Application Equipment General Information Refer to product labels for specific equipment and maintenance requirements for both drip and shank applied products DOMINUS is sold in 1000 liter Industrial Bulk Containers IBC steel lined drums or US DOT approved mild steel cylinders Do not transfer the contents to any other container before use DOMINUS must be removed from the IBC and steel drums with use of a closed system pumping system Under no circumstances is DOMINUS to be removed by pouring from the container where the contents would be subjected to op
47. Systems Inc Technical Note TN 106 9 8 0 52 0 9 0 4 13 0 60 NR NR 0 33 350 0 5 28 NR NR NR NR 9 9 0 1 10 6 0 52 0 52 0 8 16 8 2 0 86 11 7 0 51 0 51 1 0 6 0 7 0 5 0 6 0 9 0 6 0 60 0 2 0 25 0 54 0 55 0 3 21 1 1 0 1 Revised 08 2010 C IE TWA 877 100 8 6 10 1016 C100 lt 10 6 9 2 ne lt 10 6 9 65 10 57 1 9 51 400 ne 10 61 100 ne lt 10 6 lt 88 ne 10 ne 9 29 0 5 8 43 ne 10 87 10 16 10 11 33 5 9 21 2 lt 9 5 10 300 300 0 05 0 5 11 0 50 9 92 400 9 61 ne 8 6 ne 9 64 ne 10 13 50 9 89 ne 9 44 30 8 1 0 01 10 7 15 43 13 6 4 7 10 39 10 54 1 10 45 10 940 0 1 3775 First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 67 lodomethane Isoamyl acetate Isobutane Isobutanol Isobutene Isobutyl acrylate Isoflurane Isooctane Isopar E Solvent Isopar G Solvent Isopar K Solvent Isopar L Solvent Isopar M Solvent Isopentane Isophorone Isoprene Isopropanol Isopropyl acetate Isopropyl ether Jet fuel JP 4
48. The use of DOMINUS requires equipment evaluation to assure that each applicator can correctly apply DOMINUS with the proper application equipment Utilize the following procedure to evaluate current application equipment capabilities Make changes necessary prior to beginning any DOMINUS application DOMINUS Shank Equipment Calibration Instructions The following are specific instructions for the use of the DOMINUS Calibration Form provided as an Excel spreadsheet Calibration is accomplished by a calculation of ground speed Never attempt to monitor the outflow of the application equipment to determine the amount applied A check of the equipment setting can be obtained by measuring the amount of area covered by a cylinder with a known beginning and ending weight 1 Instructions Step 1 Step 2 Step 3 Step 4 Step 5 Measure and mark 100 feet 31 m of a row in the field where you will be making the application Drive the tractor past this measured section at the speed you desire to make the application The applicator must engage the soil just as it will during the application but do not turn on the fumigant valve Record the time required to travel the measured distance Never use the tractor speedometer as it does not adjust for wheel slippage and may not provide an accurate reading Measure the treatment width and convert it to feet Determine the broadcast rate for the formulation of DOMINUS that you are using by co
49. Wireless DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 ToxiRAE Pro Personal Wireless Monitor for Volatile Organic Compounds SPECIFICATIONS Size 4 6 H x 2 4 W x 1 2 D 118 x 60 x 30 mm Weight Sensor Detectable Gases 8 29 oz 235 9 Photoionization sensor with 10 6 eV standard or 9 8 eV optional lamp Response time 15 sec Isobutene Field replaceable sensor Easy access to lamp for cleaning A wide variety of ionizable chemicals using 190 built in and over 300 published correction factors Rechargeable Lithium ion battery Battery Operating time 12 hours normal operation Recharge time 4 hours through charging cradle TE Graphical LCD display with white LED backlighting activated when monitor is ba in alarm or with a button press Real time reading of VOC concentrations in parts per million or mg m3 battery status data logging on off wireless on off and reception quality STEL TWA and peak values Calibration and measurement gases correction factors Keypad 2 buttons for operation and programming sampling Internal fan Calibration Automatic with AutoRAE 2 Test and Calibration Station or manual Wireless remote alarm notification 2 audible 95 dB 30 cm vibration visible alarm flashing bright red LEDs and on screen indication of alarm conditions mass High alarm 3 beeps and flashes per second
50. and unacceptable levels of fumigant gas gt 2 ppm Immediately cease all activities and wear all PPE to inspect all equipment for any leaks and or malfunctions Do not continue use until all corrective actions have been taken to resolve the issue and AITC concentrations are determined to be lt 2ppm and or undetectable by smell 26 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 Accident DOMINUS personal exposure Call Poison Center First Responders immediately Accident In a confined area Move person to fresh air Type of exposure Skin exposure Put on The Appropriate PPE Eye exposure Move person into safety position Take off Rinse eyes contaminated slowly for 15 clothes Is person 20 minutes breathing Rinse skin Oh ae A Give artificial with plenty o Do not induce respiration using water for 15 vomiting 20 minutes appropriate material if qualified Wait for evacuation of the person s by emergency personnel Call CHEMTREC 24h number to report the incident Call 9 1 1 ambulance and or CHEMTREC 800 424 9300 ISAGRO Eastern Representative 863 840 4600 ISAGRO Western Representative 559 903 4653 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 27 28 Buffer Zone 1 Buffer Zone Definition The buffer zone is the area
51. apor removing cartridge with pre filter approved for pesticides must be available on site and provided to workers if sensory irritation occurs Whenever contact with liquid or vapors is a potential all handlers including mixers loaders and applicators in addition to the above listed PPE must wear an air purifying respirator with an organic vapor removing cartridge with pre filter approved for pesticides MSHA NIOSH approval number prefix TC 23C or a canister approved for pesticides MSHA NIOSH approval number prefix TC14G or a NIOSH approved respirator with organic vapor OV cartridge or canister with any P or HE pre filter It is required that all respirator users be fit tested yearly and cleared by a medical practitioner prior to handling or working with DOMINUS See OSHA guidelines 29CFR 1910 134 for respiratory protection that must be reviewed and complied with prior to use of respirators Medical considerations for potential users of DOMINUS In the event that any medical issues prevent the handler applicator from wearing a respirator he or she is not allowed to apply DOMINUS or work within the treatment area during application or restricted entry interval 24 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA Do not wear respiratory protection if you have Respiratory diseases like emphysema asthma skin allergies e Circulatory problems high blood pre
52. ate 109 60 4 C5H1002 9 9 2 3 10 04 200 Propylamine 1 Propylamine 107 10 8 1 1 44 09 878 1 Aminopropane Propylene carbonate 108 32 7 C4HeO3 62 1 10 5 ne Propylene glycol 1 2 Propanediol 57 55 6 18 5 5 16 102 Propylene glycol propyl ether 1 Propoxy 2 propanol 1569 01 3 1 3 10 16 Methyloxirane 75 56 9 240 66 29 10 22 20 16088 62 3 15448 47 2 Propyleneimine 2 Methylaziridine 75 55 8 C3H7N 15 1 3 10 9 0 2 Propyl mercaptan 2 2 Propanethiol Isopropyl 75 33 2 5 0 64 0 66 9 15 ne mercaptan Pyridine 110 86 1 C5H5N 0 78 07 07 925 5 Pyrrolidine coats lamp Azacyclohexane 123 75 1 C4H3N 21 13 16 80 ne RR7300 PGME PGMEA 70 30 PGME PGMEA 1 107 98 2 C4H100 1 4 1 0 ne Methoxy 2 propanol 1 Methoxy C6H41203 2 acetoxypropane Sarin GB Isopropyl 107 44 8 C4H4o0F O P 3 methylphosphonofluoridate 50642 23 4 Stoddard Solvent see Mineral Spirits 8020 83 5 Styrene 100 42 5 0 45 040 04 843 20 Sulfur dioxide 7446 09 5 02 NR NR 12 32 2 Sulfur hexafluoride 2551 62 4 SFe NR NR NR 15 3 1000 Sulfuryl fluoride Vikane 2699 79 8 SO2F2 NR NR NR 13 0 5 Tabun Ethyl N N 77 81 6 C5H14N202P 0 8 15ppt dimethylphosphoramidocyanidate Tetrachloroethane 1 1 1 2 630 20 6 C2H2Cl4 1 3 11 1 ne Tetrachloroethane 1 1 2 2 79 34 5 C2H2Cl4 NR NR 0 60 11 1 1 Tetrachlorosilane 10023 04 7
53. ation machine as possible 2 Add an additional filter equipped with a 50 or a 100 mesh screen at the inlet of the manifold to insure that the small yellow tubes remain open and delivering fumigant Do not eliminate the standard filter in the system Use this filter as a secondary filter 3 The fumigant path from the on off valve to the chisels should be as short as possible to minimize the fill requirements at each row start To minimize the fill requirements we recommend an electric ball valve be used as the on off valve and be mounted at the inlet of the new filter and the manifold 4 Adjust tubing size to match the desired output of material while maintaining even flow to each shank end Because DOMINUS is close to the same density as water the flow can be first checked with water or similar product density i e light oil linseed oil Note that to help ensure flow delivery tubing length must be equal and of a minimum length typically in the range of 3 9 for in line pressure equilibration 5 Equip the manifold with a good quality pressure gauge mounted on an extension pipe so that the driver can easily view the gauge This allows the driver to monitor the manifold system operation 6 We recommend individual site glasses for each chisel be used on the manifold to monitor for uniform delivery 7 Do not tightly coil the tubing The coil will increase the resistance to flow and reduce the capacity of the tube DOMINUS Fumiga
54. aw including but not limited to the following Ensuring that all persons who are not trained and equipped with Personal Protective Equipment PPE and who are not performing one of the handling tasks listed on product labels are excluded from the application block during the entry restricted period Ensuring that all handlers engaged in the handling and or application of DOMINUS are equipped with the label defined PPE and have been instructed in the proper use and maintenance of all PPE Ensuring that all handlers who may or will wear a respirator understand its proper use to protect themselves against inhalation exposure Ensuring that the 25 buffer zone measured from the edges of the treated area is maintained from the start of the application until 24 hours following the end of the application Buffer zones must be under the control of the supervising applicator and must not include property that is not under the control of the supervising applicator unless written permission is obtained prior to fumigation The supervising applicator must use an appropriate means to manage and maintain the buffer zone such as posting Buffer Zone signs around the perimeter of the buffer zone at potential points of entry using trained workers to patrol the buffer zone or other equivalent means Buffer zones must be posted from the start of the application until 24 hours following the end of the application and must be removed within 3 days of the end of th
55. bbreviation AK 225 mix of 45 3 3 dichloro 1 1 1 2 2 pentafluoro propane HCFC 225ca amp 55 1 3 Dichloro 1 1 2 2 3 pentafluoropropane HCFC 225cb R 123 DCTFP Vapona O O dimethyl O dichlorovinyl phosphate DCPD Cyclopentadiene dimer See Dowtherm J see Ethyl sulfide see Methoxyethyl ether DIBK 2 2 dimethyl 4 heptanone Ketene dimer DMA Carbonic acid dimethyl ester DMDS see Methyl ether DMEA DMF UDMH DMMP methyl phosphonic acid dimethyl ester see Methyl sulfide DMSO Methyl sulfoxide Ethylene glycol formal Dowtherm J 97 Diethylbenzene DS 108F Wipe Solvent Epichlorohydrin Ethane Ethanol Ethanolamine Ethene Ethoxyethanol 2 Ethyl acetate Ethyl acetoacetate Ethyl acrylate Ethylamine E Im a Ethyl lactate Isopar H Propoxypropanol 7 2 1 ECH Chloromethyloxirane 1 chloro2 3 epoxypropane Ethyl alcohol MEA Monoethanolamine Ethylene Ethyl cellosolve CAS No 442 56 0 507 55 1 78 87 5 542 75 6 78 88 6 306 83 2 1737 93 5 62 73 7 17 1 3 6 68334 30 5 68334 30 5 109 89 7 104 78 9 141 05 9 111 96 6 108 83 8 108 18 9 674 82 8 127 19 5 124 40 3 616 38 6 624 92 0 598 56 1 68 12 2 57 14 7 756 79 6 77 78 1 67 68 5 123 91 1 646 06 0 25340 17 4 97 64 3 64742 48 9 1569 01 3 106 89 8 74 84 0 64 17 5 141 43 5 74 85 1 110 80 5 141 78 6 141 97 9 140 88 5 75 04 7 Technical Not
