Hydrogen Storage Materials
Contents
1.2. Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com PCT PCI
3. Tel 03 5796 7330 Fax 03 5796 7335
4. PCTPro 2000 Sieverts Apparatus Sieverts Apparatus 1 2 a amp Cd
5. 1 3
6. H gt 417 39 17 Charbonnier J de Rango P Fruchart D Miraglia S Pontonnier L Rivoirard S Skryabina N Vulliet P J Alloys Compas BT 1 Hydrogen Posture Plan the U S Department of Energy 2006 2004 383 205 18 Balema V P Dennis K W Pecharsky V K Chem 5 2 http www hydrogen energy gov annual progressO6 html 3 Heinicke Commun 2000 1665 19 Chen S Williams J Materials Science Forum G Tribochemistry Academie Verlag Berlin 1984 4 Suryanarayana C 225 227 TransTech Publications Inc Stafa Zurich 1996 p 881 Progr Materials Sci 2001 46 1 5 Bowma
7. 2 5 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjpGsial com D D D l d Q J q Q sigma aldrich com japan RTI A A Z7 A dise i D 1A DOE DOE 2010 2015 1
8. 1 kg 1 20 1 kg H 1 3 79 2007 3 sd HYDRNOL 1 kg 2 50 N 5
9. 40 20 20 C Potential mV 40 60 80 3 PSS PAH 2 2 PSS PAH EDS FESEM 4 SEM E PSS PAH 1 X 4
10. 1 Pulverisette 5 4 Fritsch E Spex 8000M CF 1 6 MH AIH 9 MAH 1 2MH 2Al 3 H gt 2MAIH P MAIH 2MH 9 MAIH ae M AlH 2AIH gt 3MAIH 4 M Li Na TiCl 3LiBH 9 Ti BH 3LiCI 5 4 UCI 4LiBH w U BH ALiCI 6
11. PEM Xe E IS BUR C dz HR C OD Chandra AB 5 NH BH 0 B N BH H H 0O
12. AB NH BH 190 9 kg 100 140 g L 1
13. 6 CF 2 nm 8 3
14. 1 DOE 2010 24 2010 300 483 km 20 2015 1 2010
15. 24 X XRD 5 NaAlH NaAIH 20 28 XRD 4 SEM X irt irm s EL man i 6 Th MTM 5 24 NaAlH X fg 6a PsS PAH
16. Sunita Satyapal US DOE 2010 60 gm H kg 45 gm H DOE i density 5 g cm 2 g cm BaRe Mg 2 lt 373 K ar 620K Joor Mg NM Mog NiH o paf efi 550 K 4 bar 300K w NaAIH Hoss gt 1 5 bar 0 5 10 dec Pr ac Te de 5520 kg LIA H dec 580 K dec A00 K
17. 1 DOE 70 EE 10 DOE 63 103 190 v 166 306 km EPA 2 4 5 kg 1 2010
18. 1 Zetaplus BIC 3 PSS 60 mV PAH 16 mV PSS PAH 2 75 mV 16 mV CS
19. fis 2 A MAS NMR iT m d m um m 2 L um m 2 H 130 35 MHz AIHs NaAIH Na AIH a y 7AI MAS NMR Z Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 29 Lj eT Lad D 2 PL L LI amp HJHT 2 30 y Ed E EE E zZ E 99 a a p LI T b b ALDRICH sigma aldrich com japan oc y AIH UD
20. 1 H O H O PSS PAH Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjpts sial com 21 7 250 nm 40 nm PSS PAH 3 Aq a yum Fg sa sier TE E
21. H M BH fF HC V Balema Be Al Zr M BH M X Aldrich 222356 LiCI NaBH LIBH 0 68 g cm3
22. NH BH 2 CH NBH JT II T Jb ESCFChRNeEBREC NH BH 70 96 3 NaBH NH C dethyLether y NH BH NaCl H 2 H B OEt NH SEXE ST NH BH 3 NH BH BH NH 6 0 JJ XXI gx Webs
23. 1 Satyapal S Petrovic J Read C Thomas G Ordaz G Catal Today 2007 120 246 2 Schubert D M Borax Pioneer 2001 20 3 Shore S G Parry R W J Am Chem Soc 1955 77 6084 4 Shore S G Parry R W J Am Chem Soc 1958 80 8 5 Parry R W Schultz D R Girardot P R J Am Chem Soc 1958 80 1 6 Weaver J R Shore S G Parry R W J Chem Phys 1958 29 1 7 Baitalow F Baumann J Wolf G Jaenicke Rossler K Leitner G Thermochim Acta 2002 391 159 8 Wolf G Baumann J Baitalow F Hoffmann F P Thermochim Acta 2000 343 19 9 Wolf G van Miltenburg J C Wolf U Thermochim Acta 1998 317 111 10 Baumann J Baitalow E Wolf G Thermochim Acta 2005 430 9 11 Sit V Geanangel R A Wendlandt W W Thermochim Acta 1987 113 379 12 Komm R Geanangel R A Liepins R norg Chem 1983 22 1684 13 Hu M G Geanangel R A Wendlandt W W Thermochim Acta 1978 23 249 14 Xu Q Chandra M J Power Sources 2006 163 364 15 Chandra M Xu Q J Power Sources 2006 156 190 16 Denney M C Pons V Hebden T J Heinekey D M Goldberg K I J Am Chem
24. BH NH 8 catalyst 3 n NH BH i H NBH n H 8 POCOP lr H POCOP Z m3 1 3 OPtBu CSH D Linehan amp Rh CH NHBH H 3 1 Rh Rh ex situ X XAFsS NMR Rh n 4 6 in situ
25. LaNiaH 2 Mg 4 NaAlH 2 ZrNiH ZrNiD 2 NMR Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com 28 MAS NMR MQMAS NMR 1 Cotts R M in Hydrogen in Metals I Basic Properties Alefeld G J Volkl Eds Springer Berlin Heidelberg 1978 p 227 2 Richter D Hempelmann R Bowman Jr R C in Hydrogen in Intermetallic Compounds II Surfaces and Dynamic Properties Applications Schlapbach L Ed Springer Verlag Berlin 1992
26. DADB AB AB DADB NH BH 2 E H 4 7 nNH4BH NH BHj n 1 H 120 C intermolecular X 4 NH BH NHBH H 150 C intramolecular 5 2 NHBH NHB NBH H 4150 C cross linking 6 NHBH BN H gt 500 C boron nitride 7 2 AB PAB NH BH PAB PIB NHBH 12 9 2 150C
27. 18 oc AlH 3 IB EL pro E an ba ADi i E mu Fe ea m J m 3 o AIH 2D MOMAS YAI 9 235 kHz 6 pom 5 6 Al O 40 ppm 65 ppm 2 7Al 23Na B NMR ADAI Frydman 2 MQMAS NMR MOQMAS MAS NMR 3 AI 2D MOMAS NMR 1D 7A MAS NMR
