SAFETY DATA SHEET
Contents
1. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate Not available effects Potential delayed effects Not available Long term exposure Potential immediate Not available effects Potential delayed effects Not available Potential chronic health effects Not available General No known significant effects or critical hazards Carcinogenicity No known significant effects or critical hazards Mutagenicity No known significant effects or critical hazards Teratogenicity No known significant effects or critical hazards Developmental effects No known significant effects or critical hazards Fertility effects No known significant effects or critical hazards Numerical measures of toxicity Acute toxicity estimates Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 7 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 11 Toxicological information Route ATE value Dermal 103036 8 mg kg 12 Ecological information Toxicity Not available Persistence and degradability Not available Bioaccumulative potential Not available Mobility in soil Soil water partition Not available coefficient Koc Other adverse effects No known significant effects or critical hazards 13 Disposal considerations Disposal methods Waste packaging should be recycled Waste must be disposed of in acco2. Physical hazards Personal protection Caution HMIS ratings are based on a 0 4 rating scale with 0 representing minimal hazards or risks and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR 1910 1200 the preparer may choose to provide them HMIS ratings are to be used with a fully implemented HMIS program HMIS is a registered mark of the National Paint amp Coatings Association NPCA HMIS materials may be purchased exclusively from J J Keller 800 327 6868 The customer is responsible for determining the PPE code for this material National Fire Protection Association U S A Flammability Health Instability Reactivity Special Reprinted with permission from NFPA 704 2001 Identification of the Hazards of Materials for Emergency Response Copyright 1997 National Fire Protection Association Quincy MA 02269 This reprinted material is not the complete and official position of the National Fire Protection Association on the referenced subject which is represented only by the standard in its entirety Copyright 2001 National Fire Protection Association Quincy MA 02269 This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire health and reactivity hazards of chemicals The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325
3. which would be used as a guideline only Whether the chemicals are classified by NFPA or not anyone using the 704 systems to classify chemicals does so at their own risk Date of issue 19 08 2014 Date of previous issue No previous validation Version 4 Prepared by Reckitt Benckiser Hull UK Dansom Lane Hull HU8 7DS United Kingdom T 44 0 1482 326151 F 44 0 1482 582532 7 Indicates information that has changed from previously issued version Notice to reader Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 10 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 16 Other information To the best of our knowledge the information contained herein is accurate However neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein we cannot guarantee that these are the only hazards that exist Product Care RB is a member of the CSPA Product Care Product Stewardship Program Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 11 11
4. action shall be taken involving any personal risk or without suitable training Evacuate surrounding areas Keep unnecessary and unprotected personnel from entering In the case of aerosols being ruptured care should be taken due to the rapid escape of the pressurized contents and propellant If a large number of containers are ruptured treat as a bulk material spillage according to the instructions in the clean up section Do not touch or walk through spilled material Shut off all ignition sources No flares smoking or flames in hazard area Avoid breathing vapor or mist Provide adequate ventilation Wear appropriate respirator when ventilation is inadequate Put on appropriate personal protective equipment SDS D8179712 Date of issue 19 08 2014 3 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 6 Accidental release measures For emergency responders If specialised clothing is required to deal with the spillage take note of any information in Section 8 on suitable and unsuitable materials See also the information in For non emergency personnel Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil waterways drains and sewers Inform the relevant authorities if the product has caused environmental pollution sewers waterways soil or air Water polluting material May be harmful to the environment if released in large quantities Methods and materials for containme
