Stratasys RS-30
Contents
1. Aquatic toxicity No further relevant information available 12 2 Persistence and degradability No further relevant information available Degree of elimination no data available 12 3 Bioaccumulative potential No further relevant information available 12 4 Mobility in soil No further relevant information available Additional ecological information General notes Water hazard class 1 Self assessment slightly hazardous for water 12 5 Results of PBT and vPvB assessment PBT Not applicable vPvB Not applicable 12 6 Other adverse effects No further relevant information available SECTION 13 Disposal considerations 13 1 Waste treatment methods Recommendation Disposal must be made according to official regulations Uncleaned packagings Recommendation Disposal must be made according to official regulations SECTION 14 Transport information 14 1 UN Number ADR IMDG IATA Void 14 2 UN proper shipping name ADR IMDG IATA Void 14 3 Transport hazard class es ADR IMDG IATA Class 14 4 Packing group ADR IMDG IATA Contd on page 6 GB 209327 0002 B S4 Stratasys Page 6 6 Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 Revision 19 09 2013 Trade name SR 30 Soluble Support Contd of page 5 14 6 Special precautions for user Not applicable 14 7 Transport in bul2. available 4 3 Indication of any immediate medical attention and special treatment needed No further relevant information available SECTION 5 Firefighting measures 5 1 Extinguishing media Suitable extinguishing agents Carbon dioxide COz extinguishing powder or water spray fog Fight larger fires with water spray fog or alcohol resistant foam For safety reasons unsuitable extinguishing agents Water with a full water jet 5 2 Special hazards arising from the substance or mixture Can be released in case of fire Smoke Carbon monoxide CO and Carbon dioxide CO 2 Under certain fire conditions traces of other toxic gases cannot be excluded 5 3 Advice for firefighters Protective equipment Wear self contained breathing apparatus Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations SECTION 6 Accidental release measures 6 1 Personal precautions protective equipment and emergency procedures Wear protective clothing Avoid contact with eyes Avoid causing dust 6 2 Environmental precautions Do not allow to enter drainage system surface or ground water 6 3 Methods and material for containment and cleaning up Prevent formation of dust Collect mechanically Dispose of the material collected according to regulations 6 4 Reference to other sections See Section 8 for information on personal protection equipment SECTION 7 Handling and
3. VA A 5 Stratasys Page 1 6 Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 Revision 19 09 2013 SECTION 1 Identification of the substance mixture and of the company undertaking Date of compilation 28 10 2009 1 1 Product identifier Trade name SR 30 Soluble Support CAS Number 25036 16 2 1 2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available Application of the substance the preparation Soluble Release Material for Stratasys Inc FDM modelers 1 3 Details of the supplier of the safety data sheet Manufacturer Supplier Stratasys Inc Tel 1 952 937 3000 7665 Commerce Way Fax 1 952 937 0070 Eden Prairie MN 55344 USA For information in Europe contact C S B GmbH Tel 49 2151 6520860 D sseldorfer StraBe 113 Fax 49 2151 6520869 D 47809 Krefeld E Mail info csb online de Germany E mail address of the competent person responsible for the Safety Data Sheet sdb csb online de Informing department Product safety department 1 4 Emergency telephone number As above or next toxicological information centre SECTION 2 Hazards identification 2 1 Classification of the substance or mixture Classification according to Regulation EC No 1272 2008 The substance is not classified according to the CLP regulation Classification according to Directive 67 548 EEC o
4. euses par Route European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG International Maritime Code for Dangerous Goods IATA International Air Transport Association GHS Globally Harmonized System of Classification and Labelling of Chemicals CAS Chemical Abstracts Service division of the American Chemical Society LC50 Lethal concentration 50 percent LDSO Lethal dose 50 percent 209327 0002 B
5. evision 19 09 2013 Trade name SR 30 Soluble Support Contd of page 3 Change in condition Melting point Melting range no data available Boiling point Boiling range no data available Flash point no data available Inflammability solid gaseous not classified as flammable solid Ignition temperature gt 450 C Decomposition temperature gt 290 C Self inflammability Product is not selfigniting Danger of explosion Product is not explosive Critical values for explosion Lower not determined Upper not determined Oxidizing properties not applicable Vapor pressure not determined Density at 20 C 1 1 g cm Relative density at 20 C 1 1 H0 1 Vapour density AIR 1 not determined Evaporation rate not determined Solubility in Miscibility with Water insoluble Partition coefficient n octanol water not determined Viscosity dynamic not applicable kinematic not applicable 9 2 Other information No further relevant information available SECTION 10 Stability and reactivity 10 1 Reactivity see 10 3 10 2 Chemical stability Thermal decomposition conditions to be avoided No decomposition if used and stored according to specifications Avoid impact friction heat sparks electrostatic charges 10 3 Possibility of hazardous reactions Toxic fumes may be released if heated above the decomposition poi