28. in situ XFAS NMR El 2 pum E L h 00 mccum W 2 DMAB Rh 17 2006 American Chemical SOCclety 100C 1 RIED 2 3 fJ 4 5 Bluhm Sneddon 1 3 bmimCI
29. Cd 8 NalHB OCH 250 280C NaBH 4 NaH B OCH gt NaBH 3 NaOCH 8 Bayer 9 400 500C NaBH NH Na B O 7 SiO 16 Na 8 H 9 4 NaBH 7 Na SiO 9 NaBH d EKORT d ezKGRAERVICTRSFI C e Anel NaBO NaBH 30
30. e Lc e l 5 a dE _ 11 __ 16 Conversio ooit __ 19 HYDRNOL CAORA 23 vn ERE ARE si ee 2 To SA Sn cm yE AN ZAZ 29
31. 500 710 5 1 2 3 4 5 SBA 15 Geanangel 1980 DSC DTA TGA AB O A 1 179 DTA 112C AB 112 114C
32. 686093 1KT 98 800 10 g KREASE XD 90 Lithium amide LINH 8 7 gt 95 686050 10G 4 200 Sodium amide NaNH 5 1 gt 95 686042 10G 4 300 Lithium nitride Li N gt 95 399558 10G 8 800 Lithium aluminum hydride LiAIH 10 5 gt 97 686034 10G 4 200 Sodium aluminum hydride NaAlH 7 4 gt 97 685984 10G 8 400 Lithium hydride LiH 12 6 gt 95 201049 10G 8 200 Sodium hydride NaH 4 1 gt 95 223441 10G 5 600 Calcium hydride CaH 4 7 gt 95 213322 10G 4 000 Lithium borohydride LiBH4 13 9 gt 95 686026 10G 21 100 Sodium borohydride NaBH 10 6 gt 95 686018 10G 8 700 Borane ammonia complex H N BH 19 5 gt 95 287717 10G 25 500 Magnesium hydride MgH 7 6 98 683043 10G 6 800 686107 1KT 44 200 F3 1 g X RD
33. light duty vehicles 300 483 km DOE 2010 2015 DOE FreedomCAR DOE
34. sigma aldrich com japan SIGMA ALDRICH 140 0002 2 24 4F TEL 0O3 5796 7330 FAX 03 5796 7335 E mail sialjptsQsial com TEL 03 5796 7320 FAX 03 5796 7325 http www sigma aldrich com japan ISO 9001 A 234 SAJ 2008 2 JQA QMA12647
35. 9 PSS MW 70 000 Aldrich 243051 PAH MW 15000 Aldrich 283223 1 PSS PAH 20 mg mL 2 mg mL PSS PAH
36. i m e ASCl m 7Jes Tick ite e HyAnalysis sigma aldrich com pctpro E matsci sial com Y ALDRICH sigma Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com Dr Robert C Bowman Jr and Dr Son Jong Hwang California Institute of Technology NMR 50 NMR 3 3
37. 2 9 ua seini 1 Sieverts Apparatus Sievert i
38. B 2 a A 2 9
39. LHV 80 120C 40 kJ mol H 8 DFT DT 14 D A H M BH
40. 4 Ed 1 X MAS NMR 5 MAS NMR
41. Vol 2 No 2 KAREE 3
42. t2 3 20 RPAC RULI
43. van t Hoff In P 2 AH RT AS R P T R A H AS 5 3 LaNi CO 6 PCT van t Hoff 6 PCTPro 2000 1 AH AS IF 1T Lama mirada HH Ta 3 LaNi PCT van t Hoff 70w F3 Sievert
44. 5 Asemblon Asemblon 2007 Asemblon 1 4 H urs ni 1 HYDRNOL Asemblon mU 1 HYDRNOL HYDRNOL D CoA d
45. 29 4 10 GPa s hv Solution hv Solid State OLI ut Shear stress bu State No Reaction 4 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 17 HJHT 2 18
46. G 49 Q t9 E O U E U i Uu T s B E d la e Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com Dr Grigorii L Soloveichik General Electric Global Research S Satyapal DOE PEM 80 120C LaNi Tie
47. 4 alumohydride 5 BF B H 4 LiH BF Et O 993 LiBH 3 LiFW EO 4 LiAIH B OMe 9 LiBH A OMe 5 6 M BH MXn n M BH 9 M BH n MX 6 BH eld Na K Ca Al w 1 1 2
48. 6 a QCM PSS PAH 6 b PAH 19 J 72 JU MATA DAADE ELEUDZXHRNZ TIO SIO 7 250 nm E 40 nm PAHPSS PAH VU 73 CE 1 nm 500 nm 1 Zuttel A Materials Today 2003 6 24 2 Fichtner M Advanced 6b PAH read 0 a 3 o G D i us 224 us E p t ymposium Series eregalli V Parrin
49. 120C 117C DTA TGA 2 H Wolf AB AB 3 SD E5508 AB gt PAB PAB gt PIB
50. d HYDRNOL HYDRNOL HYDRNOL Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjpts sial com 1 kg H H DA HJARA E H H kg kg 3 5 kg kg HYDRNOL 1 20 0 60 0 60 0 05 0 10 2 50 Liquid Rehydrogenation 2 way Transport Standard Temperature and Pressure Compressed 1 20 0 70 0 70 0 45 0 75 3 80 Hydrogen Compression to Pressurized Tanker High Pressure 7 000 psi or 450 bar Storage Tanks Liquid 1 20 1 11 0 21 0 24 0 66 3 42 Hydrogen Cryogenic Cryogenic Tanker Cryogenic Storage Liquification including boil off losses 5
51. AB 4 SBA 15 0 10 gt 00 gt X AB SBA 15 DU 0 00 Tale 0 100 200 300 400 Time min tramp E 5 SBA 15 AB DSO H DSC Heat Released mW mg c NO 500 600 1 2
52. NH3 BH BH BH bmimCI 1 g 7 BF LT s i a i i ma n pp i da i E Ll i Al th 1 XE M E E m pls a Mul aV E JL 1 3 B NMR DFT GIAO AB 18 2006 American Chemical Society Geanangel B NMR NH BH 80C 93
53. NH BH NH BH 3 1 NH BH 2 NH BH 3 2 NH BH Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com SBA 15 Gutowska AB
54. 7 12 14 M BH 1 M BH AH 5 M BH wM nB 2n H 14 Vajo 5 MgB 5 AlB 6 Li Sn Li Mg AH GX 15 17 10 25 kJ mol H 150 250C 1 Mg7
55. 1gcm AI BH 3 dec 73 Ka 200 K NH BH NHBH 3H 0 7 g cm NH BHz NB 4H H chemisorbed CH us Kon carbon CH b p 272 k 20 pressurized H 9 413 composite material M p MPa 15 20 25 gravimetric H density mass 1 ERATGZKSRRT IBUM 10D E M Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjpts sial com DADB 1 DADB NH CI DADB NH BH NH BH DADB BH NH BH BH NH 3 CI NH BH Shore Parry NH4BH 1 3 BH NH3 BH 2 NHCI UD MEN BH NH3 CI NH BH H 1 Small amt of NH NH4BH
