TADIRAN 社製電池/取扱説明書
Contents
1. 1 2 85 30C 1 3 1 42. FUSE gt lt DIODE A CELLS A DIODE gt gt PP 1 4 0 10 1 2AA 2 3AA AA C D DD 10 280
3. 140C 80 280C 10 85C 100 120 Tv 2 2 1 2 1 2 2 2 2
4. cmos CMOS TSV gt RAM eu RAM A A A LITHIUM LITHIUM _ BATTERY _ BATTERY A 1 2 TADIRAN BATTERIES D MSDS No T 36 05 Revision B MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer Name Tadiran US office address 2001 Marcus Avenue Suite 125E Lake Success NY 11040 Emergency Telephone No CHEMTREC 1 800 424 9300 Tel for information 1 516 621 4980 Products Name Primary non rechargeable Lithium metal Thionyl Chloride Li SOCb cells and batteries Non rechargeable Cells include the models of TL TLH and TLL 3 6V series This MSDS covers the the above models 2100 2134 2135 2137 2150 2155 2186 2200 2300 2450 4902 4903 4920 4930 4934 4935 4937 4940 4951 4955 4986 5101 5104 5114 5134 5135 5137 5151 5155 5186 5233 5242 5276 5293 5315 5902 5903 5920 5930 5937 5940 and 5955 with all their finishing versions and batteries assembled from them denoted by followed up by letters or digits SECTION 2 COMPOSITION INFORMATION ON INGREDIENTS Ingredient Name CAS ACGIH TLV OHSA CHIP PEL Classifica
5. Lithium oxide LizO 3 Electrolyte with water Hydrogen Chloride HCl and SO T 36 05 SOCI2 general woIS Rev B 4 7 Revised 21 04 2010 TADIRAN BATTERIES pD DECOMPOSITION TEMPERATURE F NA HAZARDOUS POLYMERIZATION May Occur Will Not Occur X _ CONDITIONS TO AVOID Avoid mechanical abuse and electrical abuse such as short circuiting overcharge over discharge voltage reversal and heating SECTION 11 TOXICOLOGICAL INFORMATION THRESHOLD LIMIT VALUE TLV AND SOURCE NA HEALTH HAZARD ACUTE AND CHRONIC Inhalation skin contact eye contact and ingestion are not likely by exposure to sealed battery Inhalation skin contact and eye contact are possible when the battery is opened Exposure to internal contents the corrosive fumes will be very irritating to skin eyes and mucous membranes Overexposure can cause symptoms of non fibrotic lung injury and membrane irritation Carcinogenicity NTP No Carcinogenicity IARC No Carcinogenicity OSHA No Explanation of Carcinogenicity No ingredient of a concentration of 0 1 or greater is listed as a carcinogen or suspected carcinogen SIGNS AND SYMPTOMS OF OVEREXPOSURE Exposure to leaking electrolyte from ruptured or leaking battery can cause Inhalation Can cause burns and irritation of the respiratory system coughing wheezing and shortness of breath Eyes Redness tearing burns The electrolyte is corrosive to all ocular tissues Skin The e
6. CIAL FIRE FIGHTING PROCEDURES Wear self contained breathing apparatus to avoid breathing of irritant fumes NIOSH approved SCBA amp full protective equipment Wear protective clothing and equipment to prevent body contact with electrolyte solution Fire may be fought but only from safe fire fighting distance Evacuate all persons from immediate area of fire UNUSUAL EXPLOSION AND FIRE EXPLOSION Battery may explode when subject to excessive heat above 150 C recharged over discharged discharge below OV punctured and crushed During thermal decomposition generation of chlorine Cb hydrogen chloride HCI and sulfur dioxide SO2 can be formed SECTION 6 SPILL OR LEAKAGE PROCEDURES T 36 05 SOCI2 general wolS Rev B 2 7 Revised 21 04 2010 TADIRAN BATTERIES D PROCEDURES TO CONTAIN AND CLEAN UP LEAKS OR SPILLS The material contained within the battery would only be released under abusive conditions In the event of battery rapture and leakage contain the spill while wearing proper protective clothing and ventilate the area Than cover with sodium carbonate NazCO3 or 1 1 mixture of soda ash and slaked lime Keep away from water rain and snow Placed in approved container after cooling if necessary and disposed according to the local regulations NEUTRALIZING AGENTS Sodium carbonate NazCO3 or 1 1 mixture of soda ash and slaked lime WASTE DISPOSAL METHOD Product decomposed by water must be neutral
7. TADIRAN COM MSDS 1 1 1 MSDS MATERIAL SAFETY DATA SHEET
8. is broken or leaked the main hazard is the electrolyte The electrolyte is mainly solution of Lithium chloride LiCl and aluminum chloride AlCl in Thionyl chloride SOCb Fires may be fought but only from safe fire fighting distance evacuate all persons from immediate area of fire Prevent heating of the battery charging the battery discharge to predetermined limit do not crush disassemble incinerate or short circuit SECTION 9 PHYSICAL DATA BOILING POINT 760 mm Hg NA unless individual components exposed VAPOR PRESSURE mm Hg 25 C NA unless individual components exposed VAPOR DENSITY air 1 NA unless individual components exposed DENSITY gr cc gt 1 gr cc VOLATILE BY VOLUME NA EVAPORATION RATE butyl acetate 1 NA unless individual components exposed PHYSICAL STATE Solid SOLUBILITY IN WATER by weight NA unless individual components exposed PH NA unless individual components exposed APPEARANCE Geometric Solid Object ODOR If leaking gives off pungent corrosive odor SECTION 10 STABILITY AND REACTIVITY STABLE OR NOT STABLE Stable INCOMPATIBILITY MATERIAL TO AVOID Strong mineral acids water and alkali solutions HAZARDOUS 1 Reaction of lithium with water Hydrogen H2 Lithium DECOMPOSITION _ hydroxide LiOH PRODUCTS 2 Thermal decomposition over 150 C Sulfur oxides SO2 SO3 Sulfur chlorides SCl2 S2Cl2 Chlorine Cb