56. daries of the soil texture classes are inside the triangle The intersection of the three sizes on the triangle gives the texture class For instance if you have a soil with 2096 clay 6096 silt and 2096 sand it is in the silt loam class DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 Y 1 MNA p VE y 2 Soil Moisture Do not apply DOMINUS fumigant in wet or saturated soils Apply irrigation as necessary to ensure a uniform moisture level in the fumigant zone 0 9 depth Target moisture that will allow weed seeds to swell typi cally 12 1596 but not more than 19 soil moisture or gt 60 Field Capacity FC Soil type must be considered when determining conditions for application in accordance with 96 soil moisture or FC See examples below The feel and appearance method is a way of monitoring soil moisture to determine when and how much to irrigate a Loamy fine and sandy soils Appearance Field capacity determined Dry loose will hold together if not disturbed loose sand grains on fingers 0 2596 with applied pressure DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 AN USK 31 b Sandy loam and fine sandy loam soils Appearance Field capacity determined Dry forms a very weak ball aggregated soil grains break away easily from ball 75 100 c Sandy clay
57. dose rate applied per treated area 3 Reduces the potential risk of personal exposure because of lower air concentration 4 Allows for greater regulation of soil temperature and or moisture in the treated soil 1 Type of Tarp Finally the decision on which type of film to use may impact the emissions or flux rate of vapor released through the plastic tarp over time the application rate and planting interval after application as well as influence the efficacy against the targeted pests The tarps films or mulches come in two different categories as defined below 1 Low Density Polyethylene PE or LDPE These can be single to multi layer film with flux emissions typically 25096 2 Highly Retentive Films HRF such as Virtually Impermeable Films VIF or Totally Impermeable Films VIF These are films with at least 2 layers of polyethylene bonded perpendicular to each other with a 3rd layer of polyamide nylon or a 5 layer film with the composed 3 layers above plus 2 layers of adhesive resin The 3 layer films are termed Virtually Impermeable Film VIF while the 5 layer films are defined as Totally Impermeable Films The 3 to 7 layer films have a flux typically 2596 emissions and significantly reduce peak emissions concentration compared to LDPE As a rule follow the recommendations provided on the DOMINUS label and use the guidelines listed below All film types are allowed for all DOMINUS applications use of TIF pr
58. dship and Training Manual July 2014 19 Transport Incident TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES FOR DOMINUS Small Spills lt 2001 or 53 gallons Large Spills gt 200L or 53 gallons First isolate in all Then protect persons downwind First isolate in Then protect persons downwind directions during directions during Night Day Night Meters Feet K Feet Day Miles y Km Meters 25 80 01 02 250 820 2 08 05 Procedures and actions the event of a DOMINUS involved incident Clear area of personnel and move upwind Alert Emergency Responders and tell them location and nature of hazard Observe and prevent conditions that may favor potential for the product to react explosively Wear all label required PPE Prevent by any means available spillage from entering drains or water course Hemove all workers and bystanders from the affected area to a place that is upwind and away from any potential exposure Do NOT allow smoking naked lights or ignition sources within close proximity to the incident If indoors take necessary steps to increase ventilation and air mixing Move all unnecessary persons to outdoors and upwind from incident site If outdoors remove all unnecessary persons to a location away from and upwind of the incident site and take necessary precautions to perform clean up and containment work upwind from spill Take action to
59. e 106 Revised 08 2010 Formula 5 2 C3H4C12 C3H4Cl2 CoHCloF3 Cs5CloF3N C4H7Cl204P C10H12 m w 226 m w 216 C7H18N2 CaH4204 CeH44O03 CeH45N C4Ho9NO CoH7N C2HeS2 C4H41N C3H7NO gt 4 gt C2HeO4S gt 5 gt C10H14 m w 118 C2H5CIO C2He 2 7 CoH C4H 1002 2 CeH4003 gt CoH7N RAE Systems Inc 9 8 NR 1 9 1 1 0 57 fa 0 71 0 84 0 87 NR 0 2 NR 23 4 0 3 3 200 5 6 1 4 10 66 117 0 9 0 9 0 48 0 7 1 3 0 61 0 74 0 8 1 5 70 0 20 1 6 1 3 4 6 1 2 2 4 0 8 E 25 0 7 0 7 10 1 0 8 0 43 0 4 3 5 1 0 1 0 CIE eV TWA ne 10 87 15 lt 10 1 t 10 ne t 11 5 ne T ne 94 041 T 8 8 5 11 T 11 8 01 5 ne ne 9 04 25 7 73 5 T 96 0 5 8 81 10 8 23 5 10 5 T 7 4 T 7 74 3 T 9 13 10 T 7 28 0 01 T 10 0 ne T 0 1 9 10 ne 9 19 25 T 9 9 20 T ne T 10 2 0 5 11 52 ne 10 47 1000 8 96 3 10 51 ne 9 6 5 10 01 400 t 10 ne 10 3 5 8 86 5 3775 First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Prog
60. e a Hydroxytoluene Hydroxymethylbenzene Benzenemethanol a Chlorotoluene Chloromethylbenzene Formic acid benzyl ester Tribromomethane n Propyl bromide 1 3 Butadiene Vinyl ethylene 1 2 3 4 Diepoxybutane 1 Butanal Butyl alcohol n Butanol tert Butanol t Butyl alcohol 1 Butylene Butyl Cellosolve Ethylene glycol monobutyl ether Ethanol 2 2 butoxyethoxy acetate 2 2 Butoxyethoxy ethanol Butyl 2 propenoate Acrylic acid butyl ester see 2 Butoxyethanol 1 Butanethiol Tetrachloromethane Carbon oxysulfide CFC 14 see Tetrafluoromethane CFC 113 see 1 1 2 Trichloro 1 2 2 trifluoroethane DB Y LE M gt Im 5 75 07 0 64 19 7 108 24 7 67 64 1 75 86 5 75 05 8 14 86 2 107 02 8 79 10 7 107 13 1 107 18 6 107 05 1 7664 41 7 628 63 7 75 85 4 62 53 3 100 66 3 7784 42 1 100 52 7 100 61 8 71 43 2 100 47 0 100 51 6 100 44 7 104 57 4 7637 07 2 7726 95 6 108 86 1 6482 24 2 75 25 2 106 94 5 106 99 0 298 18 0 123 72 8 106 97 8 71 36 3 75 65 0 106 98 9 111 76 2 124 17 4 112 34 5 123 86 4 141 32 2 109 73 9 111 76 2 75 91 2 109 79 5 75 15 0 56 23 5 463 58 1 Formula C2H4O C2H402 C4H6O3 C4H7NO C7H1402 C5H120 C7H7N C7HgO C7H7Cl gt Bro CeHsBr C3H7OBr C3H7Br C4He C4HeO 2 C4HaO C4H10 CgH1402 2004 CaH
61. e area and put it in its charger Calibration for DOMINUS Detection 1 Turning the Monitor ON 1 Pressthe button for 1 second Press and hold N for seconds Fresh Air press Y to zero for all sensors The sensor displays Cal Updtng and is updating data Push until arriving at the display Span Cal VOC DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 UPgRE AS a M Ns 6 Display Span Cal VOC 7 standard gas 100ppm Isobutylene Gas connector 9 Press Y wait for the countdown 30 seconds 10 Press to return to monitor mode DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 55 S Fresh Air Calibration Span Calibration Span Calibration Zero Calibration Calibration Due Day Set Type Set Run Silent Adjust LOW VorN Adjust TWA Adjust STEL Enabie Sensor Adjust Date Set LEL Unit Change Password Secure Beep Must be in clean ambient air Must use four gas calibration mix CO H S and LEL Must use 100 ppm Isobutytene gas PID Must use Nitrogen 100 Sets a reminder Default 30 days 365 days Auto Alarm Reset or Latch Default Auto Runs in Silent Default No Adjusts High Alarm presets Adjusts Low Alarm presets Adjusts TWA presets Adjusts STEL presets Enable or disable sensor Adjust date and time Selec
62. e buffer zone period The buffer zone signs must include the same warning symbol and statements required for Fumigant Treated Area signs as stated on this label and or in accordance with local governing laws and regulations Ensuring that unprotected workers and bystanders not in transit do not enter the buffer zone from the start of the application until 24 hours following the end of the application Ensure the buffer zone is well secured to prevent disturbance from animals and to keep unauthorized non fumigant persons from staying in the treated area and or buffer zone during the buffer zone period However travel by unprotected workers or bystanders through the fumigated or treatment area itself is prohibited during the entire Restricted Entry Period REP Handlers protected with required PPE may work in buffer zones See the PERSONAL PROTECTIVE EQUIPMENT section on product labels Ensuring that there are no sensitive sites within 100 feet of the edge of the fumigated area A sensitive site is defined as occupied nursing homes hospitals or prisons and occupied licensed schools state licensed day care centers any child care facility other than a family day care home including infant centers preschools extended day care facilities and school age child care centers playgrounds and licensed assisted living facilities licensed by state or local governments Ensuring the use of standard Good Agricultural Practices GAPs Providing a
63. e parts 1 Wireless functionality is scheduled for availability in 2011 in North America and Europe Contact RAE Systems for availability in other regions Contact RAE Systems for availability 3 Available with Industrial Hygiene configurations only 4 Specifications are subject to change 5 Wireless units have a functioning RF modem and are ready for wireless deployments Wireless capable units can be upgraded to wireless in the field for a fee Non wireless units cannot be upgraded to wireless Additional equipment and or software licenses may be required to enable remote wireless monitoring and alarm transmission WWW raesystems com RAE Systems Inc 3 75 North First Street San Jose CA 95134 USA raesales raesystems com DS 1063 01 USA Canada 1 877 723 2878 Europe 45 8652 5155 Middle East 971 4 440 5949 China 86 10 5885 8788 Asia Pacific 852 2669 0828 TOXIRAE PRO PID COMES WITH ToxiRAE Pro PID monitor with sensor as specified alligator clip protective rubber boot and rechargeable battery installed e Charging and PC communication cradle e PC communication cable e AC adapter 100 to 240 V 50 60 Hz AC to 12 V DC e Calibration adapter e Combined instrument sensor cap removal tool e Quick Start Guide e CD with documentation e ProRAE Studio software for PC based instrument configuration and data management e Technical Note TN 106 with ionization energies and correction factors for 300 VOCs Indu
64. en air DOMINUS must be removed from US DOT mild steel cylinders by introducing compressed nitrogen gas via the pressurization port of the cylinder Maintain a functional check valve at the outlet of the nitrogen or inert gas regulator to prevent contamination of the regulator and the propellant tank Liquid DOMINUS must be delivered through a flow meter and a rate control device flow divider or manifold via proper hoses Use only plumbing materials made of brass stainless steel Teflon or polyethylene Never use magnesium or copper Replace all frayed or broken hoses Check packing on all ball valves Replace if worn Replace chisels if fumigant tube steel tubing welded to the backside of a shank is worn or damaged Test for leaks by pressurizing the application equipment with inert or compressed gas Spray all connections with soapy water solution Repair all leaks before beginning the application Frequently monitor and verify proper flow meter output The use of DOMINUS may require modifications to the application equipment to ensure proper distribution to each chisel due to small volumes used per treated area Consult your supplier to insure that the proper modifications have been completed on your application equipment before you begin the application Shank Application Equipment It is required that older flow meters re calibrated to verify flow accuracy and fit before use with DOMINUS