56. c Niobium V oxide Nb O 99 208515 1G 4 200 M Titanium lll chloride TiCls 99 686085 1G 6 500 Nd Titanium Il hydride TiH 4 0 98 686069 1G 4 300 E Zirconium ll hydride ZrH 2 1 99 208558 1G 4 100 Vanadium lll chloride WC 97 208272 1G 4 200 Scandium lll chloride SG 99 686077 1G 26 300 sigma aldrich com hydrogen I 5 HE D s Q Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com a s LI m z v i a u Dr Tabbetha Dobbins Vimal Kamineni and Dr Yuri Lvov Institute for Micromanufacturing Louisiana Tech University H lt 3
57. Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 11 12 51 2 3 P cul Ei d p LIT bg ALDRICH sigma aldrich com japan 1 Be Al 2 MH n 2 B H 39 M BH 1 ALMe 4 BH gt 2 AKBH 2 BMe 2 M Mg Ca Sr Ba B H 3 MH 3 B H Pr 39 M BH 4 BPr 3 1 2 in situ
58. Dr Abhi Karkamkar Dr Chris Aardahl and Dr Tom Autrey Pacific Northwest National Laboratory 1 300 483 km 2 300 483 km 5 kg STP C 5 kg 54 m 300 483 km 700 bar 40 g L 70 g L b p 253C
59. J ARD OSOSBC xd 1 10 dualbladder 2 HRM DOL HRM Asemblon Asemblon 2
60. Usable specific energy from H 2 kWh kg net useful energy max system mass 0 06 kg H kg system or 6 wt 96 Usable energy density from H 1 5 kWh L net useful energy max system volume 0 045 kg HL system MAEAEA e Operating ambient temperature e Min max delivery temperature e Cycle life 1 4 tank to full e Min delivery pressure from tank FC fuel cell ICE internal combustion engine 30 50 C sun 40 85 C 1000 Cycles 4 FC 35 ICE Atm abs e System fill time for 5 kg H 3 min e Min full flow rate 0 02 g s kW e Transient response 1096 9096 0 75 s and 9096 096 DOE ICE 2 5 3 5 13 kg 1 kg 1 3 79 Da
61. i B H XN i B H Bh di iv Li Na Mg C LIBH LIH B 13 9 2 LIBH MgH 3 LIH MgB 11 4 2 LiBH Al 2 LiH AlB 8 6 7 LIBH 1 75 Mg Sn 0 25 Sn Li Sn 3 5 MoB 6 3 NaBH NaH B 7 9 2 NaBH MgH 3 NaH MoB 7 8 Be BH4 Be 2B 20 8 Mog BH4 Mg 2B 14 9 Ca BH 2 3 CaH 1 3CaB 9 7 Ca BH MgH CaH MoB 8 3 Zn BH4 Zn 2B 8 5 AI BH s Al 3B 16 9 Sc BH4 ScB B 13 5 Ti BH4 s TiB B 13 1 Mn BH4 Mn 2B 9 5 Zr BH ZrB 2B 10 7 g H L AH kJ mol H 93 75 402 470 3 4 46 225 315 5 6 188 6 46 184 4 85 5 90 609 595 3 4 62 351 4 7 126 27 123 8 113 40 323 3 8 9 108 75 5 360 1031 159 4 85 12 121 6 150 13 14 260 15 25 16 108 250 17
62. 2 96 Bogdanov C NaAIH alumohydride alanate NaAlH t LiAIH 10 596 1 AIH 10 06 1 24 Kbar R1 DOE
63. Asemblon Asemblon well to wheels 3 HYDRNOL 3 2596 14 gu 3 Asemblon HYDRNOL 4 4 4 Cd HYDRNOL
64. E rcp E T Material Matters GE T aze 7ja Matters matsci sial com
65. NMR d ga KR TERNE COD SIS NM 10 6 AlH LiAlH NaAlH 7 NMR 815 UC 1 Caltech NMR ga AlH H MAS NMR T 1 500 23 MHz
66. Herberg 1 Al ZAI MQMAS MAS NMR H MAS NMR CD 77 4 2 2 ZrNiD D MAS NMR 23 Z NMR B ZrNiD
67. PCTPro 2000 in situ XRD IR CeMn Al 4a 4b in situ 4a in situ XRD D2B ILL Grenoble Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 27 H A j Tr 1 Jb HJHT 2 28 1 Eddaoudi M Kim J Rosi N Vodak D Wachter J O Keeffe M Yaghi O M Science 2002 295 469 2 Gutowska A Li L Shin Y Wang C M Li X S Linehan J C Smith
68. Ti 7 8 7 LHIiAIH D Ti 8 nMAIH TICL gt nMCI Al TiAl TiHL traces H 7 5 16 M Li Na n 3 4 MgH TiCl gt MgCl TiH 7 9 12 13 d 4 11 G Soloveichik E Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjpts
69. H MAS NMR ZAI MAS NMR AlH 6 5 CO 1 7Al MAS NMR 1 AIH Li Na Al AI Al 8 ppm Co MHz E o AIH AlH 5 8 0 25 0 1 17 18 B AlH AIlH 21 5 0 38 0 49 17 18 y AIH AlH 10 9 2 9 0 58 17 18 AIH II 36 0 4 0 0 02 LiAIH AIH 103 8 3 9 0 24 12 Li AIH AIH 33 7 1 4 0 02 12 NaAIH AlH 101 2 95 0 8 Na AlH AlHg3 42 7 11 Al metal Als 1641 z 14 aCQ 5m 27Al MAS NMR
70. 1 2 Asemblon Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 23 E 0 Aes n ET HJHT 2 24 E 0 n ET 51 e sigma aldrich com japan 3 DOL DOL DOL me 4 DOL
71. 1 Ca BH 360C 500C 12 9 696 Ca BH 93 2 3 CaH 1 3 CaB 10 3 H 12 Zn BH ZnCl NaBH NaCl DSC Zn BH 95C AER Cd o CEVDURING Tl 13 2 AI BH 8 AICI NaBH 7 AK BH 64C X 3 GB 180K 3 BH
72. 39 Plesek He m nek Ik MoH 1 3 Konoplev Bakulina MgCl NaBH 6 Mg BH 2 X XRD Mg BH GE GRC 32 XRD Mog BH 2 185 C CSS eed B 3 Mg 4 BH Mog BH 300C 376C 2 357C 1
73. DOE DOE DOE 2 4 PEM 2 2010
74. 2 108C 278C H LBH 320 380 0 H 4700 3 5096 LiBH 3 LiBH 8096 7 10 H 7596 3 7 Cik IBH Bru LIBH gt LiH B 3 2 H 7 NaBH Aldrich 480886 452882 452874 452173 452165 505C NaBH 2
75. H 10 H 15 H 10 g 18 H TRARAL H 1 g 22 H H 22 25 H 28 H B B 31 IKA ULTRA TURRAX Tube Drive Personal Workstation for Stirring Dispersing and Milling e e e IKAS ULTRA TURRAX 3
