Kidde 19915 Data Sheet
Contents
1. Fire Extinguishing Agent Pressurized r United Technologies and Non pressurized COMPOSITION INFORMATION ON INGREDIENTS This product is a mixture Component CAS Number Concentration Potassium Bicarbonate 298 14 6 75 85 Calcium Carbonate 471 34 1 5 15 Mica 12001 26 2 lt 5 Clay 1332 58 7 lt 5 Amorphous Silica 7631 86 9 lt 5 Dye NA lt 1 Note Pressurized product uses nitrogen carbon dioxide or compressed air as the expellant FIRST AID MEASURES Description of necessary first aid measures Eyes Immediately flood the eye with plenty of water for at least 15 minutes holding the eye open Obtain medical attention if soreness or redness persists Skin Wash skin thoroughly with soap and water Obtain medical attention if irritation persists Ingestion Dilute by drinking large quantities of water and obtain medical attention Inhalation Move victim to fresh air Obtain medical attention immediately for any breathing difficulty Most important symptoms effects acute and delayed Aside from the information found under Description of necessary first aid measures above and Indication of immediate medical attention and special treatment needed no additional symptoms and effects are anticipated Indication of immediate medical attention and special treatment needed Notes to Physicians Treat symptomatically FIRE FIGHTING MEASURES Suitable Extinguishing Media This preparation is used as an extin2. g Kidde J United Technologies HAZARD IDENTIFICATION Precautionary Statements Prevention None Response None Storage Protect from sunlight Store in well ventilated place Disposal None GHS Classification Non pressurized Hazard Classification SAFETY DATA SHEET Purple K Dry Chemical Fire Extinguishing Agent Pressurized and Non pressurized This product is classified as not hazardous in accordance with the Globally Harmonized System of Classification and Labelling GHS Label Elements Hazard Symbols None Signal Word None Hazard Statements None Precautionary Statements Prevention None Response None Storage None Disposal None Other Hazards Calcium carbonate and mica may contain small quantities of quartz crystalline silica as an impurity Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling lung disease known as silicosis IARC found limited evidence for pulmonary carcinogenicity of crystalline silica in humans Specific Concentration Limits The values listed below represent the percentages of ingredients of unknown toxicity Acute oral toxicity Acute dermal toxicity Acute inhalation toxicity Acute aquatic toxicity Revision Date April 10 2015 lt 10 lt 10 lt 10 lt 10 Page 2 of 10 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical
3. 0 F as vapor Nitrogen 0 1144 lb ft Carbon dioxide gas density Revision Date April 10 2015 Page 5 of 10 9 10 11 a g Kidde J United Technologies SAFETY DATA SHEET Purple K Dry Chemical Fire Extinguishing Agent Pressurized and Non pressurized PHYSICAL AND CHEMICAL PROPERTIES Boiling Range Point C F Melting Point C F Flash Point PMCC C F Vapor Pressure Evaporation Rate BuAc 1 Solubility in Water Vapor Density Air 1 VOC g l VOC Partition coefficient n octanol water Viscosity Auto ignition Temperature Decomposition Temperature Upper explosive limit Lower explosive limit Flammability solid gas STABILITY AND REACTIVITY Reactivity 196 C 321 F Nitrogen 78 5 C 109 3 F Carbon Dioxide No data available Not flammable 838 psig 70 F and 1 atmosphere Carbon Dioxide No data available No data available Not applicable None None No data available Not applicable No data available No data available Not explosive Not explosive Not flammable Pressurized containers may rupture or explode if exposed to heat Chemical Stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to Avoid Exposure to direct sunlight contact with incompatible materials Incompatible Materials Strong oxidizing agents strong acids NaK alloy NH4H2P04 alkali or a