65. ence over any recommendation and or guidance provided herein The information provided in this manual is to be considered recommendations for the proper use and application of DOMINUS pre plant fumigant with approved soil injection equipment Along with every use and application of DOMINUS is a comprehensive stewardship program whose main objective is to establish a DOMINUS Soil Fumigant Stewardship and Training Program that promotes the safe handling of DOMINUS Technical and its formulations and to ensure that DOMINUS product s are used manner consistent with all label requirements and use directions All applicators and handlers of DOMINUS are required to successfully complete the annual DOMINUS otewardship and Training Program prior to use 2 About This Manual The DOMINUS Soil Biofumigant Stewardship and Training Manual is advisory in nature and provides additional information and recommendations for the use of DOMINUS formulations This training manual is not to be interpreted as label language and as such does not replace use instructions and restrictions provided by DOMINUS labels In all cases the product label contains the most current use instructions and restrictions for use of DOMINUS formulations and supersedes any recommendation contained in this manual The user shall comply with all directions contained in the product label ISAGRO USA has developed the DOMINUS Soil Biofumigant Stewardship and Training Program fo
66. face whitening a 3000ppm Nvlon Paten Avoid contact with neat material as degradation may occur y Contact allowed only when product is diluted in water Appearance did not change with any formulation of DOMINUS No change in weight as a result of exposure to all formulations of DOMINUS Not effected at 3000ppm Caution Literature reports that no degradation with use of these materials Laboratory testing and literature reports that no degradation with Stainless Steel 304 and 316 Aluminum or their alloys Neoprene natural or butyl Caution use of these materials Slight to significant adsorption and loss of rubber surface sheen Neoprene showed slight to moderate softening Results from ISAGRO USA conducted material compatibility study DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 13 DOMINUS Dose Rates DOMINUS product and dose rates are listed in the attached table please refer to product labels for the most recent information 1 Broadcast Acre Application Rates For Pre Plant Fumigation Standard Standard Rate and Highly Formulated USA Retentive Films FP Product formulation DOMINUS 9 85 1000 8500 00020 95 25 0 0130 93 53 5 914 DOMINUS 59 128 1500 127 50 0 0029 142 88 0 0196 14029 1429 1372 DOMINUS 9 170 2000 170 00 0 0039 190 51 0 0261 187 05 1905 1829 DOMINUS 9 213 2500 212 50 0 0049
67. g crops Formulators and or applicators should request an explanation of the soil preparation practices prior to application of DOMINUS Tarps and Films It is important for applicators and growers to understand both the commonality and differences in various terms used for materials that cover soil in fumigated areas Terms such as tarps films and mulches are used interchangeably and ISAGRO USA uses all three terms to refer to coverings used in soil fumigant applications DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 33 34 Traditionally the term tarp has more often been used to describe broadcast or flat fume application sites but the term film is also an acceptable equivalent In the case of raised bed applications the term tarp is used less frequently and the term film is used more frequently Lastly the term mulch is exclusive to raised bed applications where the film is most often colored white black red silver green etc All of these films are variations of plastic layers bonded with polymers or nylon and may or may not be em bossed The use of embossing is a structural benefit exclusive to raised bed applications The injection of DOMINUS soil fumigant that takes place under a plastic covering or tarp provides 4 benefits 1 Increases the effectiveness of the product by preventing its dissipation and retaining it in the soil 2 Increases the effective
68. h another fumigant product to ensure compatibility concentration and delivery in the system is accurate In addition the safety and use recommendations will be determined by the product having the most protective requirements and regulatory restrictions The quantity of product applied is defined by the user prior to injection and based on several known factors soil type water flow drip tape type and emitter flow rate to reach the desired pest and disease control in the treatment area DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 43 2 Equipment Use and Determination Step 1 Determination of the amount of water to be brought during the application process Wetting phase Delivery of DOMINUS Flushing phase a Determination of the soil type see Chapter 3 for selection of soil type b Determination of the initial soil moisture c Use the diagram below to get an estimation of quantity of water to be applied during the application process DOM NUS Drip Injection Water Volumes Inches to Deliver Moisture and Soil Type 3 9 3 25 Initial Moisture Target Zone 1 5 1 0 5 0 0 10 20 30 Diagram 1 Determination of the water to be applied depending on type of soil and initial moisture Example Soil type Sandy Initial Moisture 40 Total quantity of water to be applied indicated on the diagram is 0 60 inches Step 2 Calculation of the total treated area
69. he use of gloves for all activities where liquid contact is possible will prevent skin contact with DOMINUS Note The gloves must be worn with Protective outerwear over field clothes or with a coverall Tyvek type sleeve over the cuff of the glove to avoid potential trapping of any fumigant vapors between skin and inner liner Ensure that gloves are the right size for all applicators DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 23 Al is N c Foot Protection CLOSED SHOES NOT MADE of ABSORBENT TYPE MATERIALS ALONG WITH SOCKS MUST BE WORN DURING THE HANDLING OF DOMINUS DURING APPLICATION AND WITHIN THE BUFFER ZONE The wearing of shoes prevents potential exposure to DOMINUS and protects against mechanical injury while handling equipment Note The shoes are to be free of holes or tears and impermeable to liquid contact with skin in order to avoid the trapping of DOMINUS between shoes and skin 3 Respiratory Protection FULL FACE MASK or HALF FACE MASK IN COMBINATION WITH SAFETY GLASSES AND APPROVED CARTRIDGES TO PROTECT AGAINST AITC VAPORS MUST BE WORN AS NECESSARY DURING THE APPLICATION PROCESS RE ENTRY AND ALL OPERATIONS WHERE CONTACT WITH LIQUID DOMINUS IS POSSIBLE AND OR VAPORS CAN BE DETECTED The use of properly fitting respiratory protection devices prevents potential inhalation of DOMINUS Respirators with an organic v
70. inylidene chloride c 1 2 DCE cis Dichloroethylene t 1 2 DCE trans Dichloroethylene R 141B see Methylene chloride CAS No 7782 50 5 10049 04 4 108 90 7 98 56 6 126 99 8 75 68 3 75 45 6 75 00 3 107 07 3 111 44 4 627 42 9 67 66 3 563 47 3 76 06 2 95 49 8 106 43 4 79 38 9 75 77 4 108 39 4 95 48 7 106 44 5 123 73 9 4170 30 3 98 92 98 506 68 3 506 77 4 110 82 7 108 93 0 108 94 1 110 83 8 108 91 8 287 92 3 765 30 0 541 02 6 141 62 8 124 18 5 123 42 2 124 48 1 96 12 8 106 93 4 95 50 1 75 71 8 75 78 5 107 06 2 75 35 4 156 59 2 156 60 5 1717 00 6 Technical Note TN 106 Revised 08 2010 Formula Clo CIO 5 C H4CIF3 C4HsCI C2H3CIF2 gt 2 2 5 C4HaCl20 C3H CIO CHCI C4H CI gt C7H7Cl C7H7Cl C2CIF3 CsHoCISi C7HgO 4 CoH12 CNBr CNCI CeH12 12 0 CeH10 CeH13N 5 C3H7N C10H3005Si5 C10H3003Si4 C10H22 1202 gt C3HsBroCl CoHaBro C6H4Cl2 CCloF2 CoHeCloSi C2H4Cl2 2 2 2 2 2 2 2 RAE Systems Inc 9 8 NR 0 44 0 74 NR NR 8 6 1 4 NR 6 7 NR 0 57 0 54 NR NR 10 6 400 0 82 0 8 0 45 NR 11 7 1 0 0 39 0 55 0 82 0 57 0 9 0 12 0 12 0 35 0 34 2 0 C IE eV TWA
71. ion Approval UN number ADR and hazard label 2 General Requirements for Hazard Labeling a General specification for placards otrength and durability Placards must conform to the following A placard may be made of any plastic metal or other material capable of withstanding without deterioration or a substantial reduction in effectiveness a 30 day exposure to open weather conditions A placard made of tag board must be at least equal to what is commercially designated as white tag board Tag board must have a weight of at least 176 pounds 80 kg per ream of 24 x 36 inch 610 x 910 mm sheets waterproofing materials included In addition each placard made of tag board must be able to pass a 60 psi 414 kappa Mullen test Reflective or retro reflective materials may be used on a placard if the prescribed colors strength and durability are maintained b Visibility and display of the placards Each placard on a motor vehicle and each placard on a rail car must be clearly visible from the direction it faces except from the direction of another transport vehicle or rail car to which the motor vehicle or rail car is coupled This requirement may be met by the placards displayed on the freight containers or portable tanks loaded on a motor vehicle or rail car Each placard on a transport vehicle bulk packaging or freight container must Be securely attached Be located clear of appurtenances and devices such as ladder
72. ix 1 0 05 0 53 0 95 4 3 3 2 A reading of 100 would then correspond to 320 ppm of the total mixture comprised of 16 ppm benzene and 304 ppm hexane RAE Systems Inc 3775 First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 61 For spreadsheet to compute the correction factor and TLV of a mixture see the appendix at the end of the CF table TLVs and Alarm Limits for Mixtures The correction factor for mixtures can be used to set alarm limits for mixtures To do this one first needs to calculate the exposure limit for the mixture The Threshold Limit Value TLV often defines exposure limits The TLV for the mixture 15 calculated in a manner similar to the CF calculation TLV mix 1 Xi TLV X2 TLV2 X3 TLV3 Xi TLVi In the above example the 8 h TLV for benzene is 0 5 ppm and for n hexane 50 ppm Therefore the TLV of the mixture is TLVmix 1 0 05 0 5 0 95 50 8 4 ppm corresponding to 8 0 ppm hexane and 0 4 ppm benzene For an instrument calibrated on isobutylene the reading corrsponding to the TLV 1s Alarm Reading TLVmix CFmix 8 4 3 2 2 6 ppm A common practice 15 to set the lower alarm limit to half the TLV and the higher limit to the TLV Thus one would set the alarms to 1 3 and 2 6 ppm respectively Calibration
73. line has the capability to treat a depth of 8 10 and width of 6 8 on each side depending upon soil type and moisture conditions 2 Drip Emitter Checking Always check irrigation lines for leaks that can create flooding or reduced fumigant movement prior to application Leaks in the irrigation system can lead to a misapplication of the product and thus reduce the effectiveness of DOMINUS in the target area To avoid this you must first test the irrigation system This action ensures there are no leaks and that all the irrigation valves of the treated area are able to deliver the product to the treated area at the desired rate of application with equal distribution Prior to beginning DOMINUS injection ensure that all leaks and or breaks in the drip lines and all possible clogging of drip emitters have been repaired Routine inspection of the drip lines and emitters is necessary throughout the injection time At all times workers must wear appropriate PPE and perform repair tasks with personal safety first It is possible that even simple repairs may require the need to halt the application until the repair can be sufficiently resolved 3 Irrigation System Compatibility with DOMINUS Product DOMINUS soil fumigant is applied in a diluted concentration with irrigation water As such use of materials constructed with polyvinyl chloride PVC polyethylene PE and or metal pipe can be used in the irrigation system Do not apply DOMINU