76. CNT MOF 2 PCTPro 2000
77. M BH LIBH 65 Schlesinger Brown 3 NaBH O NaBH 20 Na K Mg Ba 4
78. Ca BH LiBH Mg BH 1 LIBH 3 1 d 5 200C 320C 453C 2 M BH 1 600 700C Na Mg Ba 2 IH 150 bar H
79. B N NH BH Pt Denney Goldberg jr 14 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 7 Bii E i L E a Pay d LJ LA 7 Le Vid 7 D Bi LL ALDRICH sigma aldrich com japan 45C 2 4 7 lr
80. AB 8 bmimCI 85 90 95C 1 0 5 0 8 1 124800 H 3 0 95 1 2 1 5 22 1 2 1 4 1 6 H 0 9 bmimCl 3 9 4 5 5 4 8889600 H bmimCl NH BH BH 3
81. HHE a ST 20 Stirring Tube With built in stirrer for mixing and stirring volumes 2 15mL Pack of 25 tubes Prod No Z722391 40 000 m DT 20 Dispersing Tube With built in rotor stator element for dispersion and homogenization of solids and suspensions volumes 5 15mL Pack of 25 tubes Prod No 2722375 40 000 Glass beads Pack of 25 tubes Prod No Z722413 40 000 m BMT 20G and BMT 20S Ball Mill Tubes With glass or stainless steel balls for dry milling or cell disruption of volumes 2 15mL SS balls Pack of 25 tubes Prod No 2722448 40 000 p Uuu iEd u 27p2 72 BIEN MER RJ 2 2 Workstation set with 115V power supply Prod No Z722332 99 800 IKA IKA Works Ultra Turrax IKA Works D D D l Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com Lj Eu E IU i JUL LA 7 L PF 7 D ik 7K LI QU ALDRICH sigma aldrich com japan
82. PCI 1 PCI PCI x B 3 PCI P
83. a co AIH HH MAS NMR 0 kHz d1 300 s MAS 14 5 kHz d1 300 s E MAS 35 kHz d12300s dgd1 NMR gt 1 2 54 7 gt 5 kHz 5 1 0 kHz 7 496 MAS 35 kHz
84. EB Cd 5 DOE
85. 10 26 NaBO 2 CaH w NaBH 2 CaO 10 Be BH 1 BeMe 2 BeCl 140C 28 BeH BH BeH BH BH Be BH Be BH Be BH AH Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com Mg BH 50
86. HYDRNOL HYDRNOL HYDRNOL 7 C HYDRNOL 8 9 10 11 12 pum use Iun NR 1 http hydrogenhighway ca goV 2 http www wired com news autotech 0 2554 63145 00 html 3 http www greencarcongress com 2005 05 california roll html 4 http hews bbc co uk 1 hi programmes newsnight archive 2208013 stm 5 http www
87. SBA 15 AB 4 2 114C 85C 5SBA 15 AB 2 1 H me 2 AB H 2 me 80 AB 5 B NMR AB AB SBA 15 B TPD MS NMR
88. lt H H 1 H 1 9 NaAlH Aldrich 357472 LiAIH Aldrich 199877 LiH Aldrich 201049 NaH Aldrich 5 223441 5
89. BH AI BH Ti BH 20C TiB B H 6 Mn BH Mn BH nL Zr BH NaZrF ZrCl AI BH4 s c 39 Zr BH ZrB 7 ZrB B Zr
90. Viktor Balema Ph D Materials Science Sigma Aldrich Corporation 1 Hydrogen Storage MRS Bulletin Vol 27 No 9 2002 MRS Bulletin sigma aldrich com japan Q lt NL d n ps Dr Carole Read Dr George Thomas Ms Grace Ordaz and Dr Sunita Satyapal U S Department of Energy Hydrogen Program
91. MoH 800 bar LiH MoB B 100 bar 300C 5 MgB 200 bar 300C NaBH Ca BH 350 bar 400C 24 NaAlH LIBH X Mg BH Li Ca 1 Bogdanovi B Schwickardi M J Alloys Compounds 1997 253 254 2 Konovalov S K Bulychev B M norg Chem 1995 34 172 3 Stasinevich D S Egorenko G A Zh Neorg Khim 1968 13 654 4 Barkhordarian G Klassen T Dornheima M Bormann R J Alloys Compounds 2007 in press 5 Vajo
92. r1 LI 1 3 Bis 2 6 diisopropylphenyl imidazolinium chloride HaC_cCH Hac CHs 97 656623 1G 8 400 a T Z NUN 656623 5G 28 900 x LI t CH3 Ba d HsC CH3 i 1 3 Bis 2 4 6 trimethylphenyl imidazolinium chloride CH3 HaC 95 656631 1G 8 800 aom 656631 5G 30 600 HaC CH3 CHs HsSC Le 1 3 Diisopropylimidazolium tetrafluoroborate Hac VL V CH 96 660019 1G 6 800 bou 2 d 660019 5G 23 700 HaC gry CHs 1 3 Bis 1 adamantyl imidazolium tetrafluoroborate Yep 97 660035 1G 16 900 p BF 1 3 Di tert butylimidazolinium tetrafluoroborate HsC CHs 95 659991 1G 8 400 HiC NN ch 659991 5G 28 900 CH3 CH3 BF 1 Butyl 3 methylimidazolium chloride je G 99 04129 5G F 7 100 HaC LN ZN CHs 04129 25G F 28 400 1 Butyl 3 methylimidazolium bromide Br 98 5 64133 5G 13 000 HG A N Nich 64133 25G 48 800 1 Butyl 3 methylimidazolium hydrogen carbonate je pos 97 670723 10G 19 400 Ho V NNi eh 7 670723 100G 95 400 1 Butyl 3 methylimidazolium tetrafluoroborate S BR gt 97 91508 5G 10 300 HsC N ZN CH 91508 50G 34 000 91508 250G 94 600 1 Butyl 3 methylimidazolium hexafluorophosphate S PRO gt 96 70956 5G 5 600 HaC n N Z N CHs 70956 50G 34 000 70956 250G 95 400 1 Butyl 3 methylimidazolium dibutyl phosphate lt O CHe sCHs gt 96 669733 5G 18 300 m Ed 669733 50G 67 800 3 CH2 3CH3 ChemrFiles 2005 Vol 5 No 6 sigma aldrich com
93. AlH B AlB AI BH 150C 4 5 5 kJ mol H Po 9s Sc BH Sc BH Sc BH 2THF Sc BH DME ScCI e UBH 2200 2500 cm w B H 5 150C 260C 5 Ti BH l4 LIBH Ticl Ticl Ti BH Fl