5. if a risk assessment indicates this is necessary Considering the parameters specified by the glove manufacturer check during use that the gloves are still retaining their protective properties It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers In the case of mixtures consisting of several substances the protection time of the gloves cannot be accurately estimated Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product When there is a risk of ignition from static electricity wear anti static protective clothing For the greatest protection from static discharges clothing should include anti static overalls boots and gloves Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product Use a properly fitted air purifying or air fed respirator complying with an approved standard if a risk assessment indicates this is necessary Respirator selection must be based on known or anticipated exposure levels the hazards of the product and the safe working limits of the selected respirator 9 Physical and chemical properties Appearance Physical state Color Odor Odor threshold p
6. Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM SAFETY DATA SHEET h Air Wick Freshmatic Juicy Peach White Peach amp Magnolia HEALTH HYGIENE gt HOME 1 Product and ren identification Product name Air Wick Freshmatic Island Paradise Distributed by Reckitt Benckiser LLC Morris Corporate Center IV 399 Interpace Parkway P O Box 225 Parsippany New Jersey 07054 0225 1 973 404 2600 Emergency telephone 1 800 338 6167 number Medical Emergency telephone 1 800 424 9300 U S amp Canada CHEMTREC number Transport Outside U S and Canada North America call Chemtrec 703 527 3887 Website http www rbnainfo com This SDS is designed for workplace employees emergency personnel and for other conditions and situations where there is greater potential for large scale or prolonged exposure in accordance with the requirements of USDOL Occupational Safety and Health Administration This SDS is not applicable for consumer use of our products For consumer use all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations and shown in Section 15 of this SDS SDS D8179712 Formulation 0151362_2 2 Hazards identification Classification of the FLAMMABLE AEROSOLS Category 1 substance or mixture Percentage of the mixture consisting of ingredient s of unknown toxicity 78 3 GHS label elements Hazard pictograms Sig
7. H Melting point Boiling point Flash point Evaporation rate Flammability solid gas Lower and upper explosive flammable limits Code FFO151362_2 Liquid Aerosol Not available Characteristic Not available Not available Not available lt 34 C lt 93 2 F Closed cup lt 0 C lt 32 F Not available Not available Not available SDS D8179712 Date of issue 19 08 2014 5 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 9 Physical and enemies properties Vapor pressure Not available Vapor density Not available Relative density Not available Solubility Not available Partition coefficient n Not available octanol water Auto ignition temperature Not available Decomposition temperature Not available Viscosity Not available Aerosol product Type of aerosol Spray Heat of combustion 0 00000527 kJ g 10 Stability and eu Reactivity No specific test data related to reactivity available for this product or its ingredients Chemical stability The product is stable Possibility of hazardous Under normal conditions of storage and use hazardous reactions will not occur reactions Polymerization There are no data available on the mixture itself Conditions to avoid Avoid all possible sources of ignition spark or flame Incompatible materials Do not mix with household chemicals Hazardous decomposition Hazardous d
8. OL OSHA 29CFR 1910 1200 HAZCOM D8179712 8 Exposure controls personal protection Environmental exposure controls Individual protection measures Hygiene measures Eye face protection Skin protection Hand protection Body protection Other skin protection Respiratory protection Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation In some cases fume scrubbers filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels Wash hands forearms and face thoroughly after handling chemical products before eating smoking and using the lavatory and at the end of the working period Appropriate techniques should be used to remove potentially contaminated clothing Wash contaminated clothing before reusing Ensure that eyewash stations and safety showers are close to the workstation location Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes mists gases or dusts If contact is possible the following protection should be worn unless the assessment indicates a higher degree of protection safety glasses with side shields Chemical resistant impervious gloves complying with an approved standard should be worn at all times when handling chemical products
9. ation on ingredients No products were found SARA 304 RQ SARA 311 312 Classification Not applicable Fire hazard Composition information on ingredients No products were found State regulations Massachusetts New York New Jersey Pennsylvania Label elements Signal word Hazard statements Code FFO151362_2 The following components are listed DIFLVOROETHANE BUTANE PROPANE None of the components are listed The following components are listed 1 1 DIFLUOROETHANE ETHANE 1 1 DIFLUORO BUTANE PROPANE The following components are listed BUTANE PROPANE DANGER EXTREMELY FLAMMABLE AEROSOL CAUSES EYE AND SKIN IRRITATION CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE BASED ON ANIMAL DATA SDS D8179712 Date of issue 19 08 2014 9 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 15 Regulatory information Precautionary measures Do not breathe vapor or mist Do not eat drink or smoke when using this product Avoid contact with eyes skin and clothing Keep away from heat sparks open flames and hot surfaces No smoking Do not spray on an open flame or other ignition source Pressurized container Do not pierce or burn even after use Protect from sunlight Do not expose to temperatures exceeding 50 C 122 F Wash thoroughly after handling 16 Other information Hazardous Material Information System U S A Health Flammability O U N