4. THER INFORMATION NFPA Ratings NFPA Code for Health 1 NFPA Code for Flammability 0 NFPA Code for Reactivity 0 NFPA Code for Special Hazards None HMIS Ratings HMIS Code for Health 1 HMIS Code for Flammability 0 HMIS Code for Physical Hazard 0 HMIS Code for Personal Protection See Section 8 Chronic Legend ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstracts Service Number EC50 Effect Concentration 50 IARC International Agency for Research on Cancer LC50 Lethal Concentration 50 LD50 Lethal Dose 50 N A Denotes no applicable information found or available OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TSCA Toxic Substance Control Act Revision Date April 10 2015 Replaces February 9 2015 Changes made Updated to GHS Classification Revision Date April 10 2015 Page 9 of 10 16 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical Fire Extinguishing Agent Pressurized r United Technologies and Non pressurized OTHER INFORMATION Information Source and References This SDS is prepared by Hazard Communication Specialists based on information provided by internal company references Prepared By EnviroNet LLC The information and recommendations presented in this SDS are based on sources believed to be accurate Kidde Residential amp Comm
5. entrations can cause dizziness shortness of breath unconsciousness or asphyxiation Specific Target Organ Toxicity STOT repeat exposure Potassium Bicarbonate Available data indicates this component is not expected to cause target organ effects after repeat exposure Calcium Carbonate Available data indicates this component is not expected to cause target organ effects after repeat exposure Serious Eye damage Irritation Potassium Bicarbonate Not irritating rabbit Calcium Carbonate Not irritating rabbit Mica Not irritating rabbit Skin Corrosion Irritation Potassium Bicarbonate Not irritating rabbit Calcium Carbonate Not irritating rabbit Mica Not irritating rabbit Respiratory or Skin Sensitization Potassium Bicarbonate Not a dermal sensitizer in guinea pig test Calcium Carbonate Non sensitizing to skin in Mouse local lymph node assay Carcinogenicity Calcium carbonate and mica may contain small quantities of quartz crystalline silica as an impurity Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling lung disease known as silicosis IARC has classified Silica Dust Crystalline in the form of quartz or cristobalite as 1 carcinogenic to humans Revision Date April 10 2015 Page 7 of 10 11 12 13 14 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical Fire Extinguishi
6. ercial assumes no liability for the accuracy or completeness of this information It is the user s responsibility to determine the suitability of the material for their particular purposes In particular we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY EXPRESS OR IMPLIED with respect to such information and we assume no liability resulting from its use Users should ensure that any use or disposal of the material is in accordance with applicable Federal State and local laws and regulations Revision Date April 10 2015 Page 10 of 10
7. gg g Kidde J United Technologies 1 IDENTIFICATION Product Name Other Names Recommended use of the chemical and restrictions on use Identified uses Restrictions on use Company Identification Customer Information Number Emergency Telephone Number CHEMTREC Number Issue Date Supersedes Date SAFETY DATA SHEET Purple K Dry Chemical Fire Extinguishing Agent Pressurized and Non pressurized Purple K Dry Chemical Fire Extinguishing Agent Pressurized and Non pressurized Potassium Bicarbonate PK PKP Fire Extinguishing Agent Consult applicable fire protection codes Kidde Residential amp Commercial 1016 Corporate Park Drive Mebane NC 27302 USA 919 563 5911 919 304 8200 800 424 9300 703 527 3887 International April 10 2015 February 9 2015 Safety Data Sheet prepared in accordance with OSHA s Hazard Communication Standard 29 CFR 1910 1200 and the Globally Harmonized System of Classification and Labelling of Chemicals GHS HAZARD IDENTIFICATION This SDS covers the product listed above as sold in pressurized and non pressurized containers GHS classifications for both forms are listed below GHS Classification Pressurized Hazard Classification Gas under pressure Compressed gas Label Elements Hazard Symbols Signal Word Warning Hazard Statements Contents under pressure may explode if heated Revision Date April 10 2015 Page 1 of 10 2 gg