94. 15 PSS APAD 16 15 1 f iD 15 Zetaplus BIC 2 2 PSS PAH 4 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 19 E m 1 L L1 i3 r p a 4 20 eE fax radi E J m 1 Q ALDRICH sigma aldrich com japan 2
95. 5 D 2 ZrNiD 2 4 y ZrNiD E B ZrNiD P D MAS NMR f 76 79 MHz 23 D 2 20H Adolphi D MAS NMR HLT YD 2 24 NMR
96. 1H 2D BERKUT 23Na 5Sc 51V 89Y 93Nb La NMR 3 B C N Na Mg Al Si 3 MAS MQ MAS NMR NMR 5
97. 2015 Current Cost Estimates based on 500 000 units 700 bar Bg 350 bar 2015 targets kWh al 10 15 20 2010 target 2010 targets liquid hydrogen chemical hydride A a T9 m cryocompressed F 700 bar 250 bar tanks Learning Demo volumetric capacity g L complex hydride gravimetric capacity wt 1 1 05 06 63 ECOD SECT
98. Mg BH4 MgH MgH Gi 11 3 Mog BH Mg BH gt 3 H 2 B MgH amorph 73 MgH eyso gt Mg H 11 Ca BH Aldrich 389986 21057 3 THF36 CaCl NaBH Ca BH 2THF 190C 36 Ca BH k 1 12 g cm3 Ca BH Ca e BH BH 3 Ca Ca BH Mg BH
99. Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 13 14 CY ALDRICH com japan aldrich sigma 3 Mog NH LINH 9 2 LiBH MgH 39 2 LiH MgB 4 H 15 2 LiBH Al gt 2 LiH AIB 3 H 16 7 LiBH 1 75 Mg Sn 0 25 Sn gt 2 LLSn 3 5 MgB 14 H 17 KRT E UC O Silii HeRR AH M BH
100. 3 24 26 R CeHs sP C ball milling CeHs sP CH2R X KeCO KHCO TOM R R O CeHs sP O coR HH R R O R R C OH ball milling bi O HN Som H R amp R oN Som X Ij O O ball milling CaHs aP c ball milling CeHs aP SP gt LP CeHs sP CI KCO3 CeHs sP KCI 2 CeHs sP PtClo 3 2426 Spex EE 60C 2 GPa 28
101. B 427640 1G 3 500 427640 10G 24 400 ISOTEC Sigma Aldrich SI Tel 03 5788 8550 FAX 03 5788 8710 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 31 D 2 a www sigma aldrich com Chemistry Web Chem Product Central 4 Uj ram did Sirin Len Tm Prolia Erder era Sair Gigot A Pepiees Supp Hei LE Procuct Cenia Feue te or lja TEGS m li i g iE Q Substructure Search YY Reaction Database Beta Version EN uH Tr LE TEM m LL mi Ri Building Blocks Organometallic Reagents Synthetic Reagents Specialty Synthesis 3 Organic Building Blocks 3 Boronic Acids and 3 Coupling 3 Lewis Acids 3 Peptide Synthesis 3 Heterocyclic Building Derivatives 3 C C Bond Formation 3 Organic Acids 3 Carbohydrate Synthesis Blocks 3 Grignard Reagents 3 C X Bond Formation 3 Inorganic Acids 3 Oligonucleotide Synthesis 3 Amino Acid Derivatives 3 Reike and Organozinc Halogen 3 Phosphazene Bases 3 Enzyme Mediated Synthesis O Unnatural Am
102. Borisov A P Karpova T P Petrova L A Zh Neorg Khim 1995 40 1641 42 Yu X B Grant D M and Walker G S Chem Commun 2006 3906 43 Miwa K Ohba N Towata S i Nakamori Y Orimo S i Phys Rev B 2004 69 245120 44 Orimo S Nakamori Y Kitahara G Miwa K Ohba N Noritake T Towata S Applied Physics A Materials Science amp Processing 2004 79 1765 Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjptsGsial com Lithium borohydride LIBH 13 9 Decomposition temp 470 C moisture sensitive toxic Potassium borohydride KBH 7 4 Decomposition temp 500 C moisture sensitive toxic Sodium borohydride NaBH 10 6 Decomposition temp 595 C reacts with water stable in basic aqueous solutions Calcium borohydride 11 5 unsolvated bis tetrahydrofuran complex Ca BHJ 2C H O Decomposition temp 360 C after desolvatation at 190 C in vacuum soluble in water without decomposition Magnesium boride MgB Stable Used as catalyst additive sigma aldrich com hydrogen Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 96 gt 90 gt 95
103. 2015 dU 1 http www eere energy gov vehiclesandfuels about partnerships freedomcar The partnership includes the U S Council for Automotive Research USCAR and the energy companies BP Chevron ConocoPhillips ExxonMobil and Shell 2 DOE Office of Energy Efficiency and Renewable Energy Hydrogen Fuel Cells amp Infrastructure Technologies Program Multi Year Research Development and Demonstration Plan available at http www eere energy gov hydrogenandfuelcells mypp 3 FY2006 Annual Progress Report for the DOE Hydrogen Program November 2006 available at http www hydrogen energy gov annual progress html 4 S Satyapal et al FY2006 DOE Hydrogen Program Annual Merit Review and Peer Evaluation Meeting Proceedings Plenary Session available at http www hydrogen energy gov annual reviewO6 plenary html 5 High Density Hydrogen Storage System Demonstration Using NaAIH Complex Compound Hydrides Presentation by D Mosher et al United Technologies Research Center prepared under DOE Cooperative Agreement DE FC36 02AL 67610 December 16 2006 http www 1 eere energy gov hydrogenandfuelcells pdfs storage system prototype pdf E mail sialjptsGsial com amp
