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Sharp FO-4400 MSDS
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1. Preparation community provisions Waste may be disposed or incinerated under conditions which meet all federal state and local environmental regulations Contaminated Packaging Waste may be disposed or incinerated under conditions which meet all federal state and local SHARP Date Revised Apr 8 2008 Date Issued May 28 1998 MATERIAL SAFETY DATA SHEET 4 4 MSDS No B 1020 environmental regulations Precautions Do not throw the toner cartridge or toner into an open flame The hot toner may scatter and cause burns or other damage Section 14 Transport Information Special Precautions None Information on Code and Classifications According to International Regulations UN Classification None Section 15 Regulatory Information US Information Information on the label Not required TSCA Toxic Substances Control Act All chemical substances in this product comply with all applicable rules or order under TSCA SARA Superfund Amendments and Reauthorization Act Title III 302 Extreme Hazardous Substance None 311 312 Hazard Categories None 313 Reportable Ingredients None California Proposition 65 This product contains no chemical substances subject to California Proposition 65 EU Information Information on the label 1999 45 EC and 67 548 EEC Symbol amp Indication Not required R phrase Not required S phrase Not required 76 769 EEC All chemical substances in this product comply with all applicable r
2. Entry Eye contact inhalation ingestion Information Inhalation If symptoms are experienced remove source of contamination or move victim to fresh air and obtain medical advice SHARP Date Revised Apr 8 2008 Date Issued May 28 1998 MATERIAL SAFETY DATA SHEET 2 4 MSDS No B 1020 Skin Contact Flush with gently flowing water preferably lukewarm and soap for 15 minutes or until particle is removed If irritation does occur obtain medical advice Eye Contact Do not allow victim to rub eye s Flush with gently flowing water preferably lukewarm for 15 minutes or until particle is removed Have victim look right and left and then up and down If irritation does occur obtain medical attention DO NOT attempt to manually remove anything stuck to the eye s Ingestion If irritation or discomfort occurs obtain medical attention immediately Note to Physician None Section 5 Fire Fighting Measures Suitable Extinguishing Media CO2 water spray foam and dry chemical Extinguishing Media to Avoid Full water jet Special Firefighting Procedures None Fire and Explosion Hazards If dispersed in air like most finely divided organic powders may form an explosive mixture Protection of Firefighters Use self contained breathing apparatus SCBA Section 6 Accidental Release Measures Personal Precautions None Environmental Precautions None Methods for Cleaning Up Wipe off with paper or cloth DO NOT u
3. No 215 609 9 for Carbon black Apr 23 2003 Change Section 8 DFG MAK GER 6mg m3 4mg m3 SHARP Date Revised Apr 8 2008 Date Issued May 28 1998 MATERIAL SAFETY DATA SHEET 5 4 MSDS No B 1020 Oct 7 2002 Addition Contact information Change Section 15 EU information 88 379 EEC 1999 45 EC July 22 2002 Addition Product Name FO 44ND FO 50ND
4. SHARP Date Revised Apr 8 2008 Date Issued May 28 1998 MATERIAL SAFETY DATA SHEET 1 4 MSDS No B 1020 Section 1 Product and Company Identification Product Name Toner Cartridge of FO 47ND FO 47DC FO 47DCCN FO 44ND FO 50ND FO 59DC DUNT 455BSCZZ Supplier Identification Sharp Corporation 22 22 Nagaike cho Abeno ku Osaka Japan Local suppliers are listed below Please contact the nearest supplier for additional information Area Country Name and Telephone Number North U S A Sharp Electronics Corporation America Telephone number for information 1 800 237 4277 Emergency telephone number 1 800 255 3924 Canada Sharp Electronics of Canada Ltd Telephone number for information 905 890 2100 Emergency telephone number 1 800 424 9300 Oceania Australia AUSTRALIA SHARP CORPORATION OF AUSTRALIA PTY LTD Phone 02 9830 4600 1800 807 820 New Zealand NEW ZEALAND SHARP CORPORATION OF NEW ZEALAND LTD Phone 09 634 2059 Europe Germany Sharp Electronics Europe GMBH Sonninstrasse 3 20097 Hamburg Telephone number to access MSDS 040 2376 2185 For more information 040 2376 2613 United Sharp Electronics U K Ltd Kingdom Telephone number for information 01923 474013 France Sharp Electronics France S A Telephone number for information 01 49 90 34 00 Austria Sharp Electronics GMBH Telephone number for information 01 727 19 0 Ita
5. able pH Not applicable SHARP MATERIAL SAFETY DATA SHEET 3 4 No B 1020 Partition Coefficient n Octanol Water Not applicable Based on data for other products with similar ingredients Date Revised Apr 8 2008 Date Issued May 28 1998 MSDS Section 10 Stability and Reactivity Stability Stable X Unstable Hazardous Reactions Dust explosion like most finely divided organic powders Conditions to avoid Electric discharge throwing into fire Materials to Avoid Oxidizing materials Hazardous Decomposition Products CO CO2 Section 11 Toxicological Information Health Effects from Exposure No symptoms expected with intended use Toxicological Data Acute Toxicity Inhalation LC50 mg l gt 0 74 Rat 4hour This was the highest attainable concentration Ingestion oral LD50 mg kg gt 5000 Rat Dermal LD50 mg kg gt 2000 Rat Eye irritation Non irritant Rabbit Skin irritation Non irritant Rabbit Skin sensitizer No data available Mutagenicity Negative AMES test Based on data for other products with similar ingredients Local Effects see Chronic Toxicity or Long term Toxicity Chronic Toxicity or Long Term Toxicity Prolonged inhalation of excessive dust may cause lung damage It is attributed to lung overloading a generic response to excessive amounts of any dust retained in the lungs for a prolonged interval Use of this product as intended does