74. ll other workers with appropriate information regarding the use of DOMINUS products and ensuring that all handlers follow required use directions and safety measures DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 7 DOMINUS Contact Information DOMINUS soil fumigant is a highly and acutely hazardous material All uses of this fumigant are covered under appropriate local and or regional Worker Protection Standards WPS and must be conducted in accordance with all Governmental Regional and or State requirements It is not a restricted use pesticide however it must only be used by supervising applicators licensed by the Government Regulatory Agencies and or State s and trained by ISAGRO USA the proper handling worker protection and application of DOMINUS soil fumigant and handlers under their direct supervision Before using read the entire label and follow all use directions and precautions All persons working with this fumigant must be knowledgeable about its hazards and trained in the use of required air purifying respirator equipment and detector devices as applicable emergency procedures and proper use of the fumigant Contact your ISAGRO USA representative for details on obtaining approved company training materials and qualification for use of DOMINUS ISAGRO USA Main Office Number 919 321 5200 ISAGRO Representative Eastern USA 863 840 4600 ISAGRO Representative Weste
75. loam loam and silt loam soils Appearance Field capacity determined Dry soil aggregations break away easily no staining on fingers clods crumble with applied pressure 32 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA d Clay clay loam and silt clay loam soils Appearance Field capacity determined Dry soil aggregations separate easily clods are nou hard to crumble with applied pressure 3 Soil Temperature DOMINUS application is best recommended at soil temperature between gt 60 F and lt 90 F at a depth of 8 inches Chemical and physical characteristics of DOMINUS application to soils outside the parameters will potentially limit proper dissipation of DOMINUS in the soil profile and or targeted area 4 DOMINUS Compatibility With Other Plant Protection Products Care should be taken with DOMINUS and compatibility with other plant protection or fertilizer products having a high level of ammonia The mixing of DOMINUS with other fumigant or fertilizer products should first be determined to be compatible in the lab prior to mixing or use in the field Consult your local ISAGRO USA representative for information and or guidance on product compatibilities Combining DOMINUS with products of unknown compatibility could lead to human exposure or unforeseen environmental issues as well as potential problems of crop injury phytotoxicity for the succeedin
76. lowers or bulbs DOMINUS is patented and licensed exclusively to ISAGRO USA Corporation and its parent company Isagro SpA Testing since 2009 has demonstrated equal or superior control of soil pests and diseases compared to other registered fumigants As a pre plant soil treatment DOMINUS offers many value added benefits including US EPA Classification and registration as a biopesticide Application pending approval for use in organic production from National Organic Program NOP and Organic Materials Review Institute OMHI Multiple applications allowed per year No restrictions on maximum applied acres per day Application via conventional equipment broadcast shank raised bed shank drip or probe auger deep injection methods Rapid breakdown in sun and UV light 1 day When used as directed this product does not impact groundwater quality Does not leave a detectable residue of Allyl Isothiocyanate in the soil and is not transmitted to plants or food products 2 Composition DOMINUS contains the active ingredient Allyl Isothiocyanate DOMINUS is a liquid at room temperature and formulated with 9696 active and 4 inert ingredients In DOMINUS the active ingredient has a detectable odor which also serves as its own warning odorant to aid in the detection of Allyl Isothiocyanate vapors DOMINUS is currently registered in the USA for pre plant soil application and as an alternative to methyl bromide in soil fumiga
77. ly call 911 Skin Irritation Corrosive Causes severe skin burns and eye damage Do not breathe mists into mouth Avoid contact with skin and eyes Wear protective gloves and clothing eye and face protection when handling product Always wash hands immediately after handling product containers or working on equipment used for application If on skin immediately remove all contaminated clothing and wash affected area with plenty of water for 15 20 minutes and or until advised to stop by Poison Control Center advisor Eye irritation Corrosive Causes serious eye damage Wear eye and face protection If in eyes Rinse slowly and gently with water for 15 20 minutes If present remove contact lenses after the first 5 minutes and continue rinsing for the remainder of required rinse time Immediately call a poison center or doctor for further instructions as necessary for treatment DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 9 m m 2 Em Al Em Em 2 Environmental Hazards Environmental Fate Comparison Background AITC is similar in structure to methyl isothiocyanate MITC the active substance released from the soil fumigants metam sodium and metam potassium In comparison to MITC AITC has the following properties Volatility AITC is less volatile than MITC due to a higher boiling point and much lower vapor pressure In fact AITC has a vapor pressure
78. n and Commercial Use Must be knowledgeable in the handling and use of soil fumigants and in particular the DOMINUS application method s Must have participated in ISAGRO USA provided training course theoretical and practical training Must have read and understood required reading materials Must successfully exhibit appropriate knowledge of the product its application handling and requirements for protection of human health and the environment Renewal of ISAGRO USA Qualification Annual participation in the ISAGRO USA qualification process is required Distributors who have been trained by ISAGRO USA representative and are proficient in all aspects of the ISAGRO Training program can be qualified to serve as trainers once approved by ISAGRO USA Applicator Requirements and Responsibilities All participants in the ISAGRO USA training program whether provided by ISAGRO personnel or Designated Distributor Trainers must understand and comply with all DOMINUS label requirements A person trained and knowledgeable on the product s technical and safe handling must be present at the fumigation site during the application and should be in the line of sight of the applicator 6 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 The on site applicator supervising the soil fumigation is responsible for all safety measures listed on product labels and required by applicable l
79. ng call 9 1 1 immediately or an ambulance Overexposure may produce symptoms of vertigo delirium and mental disturbances Other symptoms may include coughing nausea and vomiting The hazard characteristics of DOMINUS are detailed on the product label and should be understood by all persons responsible for the handling and or application of this product Hazards to Humans and Domestic Animals Signal Words Danger Corrosive Causes eye damage with possible irreversible impact without proper treatment This product is considered to be a lachrymator Corrosive to the skin Causes skin irritation with potential for chemical burns May be harmful or fatal if swallowed Harmful if it is absorbed through the skin Do not get in eyes on skin or on clothing Do not breath product vapors Irritation to throat and mouth can occur with inhalation of vapors Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals SPECIAL NOTE If this product is tank mixed with chloropicrin or other approved fumigants the applied product must be considered a poisonous liquid or vapor especially when mixed with chloropicrin or other toxic fumigants When DOMINUS is mixed with another fumigant the more stringent buffer zones and mitigation measures must be used Inhalation of vapors may be fatal Chloropicrin is readily identified by smell Exposure to very low concentrations of vapor will cause irritation of eyes
80. nit calibrated to read 1sobutylene equivalents the reading 15 100 ppm with a 10 6 eV lamp The gas measured 15 m xylene CF 0 43 After downloading this factor the unit should read about 43 ppm when exposed to the same gas and thus read directly in m xylene values Example 3 The desired gas to measure 15 ethylene dichloride EDC The CF is 0 6 with an 11 7 eV lamp During calibration with 100 ppm isobutylene insert 0 6 times 100 or 60 at the prompt for the calibration gas concentration The unit then reads directly in EDC values Conversion to mg m To convert from ppm to mg m use the following formula Conc mg m Conc ppmv x mol wt g mole molar gas volume L For air at 25 C 77 F the molar gas volume 15 24 4 L mole and the formula reduces to Conc mg m Conc ppmv x mol wt g mole x 0 041 For example if the instrument is calibrated with a gas standard in ppmv such as 100 ppm isobutylene and the user wants the display to read in mg m of hexane whose m w 1s 86 and 15 4 3 the overall correction factor would be 4 3 x 86 x 0 041 equals 15 2 Correction Factors for Mixtures The correction factor for a mixture 1s calculated from the sum of the mole fractions of each component divided by their respective correction factors CF1 1 X2 CF2 X3 CF3 Xi CF1 Thus for example a vapor phase mixture of 5 benzene and 95 n hexane would have a CFmix of CFm
81. nomethyl ether 2 2 Methoxyethoxy ethanol Diethylene glycol monomethyl ether bis 2 Methoxyethyl ether Diethylene glycol dimethyl ether Diglyme Methyl 2 propenoate Acrylic acid methyl ester Aminomethane MAK 2 Heptanone Methyl pentyl ketone Bromomethane MTBE tert Butyl methyl ether see 2 Methoxyethanol Chloromethane MDI Mondur M CAS No 74 88 4 123 92 2 75 28 5 78 83 1 115 11 7 106 63 8 26675 46 7 540 84 1 64741 66 8 64742 48 9 64742 48 9 64742 48 9 64742 47 8 78 78 4 78 59 41 78 79 5 67 63 0 108 21 4 108 20 3 8008 20 6 64741 42 0 8008 20 6 64747 77 1 8008 20 6 64741 77 1 8008 20 6 64741 77 1 8008 20 6 64742 47 8 5989 27 5 8008 20 6 108 31 6 108 67 8 74 82 8 67 56 1 109 86 4 111 77 3 111 96 6 79 20 9 96 33 3 74 89 5 110 43 0 74 83 9 1634 04 4 74 87 3 107 87 2 Technical Note TN 106 Revised 08 2010 Formula 9 8 C 10 6 C 11 7 CIE eV CHsl 0 21 022 0 26 9 54 C7H1402 10 1 2 1 1 0 lt 10 C4H40 100 1 2 10 57 C4H4o00 19 38 1 5 10 02 C4Hg 1 00 1 00 1 00 9 24 7 12 02 15 0 60 NR NR 48 117 8 18 1 2 9 86 m w 121 17 08 m w 148 08 m w 156 09 05 027 m w 163 09 05 028 m w 191 07 04 C5H42 8 2 3 9 07 Cs5Hg 0 69 0 63 0 60 8 85 C3HsO 500 60 2 7 10 12 C5H1002 2 6 9 99 0 8 9 20 m w 115 10 04 m w 167 06 05 m w 165 06 03 m w 145