104. 241903 50G 241903 250G 415103 25G 415103 100G 399558 5G 399558 25G 415111 10G 415111 50G Tel 03 5796 7330 Fax 03 5796 7335 E mail sialjpts sial com 96 Calcium hydride CaH 4 7 Decomposition temp 600 C 99 99 497355 2G 23 700 moisture sensitive 497355 10G 18 300 99 9 558257 10G 15 300 95 213322 100G 9 600 213322 500G 33 600 E JE Lithium hydride LiH 12 6 Decomposition temp 720 C 95 201049 5G 4 700 moisture sensitive 201049 100G 15 700 P zx 201049 500G 51 000 Lithium aluminum hydride LiAIH 10 5 Decomposition temp 95 199877 10G 2 900 m i 150 175 C step 1 199877 25G 4 700 180 224 C step 2 199877 100G 11 100 gt 400 C step 3 199877 1KG 61 400 T extremely moisture sensitive gt 97 62420 10G F 5 900 LS 6 62420 50G F 15 900 PIA 62420 250G F 56 500 aZ Sodium aluminum hydride NaAlH 7 4 Decomposition temp 97 685984 10G 8 400 Fm 5C ste MI Fr TA id iR gt 90 357472 25G 12 200 Lj 250 300 C step 2 i a E gt 400 C step 3 Ba extremely moisture sensitive T 1 Sodium hydride NaH 4 1 Decomposition temp 800 C 95 223441 10G 5 600 moisture sensitive 223441 50G 11 600 223441 250G 44 000 223441 1KG 141 200 Titanium ll hydride TiH 4 0 Decomposition temp 98 209279 100G 10 000 450 550 C step 1 209279 500G 46 100 550 650 C step 2 Zirconium Il hy
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107. 98 99 9 gt 97 0 gt 98 98 98 5 99 99 gt 96 gt 98 97 222356 1G 222356 10G 222356 50G 62460 5G F 62460 25G F P4129 100G 438472 5G 438472 25G 455571 5G 455571 100G 455571 500G 60080 25G 60080 100G 452165 100G 452173 100G 452173 500G 452874 25G 452874 100G 452874 500G 452882 25G 452882 100G 452882 500G 452882 2KG 480886 25G 480886 100G 389986 1G 389986 5G 21057 1G F 21057 5G F 553913 5G 553913 25G 3 900 21 500 36 400 15 700 52 100 11 000 5 600 18 400 4 300 12 700 40 500 5 200 13 500 17 600 12 400 36 900 6 300 13 900 37 400 2 700 5 700 14 500 49 400 14 100 39 000 4 300 13 900 7 600 25 000 5 600 18 400 15 16 N A fk QALDHIEFT sigma aldrich com japan Dr Viktor P Balema Sigma Aldrich Materials Science
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109. Soc 2006 128 12048 17 Chen Y S Fulton J L Linehan J C Autrey T J Am Chem Soc 2005 127 3254 18 Bluhm M E Bradley M G Butterick R Ill Kusari U Sneddon L G J Am Chem Soc 2006 128 7748 19 Wang J S Geanangel R A Inorg Chim Acta 1988 148 185 20 Gutowska A Li L Y Shin Y S Wang C M M Li X H S Linehan J C Smith R S Kay B D Schmid B Shaw W Gutowski M Autrey T Angew Chem Int Ed 2005 44 3578 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 7 Bii 3 HJHT 2 10 F3 Borane ammonia complex H3N BH gt 90 287717 1G 4 500 287717 10G 25 500 Bis 1 5 cyclooctadiene dirhodium l dichloride Nor 98 227951 500MG 22 100 Ls 227951 5G 132 400 x c Em Bis 1 5 cyclooctadiene diiridium l dichloride AA A 97 275131 100MG 8 700 KY 275131 500MG 18 600 a CI Bis 1 5 cyclooctadiene nickel 0 20 0 22 6 244988 2G 13 300 ih Ox Ni content p Y N Heterocyclic Carbene Ligands Kit I A set of 5 ligand precursors for Ni catalysts 662232 1KT 44 000 LJ components are listed below 2
110. afsa org fsy decO3 sigfusson pdf 6 http physicsweb org articles world 15 7 10 1 7 http Awww hynor no pdf engelsk hynor presentation pdf 8 http www hynor no english 9 http www hydrogencarsnow com norway hynor project htm 10 http www eere energy gov hydrogenandfuelcells storage current technology html 11 http www hydrogen energy gov annual reviewO6 storage html 12 Dillon A C Jones K M Bekkedahl T A Kiang C H Bethune D S Heben M J Nature 1997 386 377 13 Ye Y Ahn C C Witham C Fultz B Liu J Rinzler A G Colbert D Smith K A Smalley R E Applied Physics Letters 1999 74 2307 14 Bossel et al April 2003 report The Future of the Hydrogen Economy Bright or bleak 15 http www hydrogen energy gov pdfs reviewO6 st 9 cooper pdf 16 http www exxonmobil co uk files pa uk FutureFuels Oct2003 pdf 17 http web mit edu afs athena mit edu org m mecheng fcp about96 20f962 Ocells html KREIRA RCA 5 11 nTBE E Te FO E TS ER Carbazole 9 2 Ethylhexyl carbazole 9 Ethylcarbazole 9 Phenylcarbazole 9 Methylcarbazole 4 4 Bis N carbazolyl 1 1 biphenyl 96 95 C5132 100G 2 500 C5132 250G 5 000 C5132 500G 9 500 97 649511 1G 12 700 649511 5G 42 500 96 5 E16600 5G 1 300 E16600 100G 3 900 E16600 500G 12 700 gt 99 262684 1G 8 200 262684 5G 29 100 99 325325 5G 8 500 97