10. ecomposition products carbon oxides Various Organic chemicals products 11 Toxicological information Information on toxicological effects Acute toxicity Not available Irritation Corrosion Not available Sensitization Not available Mutagenicity Not available Carcinogenicity Not available Reproductive toxicity Not available Teratogenicity Not available Specific target organ toxicity single exposure Not available Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 6 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 11 Toxicological information Specific target organ toxicity repeated exposure Not available Aspiration hazard Not available Information on the likely Not available routes of exposure Potential acute health effects Eye contact No known significant effects or critical hazards Inhalation Exposure to decomposition products may cause a health hazard Serious effects may be delayed following exposure Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Symptoms related to the physical chemical and toxicological characteristics Eye contact Adverse symptoms may include the following irritation redness Inhalation Adverse symptoms may include the following respiratory tract irritation coughing Skin contact No specific data Ingestion No specific data
11. ed Potential acute health effects Eye contact No known significant effects or critical hazards Inhalation Exposure to decomposition products may cause a health hazard Serious effects may be delayed following exposure Skin contact No known significant effects or critical hazards Ingestion No known significant effects or critical hazards Over exposure signs symptoms Eye contact Adverse symptoms may include the following irritation redness Inhalation Adverse symptoms may include the following respiratory tract irritation coughing Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 2 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 4 First aid measures Skin contact Ingestion No specific data No specific data Indication of immediate medical attention and special treatment needed if necessary Notes to physician Specific treatments Protection of first aiders Treat symptomatically No specific treatment No action shall be taken involving any personal risk or without suitable training It may be dangerous to the person providing aid to give mouth to mouth resuscitation See toxicological information Section 11 5 Fire fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire fighters S
12. fresh air and keep at rest in a position comfortable for breathing If not breathing if breathing is irregular or if respiratory arrest occurs provide artificial respiration or oxygen by trained personnel It may be dangerous to the person providing aid to give mouth to mouth resuscitation Get medical attention if adverse health effects persist or are severe If unconscious place in recovery position and get medical attention immediately Maintain an open airway In case of inhalation of decomposition products in a fire symptoms may be delayed The exposed person may need to be kept under medical surveillance for 48 hours Skin contact Flush contaminated skin with plenty of water Remove contaminated clothing and shoes Get medical attention if symptoms occur Ingestion Wash out mouth with water Remove dentures if any Move to fresh air If material has been swallowed and the exposed person is conscious give small quantities of water to drink Stop if the exposed person feels sick as vomiting may be dangerous Do not induce vomiting unless directed to do so by medical personnel If vomiting occurs the head should be kept low so that vomit does not enter the lungs Get medical attention if adverse health effects persist or are severe Never give anything by mouth to an unconscious person If unconscious place in recovery position and get medical attention immediately Maintain an open airway Most important symptoms effects acute and delay
13. nal word Danger Hazard statements Extremely flammable aerosol Precautionary statements General Read label before use Keep out of reach of children If medical advice is needed have product container or label at hand Prevention Keep away from heat sparks open flames and hot surfaces No smoking Pressurized container Do not pierce or burn even after use Do not spray on an open flame or other ignition source Response Not applicable Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 1 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 2 Hazards identification Storage Protect from sunlight Do not expose to temperatures exceeding 50 C 122 F Disposal Not applicable Supplemental label None known elements Hazards not otherwise None known classified 3 Composition information on ingredients Substance mixture Mixture There are no ingredients present which within the current knowledge of the supplier and in the concentrations applicable are classified as hazardous to health or the environment and hence require reporting in this section 4 First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water occasionally lifting the upper and lower eyelids Check for and remove any contact lenses Continue to rinse for at least 10 minutes Get medical attention if irritation occurs Inhalation Remove victim to