82. nsulting the label This formula utilizes the broadcast rate even though you may be making a bed treatment because it only calculates the portion of the area you are treating 38 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USK Determine the flow meter that is being used on your applicator Find its capacity in gallons per minute for the formulation you are using If your application is a solid tarp application your net broadcast rate should be verified by measuring the distance treated by each container The actual amount applied should correspond closely to the broadcast rate you selected from the label If your actual rate varies unacceptably re time your speed and verify your calculations Also consult your distributor to verify the correct output of the flow meter If your application is a bed fumigation where you are treating only a portion of the soil surface you should calculate your net usage Divide the bed width by the row spacing measurement from the center of one row to the center of the adjoining row to calculate the portion of the soil surface you are treating o The percentage of the soil surface treated times the broadcast rate calculates the net usage per acre As above you should verify your actual application rate by measuring the distance treated by each cylinder The difference in product density may require a change in flow meter type other
83. nts about when tarps are allowed to be perforated and or removed These requirements also affect the entry restricted period as well as appropriate PPE necessary to prevent any potential for exposure from the chemical treatment DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 29 i TN N y b N p v 1 y 1 30 3 FACTORS FUMIGATION Under all conditions the approved label recommendations must be followed The guidelines in this document are provided as supplementary advice for users If there is any discrepancy between the label language and these guidelines the label instructions take precedence Soil Evaluation 1 Soil Type Soil must be properly prepared and at the surface generally be free of large clods The area to be fumigated must be tilled to a depth of at least 5 inches below the soil air interface The type of soil can be determined with use of the soil triangle below 100 100 100 90 80 70 60 50 40 30 20 10 The soil texture triangle is used to classify the texture class of a soil The sides of the soil texture triangle are scaled for the percentages of sand silt and clay Clay percentages are read from left to right across the triangle Silt is read from the upper right to lower left Sand from lower right towards the upper left portion of the triangle The boun
84. ociated Files Instructions 149 pdf MSDS 149 03E MSDS pdf Data Sheet Methyl Methacrylate 149 pdf Back to Search Results Content Copyright 2002 2013 Nextteg LLC All Rights Reserved DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 ENTRY RAE USER MANUAL Entry RAE User Notice 1 Physical Description Display Operation programmer keys Charge status Visual alarm Gas plate Buzzer Gas inlet with external filter Charging contacts Charging cradle 10 Power jack 11 RS 232 port Bottom of monitor 11 2 Display and Legend 1 PID lamp alarm 2 2 Alarm conditions 1 2 4 O 3 Pump on 4 Pump off 5 Time ALARM EH 6 Date Day Month Year 7 Hox OW WA STH SCIES 8 9 Apply calibration gas Battery charge status H H H Password protected 888 9898 7 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 as om s mi 988888 53 54 i lm _ _ im MI RE ii 3 Turning the Monitor ON OFF To turn the monitor ON 1 Press the button for 1 second To turn the monitor OFF Press the button for 5 seconds The display will count down from 5 to 1 5 seconds Release when Unit Off appears on the display Return the Entry RAE to the dry indoor storag
85. ovides an increased margin of safety over all other film types as well as potentially increasing product performance against target pests Note that the potential presence of a higher concentration of product under the tarp when using TIF may impact the aeration time especially under conditions where the soil may be cold lt 60 F or if soils are wet and or saturated in addition when ambient air temperatures are low especially early or late season these conditions may require longer than normal planting intervals Consult an ISAGRO USA representative as needed for further recommendations prior to planting with any questions regarding use of plastic films aeration and planting intervals 2 Good Sealing of the Tarp Before beginning and after any fumigant application ensuring that the tarps are suitable barriers for fumigant emissions means No holes are present No tears are present DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USK A tight fit on the raised bed surface with ends and edges sufficiently buried with soil And in the case of broadcast applications that the glue is sufficient to hold the seams together between two tarp edges In the event of tarp holes tears needing repair first wear all PPE to inspect and repair the area affected Inspect tarps following application and routinely during the 5 day REP for any holes tears and repair with tape
86. r distributors and applicators using DOMINUS formulations ISAGRO USA will conduct and support annual training for distributors and applicators and will make all training materials available for use by DOMINUS approved distributors and applicators for use in training site specific personnel as required 3 Product Stewardship and Compliance ISAGRO USA is committed to ensuring the safe handling distribution and use of DOMINUS products ISAGRO USA will work with distributors applicators growers and state regulatory officials to ensure compliance with all use restrictions and regulatory requirements By participating in the DOMINUS Soil Fumigant Stewardship and Training Program distributors and applicators make their own commitment to comply with all label language including use restrictions and safety requirements In addition to providing training materials classroom instruction and in field guidance and support ISAGRO USA intends to fully investigate and report incidents involving misuse or non compliance Distributors and applicators who do not comply with all product use requirements will not be allowed to continue to distribute or use DOMINUS formulations All incidents occurring during the application process or handling or transportation of DOMINUS product must be reported to ISAGRO USA by calling the ISAGRO Representative for Eastern Atlantic territories at 863 840 460 and in Western Pacific territories at 559 903 4653 An Incident
87. ram Stewardship and Technical Training Manual July 2014 Ethylbenzene Ethyl caprylate Ethylenediamine Ethylene glycol Ethylene glycol Acrylate Ethylene glycol dimethyl ether Ethylene glycol monobutyl ether acetate Ethylene glycol monothio Ethylene oxide Ethyl ether Ethyl 3 ethoxypropionate Ethyl formate Ethylhexyl 2 Ethylhexanol Ethylidenenorbornene Ethyl S lactate see also DS 108F Ethyl mercaptan Ethyl sulfide Formaldehyde Formamide Formic acid Furfural Furfuryl alcohol Gasoline 1 Gasoline 2 92 octane Glutaraldehyde Glycidyl methacrylate Halothane Synonym Abbreviation Ethyl octanoate 1 2 Ethanediamine 1 2 Diaminoethane 1 2 Ethanediol 2 hydroxyethyl Acrylate 1 2 Dimethoxyethane Monoglyme 2 Butoxyethyl acetate mercapto 2 ethanol Oxirane Epoxyethane Diethyl ether EEP Acrylic acid 2 ethylhexyl ester 2 Ethyl 1 hexanol CAS No 100 41 4 106 32 1 107 15 3 107 21 1 818 61 1 110 71 4 112 07 2 60 24 2 75 21 8 60 29 7 763 69 9 109 94 4 103 11 7 104 76 7 5 Ethylidene bicyclo 2 2 1 hept 2 16219 75 3 ene Ethyl lactate Ethyl S hydroxypropionate Ethanethiol Diethyl sulfide Formalin 2 Furaldehyde 1 5 Pentanedial Glutaric dialdehyde 2 3 methacrylate 2 Bromo 2 chloro 1 1 1 trifluoroethane HCFC 22 see Chlorodifluoromethane HCFC 123 see 2
88. razomethane MIAK 5 Methyl 2 hexanone MIBK 4 Methyl 2 pentanone CH3NCO CH3NCS Methanethiol HFE 7100DL Dytek A amine 2 Methyl pentamethylenediamine MPK 2 Pentanone NMP N Methylpyrrolidone 1 Methyl 2 pyrrolidinone 1 Methyl 2 pyrrolidone Methyl 2 hydroxybenzoate 2 Propenylbenzene DMS Dimethyl sulfide Stoddard Solvent Varsol 1 White Spirits Monoethanolamine see Ethanolamine Mustard Naphtha see VM amp P Naptha Naphthalene Nickel carbonyl in CO Nicotine Nitric oxide Nitrobenzene Nitroethane Nitrogen dioxide Nitrogen trifluoride Nitromethane Nitropropane 2 Nonane Norpar 12 Norpar 13 Octamethylcyclotetrasiloxane Octamethyltrisiloxane Octane n Octene 1 Pentane Peracetic acid Peracetic Acetic acid mix Perchloroethene PGME Yu a HD Bis 2 chloroethyl sulfide Mothballs Nickel tetracarbonyl n Paraffins mostly C4o C43 n Paraffins mostly C43 C44 Peroxyacetic acid Acetyl hydroperoxide Peroxyacetic acid Acetyl hydroperoxide PCE Perchloroethylene Tetrachloroethylene CAS No 75 09 2 115 10 6 78 93 3 60 34 4 110 12 3 108 10 1 624 83 9 551 61 6 74 93 1 80 62 6 163702 08 7 163702 07 6 15520 10 2 107 87 9 872 50 4 119 36 8 98 93 09 75 18 3 8020 83 5 8052 41 3 68551 17 7 8052 41 3 505 60 2 39472 40 7 68157 62 0 91 20 3 13463 39 3 54 11 5 10102 43 9 98 95 3 79 24 3 10102 44 0 7783 54 2 75
89. re conditions and therefore all filters to be used during sampling should also be in place during calibration Using a water trap hydrophobic filter greatly reduces the chances of drawing water aerosols or dirt particles into the instrument Regular filter replacements are recommended because dirty filters can adsorb VOCs and cause slower response time and shifts in calibration Instrument Design High boiling heavy or very reactive compounds can be lost by reaction or adsorption onto materials in the gas sample train such as filters pumps and other sensors Multi gas meters including EntryRAE MultiRAE and AreaRAE have the pump and other sensors upstream of the PID and are prone to these losses Compounds possibly affected by such losses are shown in green the table may give slow response or in extreme cases no response at all In many cases the multi gas meters can still give a rough indication of the relative concentration without giving an accurate gs 5 z Lu Technical Note TN 106 Revised 08 2010 quantitative reading The ppbRAE and MiniRAE series instruments have inert sample trains and therefore do not exhibit significant loss nevertheless response may be slow for the very heavy compounds and additional sampling time up to a minute or more should be allowed to get a stable reading Table Abbreviations CF Correction
90. re facilities and school age child care centers or licensed assisted living facilities licensed by state or local governments that will be occupied during the 24 hour buffer zone period Never fumigate alone A minimum of two trained persons must be present during handling and application of soil fumigants Additional instructions must be made available to handlers in the mechanical operation of the tractor drip application equipment and how to safely work with the operator while fumigating Always handle this product in the open with all handlers positioned upwind from the container and or where there is adequate ventilation When fumigating it is required that 20 liters 5 gallons of water be carried on the tractor or near the drip application equipment and readily available for rinsing and cleaning purposes An additional 20 liters of water must be available in the service truck This water must be potable and in containers marked Decontamination water not to be used for drinking For broadcast applications keep all pets livestock and other domestic animals out of the treated areas until tarps have been removed For raised bed applications keep all pets livestock and other domestic animals out of the treated areas for 5 days Most raised bed applications will not result in tarp removal Do not allow entry by unprotected workers into the fumigated area until the Biofumigant Treated Area signs are removed and the ent