8. guishing agent and therefore is not a problem when trying to control a fire Use extinguishing agent appropriate to other materials involved Keep pressurized containers and surroundings cool with water spray as they may rupture or burst in the heat of a fire Specific hazards arising from the chemical Pressurized containers may explode in heat of fire Special Protective Actions for Fire Fighters Wear full protective clothing and self contained breathing apparatus as appropriate for specific fire conditions Revision Date April 10 2015 Page 3 of 10 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical Fire Extinguishing Agent Pressurized r United Technologies and Non pressurized ACCIDENTAL RELEASE MEASURES Personal precautions protective equipment and emergency procedures Wear appropriate protective clothing Prevent skin and eye contact Remove leaking container to a safe place Ventilate the area Environmental Precautions Prevent large quantities of the material from entering drains or watercourses Methods and materials for containment and cleaning up Sweep up or vacuum and transfer into suitable containers for recovery or disposal HANDLING AND STORAGE Precautions for safe handling Wear appropriate protective clothing Prevent skin and eye contact Conditions for safe storage Pressurized containers should be properly stored and secured to prevent falling or being knocked over Do not drag slide or roll press
9. lkaline earth metals Hazardous Decomposition Products Oxides of carbon TOXICOLOGICAL INFORMATION Acute Toxicity Potassium Bicarbonate Oral LD50 Rat gt 5000 mg kg Dermal LD50 Rabbit gt 2000mg kg Calcium Carbonate Oral LD50 Rat gt 2000 mg kg Dermal LD50 Rabbit gt 2000mg kg Inhalation LC50 rat gt 3 0mg Revision Date April 10 2015 Page 6 of 10 11 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical Fire Extinguishing Agent Pressurized r United Technologies and Non pressurized TOXICOLOGICAL INFORMATION Acute Toxicity Mica Oral LD50 Rat gt 2000 mg kg Amorphous Silica Oral LD50 Rat gt 5000 mg kg Dermal LD50 Rabbit gt 2000mg kg Dye Oral LD50 Rat gt 2000 mg kg no deaths Clay Oral LD50 Rat gt 5000 mg kg Dermal LD50 Rabbit gt 5000mg kg Nitrogen Simple asphyxiant Carbon Dioxide Simple asphyxiant LCLo inhalation in humans 90 000ppm 5 minutes Specific Target Organ Toxicity STOT single exposure Potassium Bicarbonate Available data indicates this component is not expected to cause target organ effects after a single exposure Calcium Carbonate Available data indicates this component is not expected to cause target organ effects after a single exposure Nitrogen and Carbon Dioxide Exposure to nitrogen and carbon dioxide gas at high concentrations can cause suffocation by reducing oxygen available for breathing Breathing very high conc
10. ng Agent Pressurized r United Technologies and Non pressurized TOXICOLOGICAL INFORMATION Germ Cell Mutagenicity Potassium Bicarbonate Negative in several studies for mutagenicity Calcium Carbonate Negative results in the Mammalian Cell Gene Mutation Assay with and without metabolic activation Ames test and In vitro Mammalian Chromosome Aberration Test Reproductive Toxicity Potassium Bicarbonate Available data indicates this component is not expected to cause reproductive toxicity or birth defects Calcium Carbonate Available data indicates this component is not expected to cause reproductive toxicity or birth defects Aspiration Hazard Not an aspiration hazard ECOLOGICAL INFORMATION Ecotoxicity Potassium Bicarbonate LC50 rainbow trout 1300 mg l 96h LC50 Ceriodaphnia dubia 630 mg l 96h Mobility in soil Nitrogen and carbon dioxide occur naturally in the atmosphere Persistence Degradability Nitrogen and carbon dioxide occur naturally in the atmosphere Bioaccumulative Potential Nitrogen and carbon dioxide occur naturally in the atmosphere Other adverse effects No relevant studies identified DISPOSAL CONSIDERATIONS Disposal Methods Dispose of container in accordance with all applicable local and national regulations Do not cut puncture or weld on or near to the pressurized container If spilled expellant will vaporize to the atmosphere TRANSPORT INFORMATION Safety Data Sheet information is in