14. ng vapor or mist Avoid release to the environment Use only with adequate ventilation Wear appropriate respirator when ventilation is inadequate Store and use away from heat sparks open flame or any other ignition source Use explosion proof electrical ventilating lighting and material handling equipment Use only non sparking tools Empty containers retain product residue and can be hazardous Conditions for safe storage Do not store above the following temperature 50 C 122 F Store in accordance with including any local regulations Store away from direct sunlight in a dry cool and well ventilated area incompatibilities away from incompatible materials see Section 10 and food and drink Eliminate all ignition sources Use appropriate containment to avoid environmental contamination 8 Exposure controls personal protection Control Occupational exposure limits Not applicable Appropriate engineering Use only with adequate ventilation If user operations generate dust fumes gas vapor controls or mist use process enclosures local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits The engineering controls also need to keep gas vapor or dust concentrations below any lower explosive limits Use explosion proof ventilation equipment Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 4 11 Conforms to USD
15. nt and cleaning up Small spill Stop leak if without risk Move containers from spill area Use spark proof tools and explosion proof equipment Dilute with water and mop up if water soluble Alternatively or if water insoluble absorb with an inert dry material and place in an appropriate waste disposal container Dispose of via a licensed waste disposal contractor Large spill Stop leak if without risk Move containers from spill area Use spark proof tools and explosion proof equipment Approach release from upwind Prevent entry into sewers water courses basements or confined areas Wash spillages into an effluent treatment plant or proceed as follows Contain and collect spillage with non combustible absorbent material e g sand earth vermiculite or diatomaceous earth and place in container for disposal according to local regulations see Section 13 Dispose of via a licensed waste disposal contractor Contaminated absorbent material may pose the same hazard as the spilled product Note see Section 1 for emergency contact information and Section 13 for waste disposal 7 Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment see Section 8 Pressurized container protect from sunlight and do not expose to temperatures exceeding 50 C Do not pierce or burn even after use Do not ingest Avoid contact with eyes skin and clothing Avoid breathing gas Avoid breathi
16. pecial protective equipment for fire fighters Use an extinguishing agent suitable for the surrounding fire None known Extremely flammable aerosol In a fire or if heated a pressure increase will occur and the container may burst with the risk of a subsequent explosion Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back causing fire or explosion Bursting aerosol containers may be propelled from a fire at high speed Runoff to sewer may create fire or explosion hazard Fire water contaminated with this material must be contained and prevented from being discharged to any waterway sewer or drain Decomposition products may include the following materials carbon dioxide carbon monoxide halogenated compounds carbonyl halides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire No action shall be taken involving any personal risk or without suitable training Move containers from fire area if this can be done without risk Use water spray to keep fire exposed containers cool Fire fighters should wear appropriate protective equipment and self contained breathing apparatus SCBA with a full face piece operated in positive pressure mode 6 Accidental release measures Personal precautions protective equipment and emergency procedures For non emergency personnel Code FFO151362_2 No
17. rdance with federal state and local environmental control regulations 14 Transport information Regulatory UN number Proper shipping Classes PG Label Additional information name information DOT Classification UN1950 Aerosols Limited quantity TDG Classification UN1950 AEROSOLS Limited quantity Limited quantity Classification IMDG Class UN1950 AEROSOLS Limited quantity Mexico UN1950 AEROSOLES eo Code FFO151362_2 SDS D8179712 Date of issue 19 08 2014 8 11 Conforms to USDOL OSHA 29CFR 1910 1200 HAZCOM D8179712 14 Transport information UN1950 IATA DGR Class Aerosols flammable 2 1 3 See DG List PG Packing group 15 Regulatory information U S Federal regulations Clean Air Act Section 112 b Hazardous Air Pollutants HAPs Clean Air Act Section 602 Class Substances Clean Air Act Section 602 Class Il Substances DEA List Chemicals Precursor Chemicals DEA List II Chemicals Essential Chemicals SARA 302 304 TSCA 8 a PAIR 2 benzylideneheptanal 3 p cumenyl 2 methylpropionaldehyde a methylcinnamaldehyde a hexylcinnamaldehyde TSCA 8 a CDR Exempt Partial exemption Not determined United States inventory TSCA 8b Not determined Clean Air Act CAA 112 regulated flammable substances 1 1 difluoroethane butane propane Not listed Not listed Not listed Not listed Not listed Composition inform
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