91. ring injection step DOMINUS Rate Calculator form Excel sheet is included as part of this document to assist you in calculating the requirements for a DOMINUS application 3 DOMINUS Product Injection Always wear label required PPE during handling and when connecting the DOMINUS container to the drip injection equipment or system a Equipment leaks inspection Prior to starting DOMINUS drip injection always check if leaks are present and that the equipment is in optimal working order Begin with pressurizing the system with clean water and inspecting all areas where a connection is made i e injection point cylinder connection etc Use a solution of soapy water to verify that all connections are secure and without leaks b Beginning of injection A supervising applicator must always be on site during the injection Refer to the product label for use and product handling Prior to application the ISAGRO USA drip injection calculator should be used to verify that all product and water delivery calculations are accurate and meet the physical parameters of the treated site for amount of water to deliver as per soil type distribution and ppm concentration in the irrigation water c Ending of injection After the injection disconnect all application equipment wearing all PPE defined on the product label and rec ommended by ISAGRO USA Rinse the irrigation system using the volume calculated by the Rate Calculator d Prior
92. rn USA 559 903 4653 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 DOMINUS TRAINING MANUAL TIWANVIN 9NINIVH L USA CHAPTER 1 DOMINUS PRODUCT DESCRIPTION DOMINUS Product Overview 1 Hazard Characteristics OSHA Hazard Communication Standard Classification 29 CFR 1910 1200 Signal Word Danger Pictograms gt a Hazard Statements and Categories e Acute Oral Toxicity Harmful if swallowed Wash hands thoroughly after handling Do not eat drink or smoke when using this product If swallowed call a poison center if you feel unwell Rinse mouth Acute Dermal Toxicity Toxic when in contact with skin Wear protective gloves and clothing If on skin wash with plenty of water Call a poison center or doctor if you feel unwell Immediately remove all contaminated clothing and wash separately from normal laundry before reuse If clothes are contaminated beyond use follow all label instructions for proper disposal Acute Inhalation Toxicity Fatal if inhaled Do not breathe mist vapor or spray Use product only outdoors or in a well ventilated greenhouse or glasshouse If product is inhaled move away from the source and upwind If a person needs assistance wear a respirator and remove person to fresh air and upwind from source of contact Immediately call a poison control center or doctor If a person is uncon scious and or not breathing immediate
93. roducts b Quick Links la E I TELA BETTER TECHNOLOGY GETTER QUALITY BETTER VALLE Products How to Purchase Gas Detection T Respiratory Protection First Response Hazmat Testing Water and Soil Analysis Gas Detection Detector Tubes Methyl methacrylate Allyl isothiocyanate Tube Data Tube Number 149 Gastec Tube Methyl methacrylate Chemical Allyl isothiocyanate Range 5 200 Shelf Life years 2 Notes Gastec Detector Tubes offer advanced technology that adds up to more accurate and reliable analysis with lower standard deviation With detection limits for many chemicals lower than competitor limits Gastec tubes detect trace levels of contaminants that competitors cannot Additionally Gastec s higher maximum detection limits can provide a wider range of contaminant measurement DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA 51 i Legal Notice amp Privacy Policy Offering some of the broadest operating temperature ranges available Gastec Detector Tubes can be used in virtually any environment from 32 F to 104 Each tube contains a reagent that is highly sensitive to the target substance and quickly produces a distinct color change when the chemical is present While some competitor tubes display semi quantitative results Gastec Detector T
94. roethane 1 1 2 Trimethylamine Trimethylbenzene 1 3 5 see Mesitylene TCE Trichoroethylene Methyltrichlorosilane CFC 113 TEA TEB Boric acid triethyl ester Ethyl phosphate TMB Boric acid trimethyl ester Boron methoxide Methyl phosphate Trimethyl borate Trimethyl phosphate Trimethyl phosphite Methyl phosphite Turpentine Pinenes 8596 other diisoprenes Undecane Varsol see Mineral Spirits Vinyl actetate Vinyl bromide Bromoethylene Vinyl chloride Chloroethylene VCM Butadiene dimer 4 Ethenylcyclohexene Vinylidene chloride see 1 1 Dichloroethene Vinyl 2 pyrrolidinone 1 NVP N vinylpyrrolidone 1 ethenyl 2 pyrrolidinone Viscor 120B see Mineral Spirits Viscor 120B Calibration Fluid V M amp P Naphtha Vinyl 1 cyclohexene 4 maker s amp painter s naptha Xylene m 1 3 Dimethylbenzene Xylene o 1 2 Dimethylbenzene Xylene p 1 4 Dimethylbenzene None Undetectable Compounds indicated in green can be detected using MiniRAE 2000 or ppbRAE with slow response but may be lost by CAS No TDI 4 Methyl 1 3 phenylene 2 4 584 84 9 120 82 1 71 55 6 79 00 5 79 01 6 75 79 6 76 13 1 121 44 8 150 46 9 78 40 0 430 66 0 75 50 3 108 67 8 121 43 7 512 56 1 121 45 9 8006 64 2 1120 21 4 108 05 4 593 60 2 75 01 4 100 40 3 88 12 0 Ligroin Solvent naphtha Varnish 64742 89 8 108 38 3 95 47 6 106 42 3 Formula CoHeN202 CoHsCla C2Hs3Cls CoH3Cls Co
95. ry restricted period is over Applications are prohibited after sunset and before sunrise as wind speed conditions may be unfavorable The uses of all films defined as low density polyethylene LDPE High Density polyethylene HDPE Virtually Impermeable Film VIF and Totally Impermeable Tarp TIF are allowed with DOMINUS under approved application methods Check any local label restrictions and or with your local ISAGRO USA representative for additional use recommendations of all tarp types Personal Protective Equipment PPE for DOMINUS Applicators shovelers tarp cutters and any other handler must wear for their own safety all the personal protective equipment PPE prescribed and mandated on the approved label per task 1 Portable Gas Detection GAS DETECTION DURING HANDLING AND OR USE OF AITC PRODUCTS Note ISAGRO requires that at least one type of gas detection device with sufficiently low detection limits be readily available on site when DOMINUS is being handled applied or where there is the potential for liquid contact The following devices may be used to detect AITC DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 21 DOMINUS 22 Each GASTEC Tube is intended for a single use to determine the concentration of AITC in the air space under the tarp or immediately above the tarp or soil Follow all manufacturer instructions to properly handle the Gastec tubes Although the
96. s pipes doors and tarpaulins So far as practicable be located so that dirt or water is not directed to it from the wheels of the transport vehicle Be located away from any markings such as advertising that could substantially reduce its effectiveness and in any case at least 3 inches 7 60 cm away from such markings Have the words or identification number when authorized printed on it displayed horizontally reading from left to right Be maintained by the carrier in a condition so that the format legibility color and visibility of the placard will not be substantially reduced due to damage deterioration or clogging by dirt or other matter Be affixed to a background of contrasting color or must have a dotted or solid line outer border which contrasts with the background color DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 17 a CHAPTER 2 DOMINUS USER SAFETY INFORMATION Hazard ldentification 1 Hazards to Humans and Domestic Animals DOMINUS Formulated Product Vapors can cause irritation Splashes may cause severe irritation with the potential to create permanent eye damage Prolonged contact can cause severe irritation or related adverse skin effects Ingestion may damage the mouth throat and or gastrointestinal tract Inhalation of vapors can irritate the respiratory tract If a person is not breathi
97. significant Some common matrix components such as methane and water vapor can affect the VOC signal PIDs are RAE Systems Inc 3775 N First St San Jose CA 95134 1708 USA Phone 1 888 723 8823 Email raesales raesystems com Web Site www raesystems com DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 most commonly used for monitoring VOCS in air in which case the preferred calibration gas matrix is air For a MiniRAE methane methanol and water vapor reduce the response by about 20 when their concentration 1s 15 000 ppm and by about 4096 at 30 000 ppm Despite earlier reports of oxygen effects RAE PID responses with 10 6 eV lamps are independent of oxygen concentration and calibration gases in a pure nitrogen matrix can be used H and CO up to 5 volume also have no effect e Concentration Although RAE Systems PIDs have electronically linearized output it is best to calibrate in a concentration range close to the actual measurement range For example 100 ppm standard gas for anticipated vapors of 0 to 250 ppm and 500 ppm standard for expected concentrations of 250 to 1000 ppm The correction factors in this table were typically measured at 50 to 100 ppm and apply from the ppb range up to about 1000 ppm Above 1000 ppm the CF may vary and it is best to calibrate with the gas of interest near the concentration of interest f Filters Filters affect flow and pressu
98. similar to water at equal temperature Therefore as a result AITC has better retention in soil where it has maximum pesticide activity and minimal risk of human toxicity Mobility AITC has a lower water solubility and higher log P than MITC so it will be less prone to leaching Hydrolytic and Photostability AITC is likely to have similar photostability in air water and soil as MITC based on similar photolysis of the isothiocyanate group Studies support that AITC is likely to have greater hydrolytic stability in water most likely due to the potential of AITC to intra molecularly rearrange to form a pseudo six membered ring Soil Stability AITC is less stable in soil than MITC most likely because it is better retained in soil where it readily reacts with amines and thiols present in soil organic matter proteins in the target pest species and its own soil degradation products The non biological degradation of AITC in soil i e reactions of AITC with amines and thiols including soil organic matter might have positive effects such as enhancing soil organic matter and generating small molecules e g allylamine capable of supporting microbial growth and providing plant nutrients e g ammoniacal nitrogen as anticipated from small amines in soil in the ammonification pathway 3 Physical and Chemical Hazards Unusual Fire amp Explosion Hazards Do not inhale explosion and combustion gases which at high temperatures may contain toxic sub