111. p 97 3 Barnes R G in Hydrogen in Metals IIl Properties and Applications Wipf H Ed Springer Verlag Berlin 1997 p 93 4 Chandra D Reilly J J Chellappa R Journal of Metals OM 2006 58 26 5 MacKenzie K J D Smith M E Multinuclear Solid State NMR of Inorganic Materials Pergamon Amsterdam 2002 6 Bogdanovi B Sandrock G MRS Bulletin 2002 27 712 7 Graetz J Reilly J J J Phys Chem B 2005 109 22181 8 Tarasov V P Bakum S Privalov V 1 Muravlev Yu B Samoilenko A A Russ J Inorg Chem 1996 41 1104 9 Tarasov V P Bakum S I Kuznetsova S F Russ J Inorg Chem 1997 42 694 10 Balema V P Wiench J W Dennis K W Pruski M Pecharsky V K J Alloys Compd 2001 329 108 11 Bogdanovi B Felderhoff M Germann M Hartel M Pommerin A Schuth F Weidenthaler C Zibrowius B J Alloys Compd 2003 350 246 12 Wiench J W Balema V P Pecharsky V K Pruski M J Solid State Chem 2004 177 648 13 Majzoub E H Herberg J L Stumpf R Spangler S Maxwell R S J Alloys Compd 2005 394 265 14 Herberg J L Maxwell R S Majzoub E H J Alloys Compd 2006 417 39 15 Mamatha M Bogdanovi B Felderhoff M Pommerin A Schmidt Ammonia d ND Ammonia N d ND Deuterium hydride D H Deuteriu
112. 1 4 25 C lt 10 bar 25 C 685976 10G 7 300 Ce La Nd Pr Nis Mm La 20 2796 Ce 48 5696 Pr 4 796 Nd 12 2096 Titanium Manganese Alloy TlogeZl 05 V aas Oc 09C Foe Vaf los 1 6 25 C 10 bar 25 C 685941 10G 7 300 TiMn Alloy 5800 sigma aldrich com hydrogen Hy Energy s PCTPro 2000 Gas Sorption Analyzer Most versatile and robust Sieverts Apparatus available PCT Erop D 7x aao E sv coli Ls s e perds e 5 11 ZWEI 3EU e 1 mbar 200 bar PID E OM LabView HyData 13
113. 660124 1G 8 000 660124 5G 26 500 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 25 E des ET 51 HJHT 2 26 H A j Tr A Jb ALDRICH sigma aldrich com japan PCTPro 2000 Dr Karl J Gross Hy Energy LLC
114. CTPro 2000 Ti NaAIH 2 Ti 6 96 160C PCT Ja Ho e M m 4 m i i QUT E A a T QU r pm mm T F yi ri r 3 m a E 1 E 4 m io 1 L PE wt s 2 0 5 2 4 10 17 5 25 mol96 Ti NaAIH 160C COD PCT 4 PCTPro 2000 0 1 u 10 PCTPro 2000 MicroDoser 1 PCI
115. DOE RN 2 gt 1950 Richard Parry Sheldon Shore 3 sS B N H NH BH INH4 BH NH BH
116. Gsial com M H ww MH 9 3 M Mg Ti Zr Nb x 1 2 MgCl 3LiAIH LIMg AIH4 2LiCI 10 3LIAID AlCl gt 4AlD 3LiCl 11 MgH Co gt MgCoH 12 2NaBH SnCl gt 2NaCl Sn 2H B H 13 4 10 EI
117. R S Kay B D Schmid B Shaw W Gutowski M Autrey T Angew Chem Int Ed 2005 44 3578 3 Schlapbach L Topics Appl Phys 1988 63 10 4 Struekens G Bogdanovi B Felderhoff M Sch th F Phys Chem Chem Phys 2006 8 2889 5 Sandrock G State of the Art Review of Hydrogen Storage in Reversible Metal Hydrides for Military Fuel Cell Applications ONR Report DTIC AD A328073 p 10 6 Measurements made at Hy Energy by Karl J Gross on a sample of LaNi 7 Gross K J Chartouni D Fauth F J Alloys Comp 2000 306 203 Note K Gross in situ neutron diffraction measurements Enero ml Pme rrer pee Inc Fi me 4b H A A D TI 686115 1KT 25 300 T LJ PCTPro 2000 VAT AL CAJ ed olcsgsTe TUCU d CNIR S UUVKGRRTIBUA SES d LT HEDER Lanthanum Nickel Alloy LaNi LaNi lt 1 4 25 C lt 2 bar 25 C 685933 10G 7 300 Lanthanum Nickel Alloy LaNi CO 1 4 25 C lt 0 5 bar 25 C 685968 10G 7 300 LaNi sCOo 5 Mischmetal Nickel Alloy MmNi lt
118. Vol 2 No 2 J amp Material Matters x tus Chemistry Chemistry Driving Performance Hydrogen Storage Materials m System Targets for On Board Vehicular H Storage U S DOE Dehydrogenation of Ammonia Borane Metal Borohydrides for H Storage y mm um uu gi Mechanical Processing dnd d cn nn TT Eh storage LE M X X OM XXX Cm x ON OM OLOR ER EN Protective Nanocoatings eA NON NE ON NN RN ON NN gt UN OW X X X X X XXX for Metal Hydrides ODOODOOOOOQOCX CO wx ccc Nc Nc ccc NC Organic Liquid c MOMOOERREKXE RREEREANR Storage of Hydrogen COXDOOOOOOQQCX Jd P M N NM M NM OM OM NON Gas Sorption M LELOELOCOROCO ROO i at at a x e a m p Wy Analysis Tool re Pati or DOR Solid State NMR of JH CR sj Metal Hydrides IOODDODODDOS Hydrogen the clean and safe fuel of the future sigma aldrich com c IGM A A L DARI C F 10 J Material Matters IA UL
119. dride ZrH 2 1 Decomposition temp 600 C 99 208558 100G 13 600 F3 4 800 Decomp to Li NH 350 C 8 900 31 100 Decomp 500 C 5 900 3 100 5 700 10 100 3 900 5 200 4 900 17 700 8 100 22 700 5 300 18 800 5 300 17 100 Moisture sensitive Air moisture sensitive Can be hydrogenated to sigma aldrich com hydrogen HYDRNOL Dr Esmaeel D Naeemi Dr Dan Graham and Barton F Norton Asemblon Inc 3 6 7 dis
120. e T Langmuir 1996 SETS h 12 3038 12 Tang Z Kotov N A Magonov S Ozturk B Nature Materials 2003 2 413 13 Lu Z Prouty M D Quo Z Golub V O dd Kumar C S S R Lvov Y M Langmuir 2005 21 2042 DMR 0508560 HJHT 2 Tel 03 5796 7340 Fax 03 5796 7345 E mail safcjp sial com 22 CY ALDRICH com japan sigma aldrich ERU EAN ACSOIGREIIBUBXRIBID TR Ammonia Lithium amide Sodium amide Aluminum nitride Calcium nitride Lithium nitride Magnesium nitride NH LiNH NaNH AIN CaN LiaN MgsN 17 6 8 7 5 1 moisture sensitive moisture sensitive LiNH and LiNH Air moisture sensitive 96 99 99 95 95 95 gt 90 gt 98 95 95 gt 99 5 294993 170G 213217 5G 213217 100G 213217 500G 71260 100G 432504 25G 432504 100G 432504 500G 208329 50G 208329 250G