9. is not exposed Flammabili Reactivity Health W AJ SECTION 16 OTHER INFORMATION DISCLAIMER The information and the recommendations set forth are made in good faith and believed to be accurate at the date of preparation The present file refers to normal use of the product in question Tadiran Batteries makes no warranty expressed or implied Assembly of battery packs The design and assembly of battery packs require special skills expertise and experience Therefore it is not recommended that the end user will attempt to self T 36 05 SOCI2 general wolS Rev B 6 7 Revised 21 04 2010 TADIRAN BATTERIES D assemble battey packs It is preferable that any battery using lithium cells will be assembled by TADIRAN to ensure proper battery design and construction A full assembly service is available from TADIRAN who can be contact for further information If for any reason this is not possible TADIRAN can review the pack design in confidential to ensure that the design is safe and capable of meeting the stated performance requirements T 36 05 SOCI2 general woIS Rev B 7 7 Revised 21 04 2010
10. ized if sufficiently diluted it may be added to waste water if it is sufficiently diluted PRECAUTIONS IN HANDLING AND STORAGE avoid short circuiting over charging and heating to high temperatures Store the batteries in dry and cool area and keep container dry and tightly closed in well ventilated area Store cells away from food and drink OTHER PRECAUTIONS Never attempt to disassemble machine or otherwise modify batteries or injury may result SECTION 7 HANDLING AND STORAGE The batteries should not be opened destroyed or incinerate since they may leak or rupture and release to the environment the ingredients that they normally contained in the hermetically sealed container HANDLING Do not short circuit terminals or expose to temperatures above the temperature rating of the battery over charge the battery forced over discharge voltage below 0 0V throw to fire Do not crush or puncture the battery or immerse in liquids STORAGE is preferably done in cool below 30 C dry and ventilated area which is subject to little temperature change Do not place the battery near heating equipment nor expose to direct sunlight for long periods Elevated temperatures can result in shortened battery life and degrade performance Keep batteries in original packaging until use and do not jumble them Do not store batteries in high humidity environment for long periods OTHER cells and batteries are not rechargeable batte
11. lectrolyte is corrosive and causes skin irritation and burns Ingestion The electrolyte solution causes tissue damage to throat and gastro respiratory track MEDICAL CONDITION AGGRAVATED BY EXPOSURE Preexisting skin asthma and respiratory diseases are generally aggravated by exposure to liquid electrolyte vapors or liquid For further information refer to section 4 SECTION 12 ECOLOGICAL INFORMATION 1 When properly used or disposed the battery does not present environmental hazard 2 Cells do not contain mercury cadmium or lead 3 Do not let internal components enter marine environment Avoid release to waterways wastewater or ground water SECTION 13 DISPOSAL CONSIDERATIONS 1 Dispose in accordance with the applicable regulations in country and state 2 Disposal should be performed by permitted professional disposal firms knowledgeable in Federal State or Local requirements of hazardous waste treatment and hazardous waste transportation 3 Incineration should never be performed by battery users but eventually by trained professional in authorized facility with proper gas and fume treatment 4 Battery recycling should be done in authorized facility T 36 05 SOCI2 general wolS Rev B 5 7 Revised 21 04 2010 TADIRAN BATTERIES pD SECTION 14 TRANSPORTATION SHIPPING Lithium metal cells and batteries are considered as Dangerous Goods e g UN 3090 for cells and batteries and UN 3091 for cells or bat