99. ssure heart disease Psychological distress claustrophobia anxiety Other problems affecting the sealing of the mask i e beards or mustaches Other contraindications Having a beard is one of the biggest obstacles to adequate protection A beard even stubble can compromise the performance of respiratory protection due to interference with the proper seal of the respirator Wearers must be clean shaven prior to using the respirator Conditions for use of respirators Do not store in an area where potential contamination can occur When the respirator is not in use remove the cartridges and store in a Ziploc plastic bag or airtight container separate from the respirator Clean and disinfect the respirator after each use with alcohol wipes and or wash clean with soap and water To ensure the upkeep and maintenance of personal protective equipment maintain an equipment log to document the hours the cartridges are used Replace cartridges and filters after a total of 8 hours use Always replace cartridges and filters if they become damaged or if there is any odor detection when in use Understand the value of respiratory protection but also its limitations Operating instructions Discard and replace both filters at the same time Ensure that both filters are of the same type and class The effective life of a filter will vary depending on the level of contaminant work rate exposure time etc avoid heat exhaus
100. stances such as COx NOx and or SOx Burning produces heavy smoke Hazardous Decomposition Products May release irritating and toxic gases if ignited Hazardous Decomposition If temperatures reach the flash point for this product it may generate flammable gases on contact with elementary metals alkalies and alkaline earth alloys in powder or vapors and powerful reducing agents It may generate toxic gases on contact with oxidizing mineral acids and powerful oxidizing agents It may ignite on contact with oxidizing mineral acids and powerful oxidizing agents Hazardous Polymerization Does not occur DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 N DOMINUS Description 1 The Right Choice for Pre Plant Soil Treatment Producing a profitable crop always begins with the right choice DOMINUS Soil Fumigant from ISAGRO USA is a new choice for growers needing broad spectrum control of agronomically important pests and disease DOMINUS meets the standards for pre plant soil treatment efficacy and performance expected in today s marketplace DOMINUS soil fumigant Allyl Isothiocyanate controls soil borne pathogens weeds weed seeds nematodes and insects It has been developed for pre plant fumigation of soils used to grow a wide variety of crops such as strawberries fresh market tomatoes peppers melons ginger berries cucurbits and ornamentals such as turf and cut f
101. strial Hygiene versions only e Calibration card quality certificate packing list and warranty registration card OPTIONAL ACCESSORIES AutoRAE 2 Automated Test and Calibration Station e Multi unit charging station for up to five monitors e Refer to the Portables Pricing Guide for other accessories maintenance kits gas sensors and replacement parts ORDERING INFORMATION MODEL PGM 1800 e ndustrial Hygiene advanced and Safety basic configurations are available Industrial Hygiene configurations Advanced PID sensor 10 6 eV 0 1 to 2 000 ppm 0 1 ppm resolution Datalogging 9 8 eV or 10 6 eV lamp options Safety configurations 10 6 eV 1 to 1 000 ppm 1 ppm resolution PID No datalogging 10 6 eV lamp option only e Wireless wireless capable or non wireless versions are available e Refer to the Portables Pricing Guide for part numbers Toll Free 877 723 2878 DOMINUS Fumigation Management Program Stewardship and Technical Training Manual July 2014 75 76 DOMINUS Fumigation Management Program Stewardship Technical Training Manual July 2014 DOMINUS APPLICATION LOG 9071 NOILVOl 1ddV Please visit isagro usa com for an electronic version for completion and submission Direct link is hftpZ www isagro usa com downloads Ilsagro Dominus TrialLog r8 fillable pdf APPLICATION LOG 6 6 6 6
102. t volume or LEL Change the password Default 0000 Lets user know monitor is on If on beeps once per minute DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA Entry RAE Use For DOMINUS Application 1 During the Application Wear the appropriate PPE as described in the stewardship training manual To turn the monitor ON 1 Press the button for 1 second Alarms If the Entry RAE detects any level of gas an ALARM visual and hearing is produced When you heard this alarm it means that a problem has occurred Leaks or spillage in Irrigation system DOMINUS Kegs What to do in case of alarm 1 Ensure that all PPE is correctly worn 2 Stop the application 3 Fix the leaks or spillage 2 Once the application is completed To turn the monitor OFF 1 Press the button for 5 seconds 2 The display will count down from 5 to 1 5 seconds 3 Release the button when Unit Off appears on the display 4 Return the Entry RAE to the dry indoor storage area and put it in its charger 3 Data recovery Data logging occurs automatically for all enabled sensors at one minute intervals allowing five days of continuous data storage When the end of the storage memory is reached the monitor will automatically wrap around to the beginning of the log and overwrite the oldest stored data 4 Charging the Entry RAE The Li lon battery pack can be
103. t low concentrations where it is rapidly broken down by ultraviolet UV light 12 DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA 5 Product Compatibility Journal of the Food Hygienic Society Japan Vol 36 No 3 June 1995 Corrosive Effect of 3 000ppm AITC Vapor on Various Materials 1 to 20 days Material Compatibility Comments Appearance did not change with any formulation of DOMINUS No adsorption of DOMINUS into HDPE material causing a HDPE Y MM weight increase of the HDPE No change of hardness when HDPE is exposed to DOMINUS Appearance did not change with any formulation of DOMINUS PTEE Y No change in weight as a result of exposure to all formulations of DOMINUS No change of hardness when PTFE is exposed to DOMINUS Appearance did not change with any formulation of DOMINUS No change in weight as a result of exposure to all formulations of Mild steel DOMINUS opecimens exhibited no corrosion at extended time intervals No change in weight as a result of exposure to all formulations of DOMINUS Appearance did not change with any formulation of DOMINUS No change in weight as a result of exposure to all formulations of DOMINUS Tin Not effected at 3000 ppm vapor Literature states evidence of pitting and metal degradation while Copper Do Not Use no effect when exposed to vapor at 100ppm Not effected at 100ppm vapor slight effect Sur
104. than what has been used for conventional fumigants Flow meters are accurate only if operated between 15 and 85 of their capacity The DOMINUS Calibration form Excel sheet is included as part of this document to assist you in calculating the flow meter setting for a DOMINUS application Take care to use the proper capacity rating for each flow meter f the resulting calculation is less than 15 setting on the flow meter or flow meter is worn we recommend substituting a smaller or newer flow meter for the DOMINUS application Flow meters are typically calibrated with water and not to the specific gravity of fumigants A range of flow meters are available but will only allow up to 10096 of flow rate typically in the range of 0 33 to 4 16 GPM 1 25 to 15 60 LPM AITC formulations Prior to calibration of a flow meter first determine whether or not it is designed for water and the maximum 100 flow capacity of the meter The flow meter capacity flow rate is located on the face plate of the flow meter with a corresponding Float Code number Float codes for use with AITC formulations are of the series numbers 706 708 710 712 or 714 to the following chart to determine if a good fit exists to target flow percent volume per minute Note Application flow rate delivery is dependent upon tractor speed The tractor speed can be variable based on type and size of plastic broadcast vs raised bed and form
105. tion Based on its physical and chemical characteristics DOMINUS can be applied via agricultural drip irrigation systems and directly to soil via tractor mounted soil injection equipment Active Ingredient CAS Number Weight 96 4 57 06 7 96 30 Adjuvant Surfactant DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 11 MI m _ 3 Physical Chemical Properties DOMINUS Formulated Product 1 33 kPa 38 3 C 10 C 0 53 mPa sec 30 C20 45 MPa sec Summary Allyl Isothiocyanate Characteristics Liquid oily Does not mix readily with water note an adjuvant is required when mixing with water for drip applied injection Alkaline Toxic or noxious vapors gas Vapor pressure is 4 mm Hg Vapors are 3 4 times heavier than air Liquid is not significantly heavier than water Produces insignificant pressure The majority of pressure in the cylinders is what is added as a nitrogen pad 4 Mode of Action The chemical mechanism by which Allyl Isothiocyanate controls various soil borne pathogens and pests is considered to be multi site and classified as a general irritant and or desiccant against target disease and pests Allyl Isothiocyanate enters a gas phase once injected into the soil using either drip irrigation systems or using tractor mounted shank injection The gas then disperses through the soil pore spaces and finally into the atmosphere a
106. tion it is also recommended not to wear the mask over a period exceeding 30 minutes at one time especially if the wearer is in a greenhouse with temperatures exceeding 85 F and or high humidity 4 Eye Protection IF A HALF FACE MASK IN COMBINATION WITH SAFETY GLASSES IS WORN DURING THE APPLICATION RE ENTRY PROCESS DO NOT USE GOGGLES WITHOUT SIDE VENTILATION TO AVOID THE POTENTIAL OF TRAPPING VAPORS INSIDE CONTACT LENSES SHOULD NOT BE WORN DURING FUMIGATION AS THEY MAY TRAP VAPORS BETWEEN THE LENS AND THE EYE CAUSING IRRITATION AND OR DAMAGE TO AVOID POTENTIAL IRRITATION TO EYES AND THROAT USE OF A FULL FACE RESPIRATOR IS RECOMMENDED DURING PRODUCT HANDLING AND WHERE THE POTENTIAL FOR LIQUID CONTACT IS POSSIBLE Note ISAGRO USA recommends on site availability of a portable eye wash station with saline solution to be used in case of eye exposure Eyewash should be used within the first 60 seconds of exposure to maximize its benefit DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 2b DOMINUS 5 Emergency Response TO ENSURE QUICK ACTION IN CASE OF EMERGENCY THE APPLICATOR IN CHARGE SHOULD HAVE A CELL PHONE WITH FULLY CHARGED BATTERY EMERGENCY NUMBERS FOR FIRST RESPONDERS AND A LOCAL AMBULANCE SERVICE SHOULD BE STORED IN THE CELL PHONE MEMORY CHEMTREC for chemical spills and accidents FOR CHEMICAL EMERGE CY CALL 800 424 9300
107. tion Management Program Stewardship and Training Manual July 2014 41 42 In line site glasses on flow divider Output for single shank line In line site glasses on flow divider 4 Fumigant Rig Operation at the Beginning of a Row In order to achieve a sufficient delivery at the start of the row give the driver the following instructions 1 Begin by lowering the bed press and driving forward until the chisels are covered with soil and or until the chisels are at the point where the row will start and stop the tractor 2 Turn on the fumigant flow and confirm presence in all site glasses flow meter and divider manifold 3 Wait to start the forward progress of the tractor typically 3 5 seconds until the flow meter percent is steady and the manifold pressure gauge begins to rise from zero As the tractor gains speed full flow will be achieved and full delivery will be achieved at the start of the row Normal operation of the fumigant application system will generate approximately the same pressure on the manifold pressure gauge each pass Should this pressure rise above its normal reading the green red or yellow tubes should be checked to assure that all are open and delivering fumigant DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 N 5 Prior to Leaving the Injection Site Once application has been done the site must be secured to ensure that no