6. ly Sharp Electronics Italy S P A Telephone number for information 02895951 Spain Sharp Electronics Espana S A Telephone number for information 93 581 97 00 Netherlands Sharp Electronics Benelux B V Telephone number for information 30 6359500 Sweden Sharp Electronics Nordic AB Telephone number for information 08 634 36 00 Middle U A E Sharp Middle East FZE East P O Box 17115 Jebel Ali Dubai Telephone number for information 04 815311 Section 2 Ingredients Ingredients Cas No Proportion OSHAZ Tables ACGIH TLV IARC DFG MAK GER Other Limits Polyester resin Trade Secret gt 90 Trade secret No 361615 5042 P in New Jersey Carbon black 1333 86 4 1 5 EEC No 215 609 9 Polyolefin wax 9003 07 0 1 5 Organic pigment Trade Secret 1 5 Trade secret No 361615 5025 P in New Jersey 3 5mg m3 3 5mg m3 2B Ill 3B TWA Austl 3 mg m Section 3 Hazardous Identification Classification Not classified as dangerous 1999 45 EC Most Important Hazards and Effects of the Products For Human Health This toner is not classified as a human carcinogen No symptoms expected with intended use For the Environment No data are available on the adverse effects of this product on the environment For others None Specific hazards Dust explosion like most finely divided organic powders Section 4 First Aid Measures Symptoms of Overexposure No symptoms expected with intended use Routes of
7. not result in inhalation of excessive dust In a study in rats by chronic inhalation exposure to a typical toner a mild to moderate degree of lung fibrosis was observed in 92 of rats in the high concentration 16mg m3 exposure group and a minimal to mild degree of fibrosis was noted in 22 of the animals in the middle 4mg m exposure group But no pulmonary change was reported in the lowest 1mg m exposure group the most relevant level to potential human exposures Carcinogenicity IARC Monographs Not listed NTP USA Not listed OSHA Regulated USA Not listed In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen possible human carcinogen This evaluation is given to Carbon Black for which there is inadequate human evidence but sufficient animal evidence The latter is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung Studies performed in animal models other than rats have not demonstrated an association between carbon black and lung tumors Moreover a two year cancer bioassay using a typical toner preparation containing carbon black demonstrated no association between toner exposure and tumor development in rats Section 12 Ecological Information No data are available on the adverse effects of this material on the environment Section 13 Disposal Consideration Appropriate Methods of Disposal
8. se vacuum cleaner when a large amount is released It like most finely divided organic powders may create a dust explosion Section 7 Handling and Storage Handling Technical Measures None Precautions None Safe Handling Advice Try not to disperse the particles Storage Technical Measures None Storage Conditions Keep container closed Store in a cool and dry place Keep out of reach of children Incompatible Products None Section 8 Exposure Control Personal Protection Engineering Measures Ventilation None required with intended use Control Parameters As total dust OSHA PEL USA 15mg m3 ACGIH TLV USA 10mg m3 DFG MAK GER 4mg m3 Worksafe TWA Austl 10mg m3 Personal Protective Equipment None required when used as intended in Sharp equipment For use other than normal customer operating procedures such as in bulk toner processing facilities goggles and respirators may be required Hygiene Measures Wash hands after handling Section 9 Physical and Chemical Properties Appearance Physical State Solid Form Powder Color Black Odor Faint odor Explosion Properties No data available Particle Size um 5 15 Density g cms 1 2 bulk density 0 5 Boiling Point Not applicable Solubility in water Negligible Melting Point C No data available Oxidizing Properties No data available Softening Point C 120 130 Ignition Temperature C 450 Flash Point Not applicable Vapor Pressure Not applic
9. ules or order under 76 769 EEC Article 14 2 1 of Directive 1999 45 EC is not applicable to this product Section 16 Other Information NFPA Hazard Rating The National Fire Protection Agency USA Health 1 Flammability 1 Reactivity 0 HMIS Rating The National Paint and Coating Association USA Health 1 Flammability 1 Reactivity 0 Recommended Uses Toner for Electrophotographic Equipment Restrictions This information relates only to the specific material designated as supplied by the manufacturer This information is supplied to us by the manufacturer and Sharp offers no warranties as to its accuracy and accepts no responsibilities for any typographical errors which may appear on these sheets It is the responsibility of the user to determine the suitability of this product for each particular use Literature References ANSI Z2400 1 1993 ISO 11014 1 Commission Directive 91 155 EEC IARC 1996 IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans Vol 65 Printing Process and Printing Inks Carbon Black and Some Nitro Compounds Lyon pp 149 261 H Muhle B Bellmann O Creutzenberg C Dasenbrock H Ernst R Kilpper J C MacKenzie P Morrow U Mohr S Takenaka and R Mermelstein 1991 Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats Fundamental and Applied Toxicology 17 pp 280 299 Rivision Record Apr 8 2008 Periodical review Apr 23 2003 Addition Section 2 EEC
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