121. ello M Applied Physics Tag U C Si HAEl 3 2 nm AEEY A Materials Science and Processing 2001 72 143 5 Gross K G CEP 12 Hydrogen Workshop April 14 15 2003 http gcep stanford edu events workshops_hydrogen_04_03 html accessed Feb 23 2007 6 Bogdanovi ie hie pr m a lcm B Schwickardi M Journal of Alloys and Compounds 1997 253 1 PAH f 6b 7 Lvov Y Ariga K Onda M Ichinose I Kunitake T Colloids and PSS PAH B X 6a tHL UT KARMOK on A Physicochemical and Engineering Aspects 1999 146 337 N ong m TE 8 Decher G Science 1997 227 1232 9 Kuila D Tien M Lvov Y WAEI a in ede e uu Fut ade D McShane M Aithal R Singh S Potluri A Kaul S Patel D Krishna G Proceedings of SPIE The International Society for Optical Engineering 2004 5593 267 10 Kamineni V Lvov Y M Dobbins T A Langmuir augi EE YL z Submitted 11 Lvov Y Ariga K Ichinose I Kunitak
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123. ino Acid Reagents 3 C X Bond Formation 3 Organic Bases 3 Fluorous Synthesis Derivatives 3 Organosilicon Non halogen s gon 3 Inorganic Bases 3 Supported Synthesis 3 Monosaccharides 3 Organotin 3 Oxidation Inorganic Salts Nucleosi rganolithium R tion 3 Nucleosides 2 Organolithiu Es Reductio NN 3 Dehydrating Reagents 3 Chiral Building Blocks 3 Organoaluminum 3 Protection and Derivatization 3 Compressed and 3 Others 3 Radical Chemistry Liquefied Gases 3 Phase Transfer Catalysts 3 Chelation Complexation Compounds 3 Chiral Catalysts Ligands 3 All Metals 3 Aluminum 3 Rhenium 3 Ammonium and Reagents 3 Palladium 3 Boron 3 Tin O Choline 3 Chiral Auxiliaries 3 Ruthenium O Chromium 3 Tungsten C3 Imidazolium 3 Chiral Building Blocks O Rhodium 3 Cobalt Q Vanadium 3 Phosphonium 3 Chiral Resolution Reagents 3 Nickel Q Iridium Q Zirconium 3 Pyrazolium 3 Platinum 3 Iron 3 Phosphorus Compounds 3 Pyridinium 3 Titanium 3 Manganese O NHC Ligands 3 Pyrrolidinium 3 Gold 3 Molydenum 3 Porphyrins 3 Sulfonium 3 Silver 3 Osmium 3 Other Ligands 3 Copper 3 Rare Earth Metals O Metal Scavengers 3 Zinc 2008 2 1
124. m D Deuterium D Lithium aluminum deuteride LiAID Lithium deuteride LiD Lithium borodeuteride LiBD Sodium borodeuteride NaBD Sodium borohydride 11B Na BH Trimethyl borate B UB OCHL Tributy borate B 10B OCH3 sigma aldrich com hydrogen EEF W Schuth F Weidenthaler C J Alloys Compd 2006 407 78 16 Zogal O J Stalinski B Idziak S Z Physk Chem N F 1985 145 167 17 Hwang S J Bowman R C Graetz J Reilly J J In Wang J C F Tumas W Rougier A Heben M J Akiba E Eds Hydrogen Storage Materials Mater Res Soc Symp Proc Warrendale PA 2006 Vol 927E 0927 EE03 03 18 Hwang S J Bowman Jr R C Graetz J Reilly J J Langley W Jensen C M J Alloys Compd 2007 in press 19 Frydman L Harwood J S J Am Chem Soc 1995 117 5367 20 Amoureux J P Fernandez C Solid State NMR 1998 10 211 21 Amoureus J P Pruski M In Grant D M Harris R K Eds Encyclopedia of NMR John Wiley amp Sons Chichester UK 2002 9 226 22 Adolp
125. n R C Hwang S J Material 20 Mamathab M Bogdanovie B Felderhoff M Pommerin A Schmidt Matters 2007 Vol 2 No 2 29 6 Balema V P Balema L Phys Chem W Sch th F Weidenthaler F J Alloys Compds 2006 407 78 21 Chem Phys 2005 7 1310 7 Minkel J R New Scientist 2002 174 18 Brinks H W et al J Phys Chem 2006 110 25833 22 Chen J J Mater 8 Dymova T N Aleksandrov D P Konoplev V N Silina T Kuznetsov Sci 2001 36 5829 23 Balema V P Wiench J W Dennis K W Pruski N T Russian J Coord Chem 1993 19 491 9 Chaudhuri S Graetz J M Pecharsky V K J Am Chem Soc 2002 124 6244 24 Balema V P m Ignatov A Reilly J J Muckerman J T J Am Chem Soc 2006 128 Wiench J W Dennis K W Pruski M Pecharsky V K Chem Commun En d an 1 1404 10 Bellosta von Colbe J M Felderhoff M Bogdanovi B 2002 1606 25 Boldyrev V V Reactivity of Solids Past Present and Future ag Sch th F Weidenthaler C Chem Commun 2005 4732 11 Kojima Y IUPAC and Blackwell Science Ltd Oxford 1996 26 Takacs L Progr LIN Kawai T Haga T Matsumoto M Koiwai A J Alloys Compas 2007 Materials Sci 2002 47 355 27 Maurice D R Courtney T H Metall BR a B On the web 7 February 2007 12 Hout J Boily S Gunther V Schulz R J Trans A 1990 21 286 28 Koch C C Int J Mechanochem Mech
126. y YJ 1 2 5 8 kg 30 kJ 400 kW 80 kW 0 02 g s kW DOE 1 6 gs PEM 80
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