11. red Use dust mask where dustiness is prevalent or TLV is exceeded In oxygen deficient atmospheres use a self contained breathing apparatus as an air purifying respirator will not provide protection Skin Protection Not normally needed when used as a portable fire extinguisher Use gloves if irritation occurs Eye Face Protection Chemical goggles or safety glasses with side shields Body Protection Normal work wear PHYSICAL AND CHEMICAL PROPERTIES Non Pressurized Appearance Physical State Color Odor Odor Threshold pH Specific Gravity Boiling Range Point C F Melting Point C F Flash Point PMCC C F Vapor Pressure Evaporation Rate BuAc 1 Solubility in Water Vapor Density Air 1 VOC g l VOC Partition coefficient n octanol water Viscosity Auto ignition Temperature Decomposition Temperature Upper explosive limit Lower explosive limit Flammability solid gas Solid powder Purple Pink Odorless No data available Not applicable No data available Not applicable No data available Not flammable No data available No data available No data available Not applicable None None No data available No data available No data available No data available No data available No data available No data available Expellant Appearance Physical State Compressed gas Color Colorless Odor None Odor Threshold No data available pH Not applicable Specific Gravity 0 075 lb ft 7
12. tended to address a specific material and not various forms or states of containment Specific volumes pressures or hardware configurations containing such materials can dictate various different hazard classifications for transportation and labelling requirements Under Federal Regulations only trained and qualified individuals are permitted to label and ship products following the applicable Department of Transportation DOT Federal Aviation Administration FAA Transport Canada TC International Maritime Dangerous Goods IMDG or International Air Transport Association IATA requirements Revision Date April 10 2015 Page 8 of 10 15 16 SAFETY DATA SHEET DP g_ Kid d e Purple K Dry Chemical Fire Extinguishing Agent Pressurized r United Technologies and Non pressurized REGULATORY INFORMATION United States TSCA Inventory This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance Control Act Chemical Substance Inventory Canada DSL Inventory All ingredients in this product are listed on the Domestic Substance List DSL or the Non Domestic Substance List NDSL or are exempt from listing SARA Title Ill Sect 311 312 Categorization Pressurized Pressure hazard SARA Title Ill Sect 311 312 Categorization Non pressurized None SARA Title Ill Sect 313 This product does not contain any chemicals that are listed in Section 313 at or above de minimis concentrations O
13. urized containers Do not drop pressurized containers or permit them to strike against each other Never apply flame or localized heat directly to any part of the pressurized or plastic container Store pressurized and plastic containers away from high heat sources Storage area should be cool dry well ventilated under cover out of direct sunlight EXPOSURE CONTROLS PERSONAL PROTECTION Control parameters Exposure limits are listed below if they exist Mica ACGIH TLV 3 mg m TWA measured as respirable fraction of the aerosol OSHA PEL 20 mppcf lt 1 crystalline silica Calcium Carbonate OSHA PEL 15 mg m TWA total dust 5 mg m TWA respirable fraction Clay as Kaolin Respirable Fraction ACGIH TLV 2 mg m TWA OSHA PEL 15 mg m TWA total dust 5 mg m TWA respirable fraction Nuisance Dust Limit OSHA PEL 50 mppcf or 15 mg m TWA total dust 15 mppcf or 5 mg m TWA respirable fraction Appropriate engineering controls Use with adequate ventilation There should be local procedures for the selection training inspection and maintenance of this equipment When used in large volumes use local exhaust ventilation Revision Date April 10 2015 Page 4 of 10 SAFETY DATA SHEET Purple K Dry Chemical Fire Extinguishing Agent Pressurized and Non pressurized a g Kidde J United Technologies EXPOSURE CONTROLS PERSONAL PROTECTION Individual protection measures Respiratory Protection Not normally requi
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