108. tion against accidental exposure or contamination DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USK Buffer zones must be on the property where the treated area is located and must not include property that is not under the control of the supervising applicator unless written permission is obtained prior to fumigation This includes the signature from the responsible party ies from all property ies that will be included or partially included in the buffer zone Buffer zones shall not extend onto public roads or areas unless specifically allowed or onto any other land for which written consent is not attainable The supervising applicator must use appropriate means to manage and maintain the buffer zone such as posting Biofumigant warning signs around the perimeter of the buffer zone at potential points of entry using trained workers to patrol the buffer zone or other equivalent means Biofumigant warning signs must be used and must be posted from the start of the application until 24 hours after the end of the application The signs must include the same warning symbol and statements required for notification warning signs with the exception that signs will indicate Biofumigant Treated Area at the top of the sign and will delete the statement areas under fumigation Biofumigant Treated Area signs must be removed within 3 days of the end of the buffer zone period Note The
109. tions and maintenance see Appendix A DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USA 2 Skin Protection a Body protection LOOSE FITTING or WELL VENTILATED LONG SLEEVED SHIRT AND LONG PANTS ARE REQUIRED DURING APPLICATION RE ENTRY PROCESS AND ALL OPERATIONS WHERE EXPOSURE TO DOMINUS LIQUID CONCENTRATE IS POSSIBLE DOMINUS is heavier than air it can be trapped inside clothing The wearing of 4 protective coveralls will decrease this potential route of exposure 4 Note ISAGRO USA requires the use of protective Tyvek type coveralls or good quality M cotton coveralls capable of covering the entire body and head The use of a chemical apron is also recommended with activities that may enhance the potential for liquid contact Ensure that protective suits are the right size for all applicators In the event of liquid contact with DOMINUSS coveralls should be removed and replaced Properly dispose of any clothing that is heavily soiled during fumigant handling and or applications Do not wash with other clothes Wash all clothing in hot water using industrial soaps capable of cleaning solvents and or oils b Hand Protection GLOVES WITH CHEMICAL PROTECTION MADE of NITRILE NEOPRENE LATEX or RUBBER ARE REQUIRED DURING HANDLING APPLICATION EARLY ENTRY TARP CUTTING AND ALL OPERATIONS WHERE EXPOSURE TO DOMINUS LIQUID CONCENTRATE IS POSSIBLE T
110. to leaving the injection site Once the application is complete the site must be secured to ensure that no unauthorized people will enter the buffer zone area and into the treated area Not respecting any or all of these requirements will increase the potential of personal exposure to humans and or the environment with DOMINUS soil fumigant Before leaving the site ensure that Biofumigant Warning placards see below are in place and Completed with all the required information o Date of application o Date of Re Entry Period 5 days or 120 hrs from the end of the application o Contact name and phone number of the supervising applicator o Additional Contact information phone number if required by local regulatory agencies DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 USK Posted at all entrances or access points to the treated area as necessary to inform and prevent access DANGER PELIGRO PESTICIDES PESTICIDAS Areas Under Fumigation 5 Biofumigant In Use D 0 S Allyl Isothiocyanate Date Ti Restricted period is over Supervising Applicator Contact Address Telephone EMERGENCY TELEPHONE NUMBERS Day Night FOR SPILLS OR TRANSPORTATION EMERGENCIES 800 424 9300 Chemtrec DO NOT ENTER NO ENTHE DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 47 48 FT2 ACRE 43560 ML
111. tylene equivalents Manually multiply the reading by the correction factor CF to obtain the concentration of the gas being measured 2 Calibrate the unit with isobutylene in the usual fashion to read in isobutylene equivalents Call up the correction factor from the instrument memory or download it from a personal computer and then call it up The monitor will then read directly in units of the gas of interest 3 Calibrate the unit with isobutylene but input an equivalent corrected span gas concentration when prompted for this value The unit will then read directly in units of the gas of interest The term ionization energy is more scientifically correct and replaces the old term ionization potential High boiling heavy compounds may not vaporize enough to give a response even when their ionization energies are below the lamp photon energy Some inorganic compounds like H20 and NO give weak response even when their ionization energies are well below the lamp photon energy Example 1 With the unit calibrated to read 1sobutylene equivalents the reading 15 10 ppm with a 10 6 eV lamp The gas being measured 15 butyl acetate which has a correction factor of 2 6 Multiplying 10 by 2 6 gives an adjusted butyl acetate value of 26 ppm Similarly if the gas being measured were trichloroethylene CF 0 54 the adjusted value with a 10 ppm reading would be 5 4 ppm e w TEM 4 Example 2 With the u
112. ubes provide exact quantitative measurements The pre calibrated direct read detector tubes offer distinct lines of demarcation for easier viewing and require no interpretation dual scales or calor charts To expedite analysis many Gastec tubes require only 1 pump stroke Alternatively competitors can require up 20 pump strokes to measure the same substance You can rely on Gastec quality No other manufacturer has more detector tubes certified by the Safety Equipment Institute SEI than Gastec To ensure the highest level of quality Gastec products are manufactured in 150 9001 certified facilities Gastec Detector Tubes and Gas Sampling Pumps are designed manufactured and calibrated to work together to produce accurate readings Each box of standard Gastec Detector Tubes contains 10 tubes and can conduct 10 total tests comprehensive instruction sheet is included with each box The instruction sheets represented here are examples of the typical instructions for each part number The actual instruction sheet found in each box of Gastec detector tubes may vary slightly for each lot number of detector tubes from the typical instruction sheet found here FOR PROPER PERFORMANCE CONSULT THE ACTUAL INSTRUCTIONS IN EACH BOX OF DETECTOR TUBES If you require an additional instruction sheet for your specific lot number of detector tubes please contact Nextteg Customer Service toll free at 877 312 2333 x20 ar info nextteg com Ass
113. ulation These factors must be considered when choosing the best flow meter size and float code to deliver accuracy in fumigant applications DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 39 BROADCAST SHANK EQUIPMENT ONLY Flow Units Gallons per Minute GPM Fluid Water 100 Methyl Bromide 50 Methyl Bromide DOMINUS 96 AITC Kg L 1 1 1 Target flow meter settings are determined by tractor speed trials and are to be the average of 3 consecutive passes within 5 of target speed The average speed is then inserted into the following table Excel sheet along with of shanks and shank spacing target rate and flow meter GPM These data will be used to calcu late a theoretical flow meter setting Consult your distributor for information on any other flow meter types you may have ENTER VALUES IN GREEN COLORED CELLS ONLY Time to cover 31m 100 20 00 sec Broadcast Treatment Width shanks X shank spacing 12 00 inches 11 00 feet Broadcast rate DOMINUS 96 Insert from DOMINUS Rates Table MB Flowmeter Capacity 0 66 GPM DOMINUS Flowmeter GPM Equivalent from Table Above Enter Values in green cells ONLY Formula 1 60 sec min 65 ft s ft min 2 93 00 m min x trt width ft ft 2 min 3 1023 FT min O ft2 A 0 023485 Acre min 4 0 02348485 Acre min x 30 GPA Gal Min Target 96 Flow Meter Setting DOMINUS GPM 5 0 70454545 Gal min 1 0g Flowmeter NOTE A
114. wy DOMINUS STEWARDSHIP AND TRAINING MANUAL July 2014 DOMINUS STEWARDSHIP AND TRAINING MANUAL July 2014 TABLE OF CONTENTS INTRODUCTION s cosas tmn 6 5 1 DOMINUS Soil Fumigant Stewardship and Training Program 5 2 About This 8 5 3 Product Stewardship 5 DOMINUS Qualified Applicator 6 4 Stewardship and Training Program Overview 6 5 Objectives of the DOMINUS Biofumigant Stewardship Program 6 6 Requirements for ISAGRO USA Qualification 6 DOMINUS Contact 8 CHAPTER 1 DOMINUS PRODUCT 9 DONINUS Product Overview 9 1 Hazard 1 9 2 Environmental HazardS PIRE SEES TIRESREEPEESTZXGGsEPEEEEERATEPERRREES 10 3 Physical and Chemical 10 DOMINUS
115. y Protect uninjured eye if only one eye is exposed to DOMINUS Immediately take off all contaminated clothing Areas of the body that have or are only suspected of having come into contact with the product must be rinsed immediately with plenty of running water and soap WARNING This product is toxic through skin contact OBTAIN IMMEDIATE MEDICAL ATTENTION for all prolonged or severe exposure to the chemical Remove contaminated clothing immediately If usable wash separate from normal laundry If clothing is contaminated beyond use dispose of properly and safely Thoroughly wash those body parts thought to be exposed then proceed with a full body shower or bath Do NOT induce vomiting Give nothing to eat or drink to an unconscious person Have person sip a glass of water if able to swallow Seek medical attention for further action as necessary to treat irritation to skin nose or throat If breathing is irregular or stopped administer artificial respiration If a person is not breathing call 9 1 1 immediately or an ambulance In case of inhalation consult a doctor immediately and show him packing or label for proper treatment Note to Physician Probable mucosal damage may contraindicate the use of gastric lavage Treatment is symptomatic Symptoms of overexposure to AITC include irritation to eyes skin and respiratory system shortness of breath nausea and vomiting DOMINUS Fumigation Management Program Stewar
116. y 2014 49 50 Re entry Procedure The Objective of the re entry procedure is to insure that the label prescribed REP of 5 days or 120 hours is sufficient to allow the entry of workers into the treated area Prior to clearing the treated area a site inspector with appropriate PPE available must confirm that the presence of AITC is below the threshold of 2 ppm as measured with Gastec or Rae System type detector tubes and or devices The site inspector upon arriving at the treated site should inspect the tarp conditions and ensure no unauthorized personnel are within the treated area Beginning with the upwind corner of the treated area inspect for any sensory response to the presence of AITC followed by use of the Gastec detector and or Rae System devices Once the area has been tested and shown to be below threshold limits continue to take samples at regular intervals around the field ending up at the most downwind portion of the field If at any time there is detection above the threshold or sensory response is noted the site inspector should wait for 5 15 minutes before taking another sample If the level of detection does not decrease then entry into the treated area is to be delayed until levels are below detection and sensory response is no longer noted DOMINUS Fumigation Management Program Stewardship and Training Manual July 2014 DOMINUS AIR AND SOIL MONITORING SNIHOLINON TIOS ANV APPENDIX A View P

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