6. k according to Annex II of MARPOL73 78 and the IBC Code Not applicable Transport Additional information Not dangerous according to the above specifications UN Model Regulation SECTION 15 Regulatory information 15 1 Safety health and environmental regulations legislation specific for the substance or mixture National regulations Decree to be applied in case of technical fault Directive 96 82 EC does not apply Water hazard class Water hazard class 1 Self assessment slightly hazardous for water Other regulations limitations and prohibitive regulations The monomer compounds of this product are listed in EINECS ELINCS Europa 15 2 Chemical safety assessment A Chemical Safety Assessment has not been carried out SECTION 16 Other information These data are based on our present knowledge However they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship Department issuing MSDS C S B GmbH Phone 49 2151 652086 0 Diisseldorfer Str 113 Fax 49 2151 652086 9 47809 Krefeld Germany Abbreviations and acronyms RID R glement international concernant le transport des marchandises dangereuses par chemin de fer Regulations Concerning the International Transport of Dangerous Goods by Rail ICAO International Civil Aviation Organization ADR Accord europ en sur le transport des marchandises danger
7. n The lists that were valid during the compilation were used as basis 8 2 Exposure controls Personal protective equipment General protective and hygienic measures Do not breathe dust Avoid contact with the eyes Avoid close or long term contact with the skin Wash hands during breaks and at the end of the work Breathing equipment If all workplace limits are observed and good ventilation is ensured no special precautions necessary Protection of hands Use heat resistant gloves when handling hot molten product Material of gloves The selection of the suitable gloves does not only depend on the material but also on further marks of quality and varies from manufacturer to manufacturer Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed Eye protection Safety glasses Body protection Body protection must be chosen depending on activity and possible exposure SECTION 9 Physical and chemical properties 9 1 Information on basic physical and chemical properties General Information Appearance Form Pellets Colour milky white Smell nearly odourless Odour threshold no data available pH value not applicable Contd on page 4 GB 209327 0002 B lA z Stratasys Page 46 Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 R
8. nt 10 4 Conditions to avoid No further relevant information available 10 5 Incompatible materials No further relevant information available 10 6 Hazardous decomposition products Carbon monoxide CO and Carbon dioxide CO 2 Possible in traces Hydrocarbons Styrene Nitrogen oxides NOx Organic acids Acrylmonomeres Acrylcompounds Alcohols GB Contd on page 5 209327 0002 B sf Stratasys Page 51 Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 Revision 19 09 2013 Trade name SR 30 Soluble Support Contd of page 4 SECTION 11 Toxicological information 11 1 Information on toxicological effects Acute toxicity LD LC50 values that are relevant for classification no data available Primary irritant effect on the skin Dust particles may mechanically irritate the skin on the eye Dust particles may mechanically irritate the eye Subacute to chronic toxicity not classified Additional toxicological information When used and handled according to specifications the product does not have any harmful effects according to our experience and the information provided to us Sensitisation No sensitizing effect known Repeated dose toxicity not classified CMR effects carcinogenity mutagenicity and toxicity for reproduction According to present knowledge no CMR effects known SECTION 12 Ecological information 12 1 Toxicity
9. r Directive 1999 45 EC Void Classification system void 2 2 Label elements Labelling according to Regulation EC No 1272 2008 Void Hazard pictograms Void Signal word Void Hazard statements Void 2 3 Other hazards Results of PBT and vPvB assessment PBT Not applicable vPvB Not applicable SECTION 3 Composition information on ingredients 3 1 Chemical characterization Substances CAS No Designation 25036 16 2 Terpolymer of Methacrylic Acid Styrene and Butylacrylate Identification number s void polymer GB Contd on page 2 209327 0002 B sf Stratasys Page 26 Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 Revision 19 09 2013 Trade name SR 30 Soluble Support Contd of page 1 SECTION 4 First aid measures 4 1 Description of first aid measures General information Remove contaminated clothing After inhalation Supply fresh air consult doctor in case of symptoms After skin contact Wash with soap and water After contact with the molten product cool rapidly with cold water Do not pull solidified product away from the skin Call a doctor immediately After eye contact Rinse opened eye for several minutes under running water If symptoms persist consult doctor After swallowing No special measures required 4 2 Most important symptoms and effects both acute and delayed No further relevant information
10. storage 7 1 Precautions for safe handling Ensure good ventilation exhaustion at the workplace Prevent formation of dust Any deposit of dust which cannot be avoided must be removed regularly Contd on page 3 GB 209327 0002 B SA Stratasys a Safety data sheet according to 1907 2006 EC Article 31 Printing date 20 09 2013 Version number 1 Revision 19 09 2013 Trade name SR 30 Soluble Support Contd of page 2 Do not breathe dust Avoid contact with eyes Make sure that all applicable workplace limits are observed Information about protection against explosions and fires Protect against electrostatic charges Keep ignition sources away Do not smoke 7 2 Conditions for safe storage including any incompatibilities Storage Requirements to be met by storerooms and containers Observe all local and national regulations for storage of water polluting products Information about storage in one common storage facility Not required Further information about storage conditions Store in cool dry conditions in well sealed containers 7 3 Specific end use s No further relevant information available SECTION 8 Exposure controls personal protection Additional information about design of technical systems No further data see item 7 8 1 Control parameters Components with critical values that require monitoring at the workplace Observe all workplace limits for dust Additional informatio
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