12. n case of battery rupture explosion or major leakage evacuate personnel from contaminated area and provide good ventilation to clear out corrosive fumes gases or the pungent odor Seek immediate medical attention Eyes First rinse with plenty of water for 15 minutes remove contact lenses if easily possible and then seek medical attention Skin Remove contaminated clothes and rinse skin with plenty of water or shower for 15 min Refer to medical attention Inhalation Remove to fresh air rest and half upright position use artificial respiration if needed and refer to medical attention Ingestion rinse mouth DO NOT induce vomiting give plenty of water to drink and refer to medical attention SECTION 5 FIRE FIGHTING MEASURES FLASH POINT NA LOWER LEL NA FLAMMABLE LIMIT IN AIR NA UPPER LEL NA EXTINGUISHING MEDIA 1 Lith X Class D extinguishing media is the only effective on fires involving a few lithium batteries If the cells are directly involved in a fire DO NOT USE WATER SAND CO2 HALON and DRY POWDER OR SODA ASH EXTINGUISHERS 2 If the fire is in adjacent area and the cells that are either packed in their original containers or unpacked the fire can be fought based on fueling material e g paper and plastic products In these cases the use of copious amounts of cold water is effective extinguishing media Storage area may also employ sprinkler system with cold water AUTO IGNITION NA SPE
13. ries and should not be charged Applying pressure and deforming the battery may lead to disassembly followed by eye skin and throat irritation Follow manufacturer recommendations regarding maximum recommended current and operating temperature range SECTION 8 EXPOSURE CONTROLS amp PERSONAL PROTECTION GENERAL The following safety measures are not necessary in normal use They need only be applied if there is a risk that in use or handling the recommendations as outlined in Section 3 have not been followed T 36 05 SOCI2 general wolS Rev B 3 7 Revised 21 04 2010 TADIRAN BATTERIES pD RESPIRATORY PROTECTION In case of abuse or leak of liquid or fumes use NIOSH approved Acid Gas Filter Mask or Self Contained Breathing Apparatus VENTILATION In case of abuse use adequate mechanical ventilation local exhaust for battery that vents gas or fumes PROTECTIVE GLOVES In case of spill use PVC or Nitrile gloves of 15 mils 0 015 inch or thicker EYE PROTECTION Use ANSI approved chemical worker safety goggles or face shield OTHER PROTECTIVE EQUIPMENT In case needed chemical resistance clothing is recommended along with eye wash station and safety shower should be available meeting ANSI design criteria WORK HYGIENIC PRACTICES Use good hygiene practice Wash hands after use and before drinking eating or smoking Launder contaminated cloth before reuse SUPPLEMENTARY SAFETY AND HEALTH DATA If the battery
14. teries in equipment or with equipment The UN Recommendations on Transport of Dangerous Goods Model Regulations The UN Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria Lithium batteries Part III Section 38 3 Worldwide besides the United State Cells and Batteries must be packed accordance with Special Provisions of the applicable code e g IATA ICAO IMO ADR and the UN Model Regulations Within the US the US DOT CFR 49 regulations Parts 171 172 173 and 175 are governing the transportation of lithium cells and batteries The requirements for the different transportation conditions e g Air Sea with and within equipment and for disposal are defined in part 173 185 Lithium cells and batteries Identification and labeling in compliance with the product drawing should include the battery title nominal voltage lot number and warning SECTION 15 REGULATORY INFORMATION 1 All the cells and batteries are defined as articles and thus are exempt from the requirements of the Hazard Communication Standard 2 The internal component Thionyl chloride is hazardous under the criteria of the Federal OHSA Hazard Communication Standard 29 CFR 1920 1200 3 NFPA rating Lithium batteries are not included in the NFPA material list Below is the NFPA rating for lithium metal Lithium metal is an internal component enclosed by hermetically sealed metallic can Under normal application
15. tion Lithium Metal Li 7439 93 2 lt 5 Not Established None F R14 15 C R34 R 14 15 34 S 1 2 8 43 45 Thionyl Chloride SOCb 7719 09 7 lt 47 1 ppm 5 mg m R 14 20 22 29 5 mg M 35 S 1 2 26 36 37 39 45 Carbon C 1333 86 4 lt 6 3 5 mg m 3 5 mg m None known Aluminum Chloride AICl 7446 70 0 lt 5 2 mg m Al R 34 salt soluble S 1 2 7 8 28 45 Lithium Chloride LiCl 7447 41 8 lt 2 Not Established Glass lt 1 Not Established PVC 9002 86 2 lt 1 Not Established PTFE 9002 84 0 lt 1 Not Established SECTION 3 HAZARD IDENTIFICATION The lithium Thionyl chloride batteries described in this MSDS are hermetically sealed units which are not hazardous when used according to the recommendations of the manufacturer Under normal condition of use of the batteries the electrode materials and the liquid electrolyte they contained are non reactive provided the battery integrity is T 36 05 SOCI2 general woIS Rev B 1 7 Revised 21 04 2010 TADIRAN BATTERIES D maintained Risk of exposure exists only in case of mechanical electrical or thermal abuse Thus the batteries should not short circuit recharge puncture incinerate crush immerse in water force discharge or expose to temperatures above the temperature range of the cell or battery In these cases there is risk of fire or explosion SECTION 4 FIRST AID MEASURES I
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